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| Oct 20 • 14:30 | Carlos Berlocq |  | - |  | Donald Young | 0 | : | 2 |
| Oct 20 • 18:30 | Pierre-Hugues Herbert |  | - | | Édouard Roger-Vasselin | 2 | : | 1 |
| Oct 20 • 18:30 | Simone Bolelli |  | - |  | Rafael Nadal | 0 | : | 2 |
| Oct 20 • 20:00 | David Goffin |  | - |  | Dominic Thiem | 2 | : | 0 |
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| Oct 21 • 14:00 | Ivan Dodig |  | - |  | Marco Chiudinelli | 2 | : | 1 |
| Oct 21 • 14:00 | Kenny de Schepper | | - | | Federico Delbonis | 2 | : | 0 |
| Oct 21 • 15:30 | Gastão Elias |  | - |  | Benjamin Becker | 0 | : | 2 |
| Oct 21 • 16:00 | Steve Johnson | | - |  | Milos Raonic | 0 | : | 2 |
| Oct 21 • 17:40 | Lukáš Rosol |  | - | | Ivo Karlović | 0 | : | 2 |
| Oct 21 • 18:30 | Stanislas Wawrinka | | - |  | Mikhail Kukushkin | 1 | : | 2 |
| Oct 21 • 20:00 | Jarkko Nieminen |  | - | | Vasek Pospisil | 1 | : | 2 |
| Oct 22 • 13:00 | Andrey Golubev | | - |  | Teymuraz Gabashvili | 2 | : | 0 |
| Oct 22 • 14:00 | Ernests Gulbis |  | - | | Borna Ćorić | 0 | : | 2 |
| Oct 22 • 14:30 | Jerzy Janowicz |  | - |  | Denis Istomin | 0 | : | 2 |
| Oct 22 • 17:30 | Roger Federer | | - |  | Gilles Müller | 2 | : | 0 |
| Oct 22 • 18:30 | Alexander Zverev | | - |  | Grigor Dimitrov | 1 | : | 2 |
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| Oct 22 • 15:45 | David Goffin | | - | | Ivan Dodig | 2 | : | 0 |
| Oct 22 • 16:00 | Pierre-Hugues Herbert | | - | | Rafael Nadal | 0 | : | 2 |
| Oct 23 • 14:00 | Mikhail Kukushkin | | - | | Benjamin Becker | 1 | : | 1 |
| Oct 23 • 14:00 | Borna Ćorić | | - | | Andrey Golubev | 2 | : | 0 |
| Oct 23 • 15:30 | Kenny de Schepper | | - | | Ivo Karlović | 1 | : | 2 |
| Oct 23 • 16:00 | Donald Young | | - | | Milos Raonic | 1 | : | 2 |
| Oct 23 • 18:00 | Roger Federer | | - | | Denis Istomin | 2 | : | 1 |
| Oct 23 • 20:00 | Vasek Pospisil | | - | | Grigor Dimitrov | 0 | : | 2 |
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| Oct 24 • 14:00 | David Goffin | | - | | Milos Raonic | 2 | : | 1 |
| Oct 24 • 16:00 | Benjamin Becker | | - | | Ivo Karlović | 0 | : | 2 |
| Oct 24 • 18:30 | Borna Ćorić | | - | | Rafael Nadal | 2 | : | 0 |
| Oct 24 • 20:00 | Roger Federer | | - | | Grigor Dimitrov | 2 | : | 0 |
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| Oct 25 • 14:30 | David Goffin | | - | | Borna Ćorić | 2 | : | 1 |
| Oct 25 • 16:00 | Roger Federer | | - | | Ivo Karlović | 2 | : | 1 |
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| Oct 26 • 14:30 | Roger Federer | | - | | David Goffin | 2 | : | 0 |
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