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| May 10 • 12:00 | Matteo Donati |  | - |  | Santiago Giraldo | 2 | : | 1 |
| May 10 • 12:00 | Kevin Anderson |  | - |  | Florian Mayer | 2 | : | 1 |
| May 10 • 13:30 | Jérémy Chardy |  | - |  | Lukáš Rosol | 2 | : | 0 |
| May 10 • 13:30 | Federico Gaio | | - |  | Leonardo Mayer | 0 | : | 2 |
| May 10 • 15:00 | Luca Vanni | | - |  | Nicolás Almagro | 0 | : | 2 |
| May 10 • 15:00 | Ernests Gulbis |  | - | | Jiří Veselý | 1 | : | 2 |
| May 11 • 11:15 | Jack Sock |  | - | | Gilles Simon | 1 | : | 2 |
| May 11 • 12:00 | Jerzy Janowicz |  | - |  | Grigor Dimitrov | 0 | : | 2 |
| May 11 • 12:30 | Philipp Kohlschreiber | | - | | Donald Young | 2 | : | 0 |
| May 11 • 12:40 | John Isner | | - |  | João Sousa | 2 | : | 0 |
| May 11 • 14:15 | Juan Mónaco | | - |  | Dušan Lajović | 2 | : | 1 |
| May 11 • 15:45 | Simone Bolelli | | - |  | Dominic Thiem | 0 | : | 2 |
| May 11 • 16:30 | Adrian Mannarino | | - |  | Marsel İlhan | 0 | : | 2 |
| May 11 • 16:30 | Pablo Cuevas |  | - | | Paolo Lorenzi | 2 | : | 0 |
| May 11 • 19:00 | Richard Gasquet | | - | | Thomas Fabbiano | 2 | : | 0 |
| May 11 • 19:30 | Steve Johnson | | - | | Fabio Fognini | 0 | : | 2 |
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| May 12 • 11:00 | Thomaz Bellucci |  | - | | Diego Schwartzman | 1 | : | 0 |
| May 12 • 11:00 | Marin Čilić |  | - | | Guillermo García López | 0 | : | 2 |
| May 12 • 12:30 | Feliciano López | | - |  | Nick Kyrgios | 2 | : | 0 |
| May 12 • 12:30 | Bernard Tomic | | - | | Viktor Troicki | 1 | : | 2 |
| May 12 • 12:30 | Martin Kližan |  | - |  | Alexandr Dolgopolov | 0 | : | 2 |
| May 12 • 14:15 | Andrea Arnaboldi | | - |  | David Goffin | 1 | : | 2 |
| May 12 • 14:30 | Marcel Granollers | | - | | Roberto Bautista-Agut | 0 | : | 2 |
| May 12 • 15:45 | Sam Querrey | | - | | Jo-Wilfried Tsonga | 0 | : | 2 |
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| May 12 • 13:30 | Stanislas Wawrinka |  | - | | Juan Mónaco | 2 | : | 1 |
| May 12 • 15:00 | Novak Djokovic | | - | | Nicolás Almagro | 2 | : | 1 |
| May 12 • 16:00 | Kevin Anderson | | - | | Philipp Kohlschreiber | 0 | : | 0 |
| May 12 • 19:00 | Richard Gasquet | | - | | David Ferrer | 0 | : | 2 |
| May 12 • 21:00 | Tomáš Berdych | | - | | Matteo Donati | 2 | : | 0 |
| May 13 • 11:00 | Guillermo García López | | - | | Alexandr Dolgopolov | 2 | : | 0 |
| May 13 • 11:00 | John Isner | | - | | Leonardo Mayer | 2 | : | 0 |
| May 13 • 12:00 | Jiří Veselý | | - |  | Kei Nishikori | 0 | : | 2 |
| May 13 • 12:00 | Andy Murray |  | - | | Jérémy Chardy | 2 | : | 0 |
| May 13 • 13:30 | Marsel İlhan | | - | | Rafael Nadal | 0 | : | 2 |
| May 13 • 13:45 | Dominic Thiem | | - | | Gilles Simon | 1 | : | 0 |
| May 13 • 14:30 | Thomaz Bellucci | | - | | Roberto Bautista-Agut | 2 | : | 1 |
| May 13 • 15:00 | Fabio Fognini | | - | | Grigor Dimitrov | 2 | : | 1 |
| May 13 • 16:30 | David Goffin | | - | | Jo-Wilfried Tsonga | 2 | : | 1 |
| May 13 • 19:00 | Feliciano López | | - | | Viktor Troicki | 1 | : | 2 |
| May 13 • 19:30 | Pablo Cuevas | | - | | Roger Federer | 0 | : | 2 |
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| May 14 • 12:00 | John Isner | | - | | Rafael Nadal | 0 | : | 2 |
| May 14 • 12:30 | Guillermo García López | | - | | David Ferrer | 0 | : | 2 |
| May 14 • 13:50 | Andy Murray | | - | | David Goffin | 0 | : | 0 |
| May 14 • 14:25 | Stanislas Wawrinka | | - | | Dominic Thiem | 2 | : | 0 |
| May 14 • 16:05 | Kevin Anderson | | - | | Roger Federer | 0 | : | 2 |
| May 14 • 16:20 | Tomáš Berdych | | - | | Fabio Fognini | 2 | : | 1 |
| May 14 • 19:00 | Viktor Troicki | | - | | Kei Nishikori | 0 | : | 2 |
| May 14 • 19:30 | Novak Djokovic | | - | | Thomaz Bellucci | 2 | : | 1 |
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| May 15 • 12:00 | David Goffin | | - | | David Ferrer | 1 | : | 2 |
| May 15 • 14:00 | Tomáš Berdych | | - | | Roger Federer | 0 | : | 2 |
| May 15 • 16:00 | Novak Djokovic | | - | | Kei Nishikori | 2 | : | 1 |
| May 15 • 21:00 | Stanislas Wawrinka | | - | | Rafael Nadal | 2 | : | 0 |
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| May 16 • 14:00 | Novak Djokovic | | - | | David Ferrer | 2 | : | 0 |
| May 16 • 20:00 | Stanislas Wawrinka | | - | | Roger Federer | 0 | : | 2 |
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| May 17 • 16:00 | Novak Djokovic | | - | | Roger Federer | 2 | : | 0 |
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