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| Aug 16 • 20:00 | Dominic Thiem |  | - |  | Martin Kližan | 1 | : | 2 |
| Aug 17 • 01:00 | Grigor Dimitrov |  | - |  | Lukáš Rosol | 2 | : | 1 |
| Aug 17 • 17:00 | Gilles Simon |  | - |  | Ivo Karlović | 1 | : | 2 |
| Aug 17 • 17:00 | Thomaz Bellucci |  | - | | Jiří Veselý | 2 | : | 0 |
| Aug 17 • 17:00 | João Sousa |  | - |  | Philipp Kohlschreiber | 2 | : | 1 |
| Aug 17 • 17:00 | Viktor Troicki |  | - |  | Mardy Fish | 0 | : | 2 |
| Aug 17 • 18:30 | Sergiy Stakhovsky |  | - |  | Bernard Tomic | 0 | : | 2 |
| Aug 17 • 18:30 | Vasek Pospisil |  | - | | Denis Kudla | 2 | : | 0 |
| Aug 17 • 18:30 | Adrian Mannarino | | - |  | Andreas Seppi | 0 | : | 2 |
| Aug 17 • 20:00 | Gilles Müller |  | - | | Benoît Paire | 0 | : | 2 |
| Aug 17 • 20:00 | Jared Donaldson | | - | | Nicolas Mahut | 2 | : | 1 |
| Aug 17 • 20:40 | Jerzy Janowicz |  | - | | Gaël Monfils | 2 | : | 0 |
| Aug 17 • 21:00 | Lu Yen-Hsun |  | - |  | David Goffin | 1 | : | 2 |
| Aug 18 • 01:00 | Fabio Fognini | | - | | Thanasi Kokkinakis | 1 | : | 2 |
| Aug 18 • 01:00 | Roberto Bautista-Agut |  | - |  | Pablo Cuevas | 2 | : | 0 |
| Aug 18 • 02:30 | Bjorn Fratangelo | | - | | Jack Sock | 0 | : | 2 |
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| Aug 18 • 17:00 | Borna Ćorić | | - | | Alexander Zverev | 2 | : | 1 |
| Aug 18 • 17:00 | Pablo Andújar | | - | | Tommy Robredo | 1 | : | 2 |
| Aug 18 • 17:00 | Nick Kyrgios | | - | | Richard Gasquet | 0 | : | 2 |
| Aug 18 • 17:00 | Kevin Anderson |  | - |  | Leonardo Mayer | 2 | : | 1 |
| Aug 18 • 18:30 | Jo-Wilfried Tsonga | | - | | Fernando Verdasco | 1 | : | 2 |
| Aug 18 • 18:30 | John Isner | | - | | Sam Querrey | 0 | : | 2 |
| Aug 18 • 20:00 | Rajeev Ram | | - | | Jérémy Chardy | 0 | : | 2 |
| Aug 18 • 20:00 | Feliciano López | | - | | Milos Raonic | 2 | : | 0 |
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| Aug 18 • 19:15 | Grigor Dimitrov | | - | | Vasek Pospisil | 2 | : | 0 |
| Aug 18 • 20:30 | Marin Čilić | | - | | João Sousa | 2 | : | 0 |
| Aug 18 • 22:30 | Alexandr Dolgopolov | | - | | Bernard Tomic | 2 | : | 0 |
| Aug 18 • 23:30 | Ivo Karlović | | - | | Martin Kližan | 2 | : | 0 |
| Aug 19 • 01:00 | Thomaz Bellucci | | - | | Tomáš Berdych | 0 | : | 2 |
| Aug 19 • 01:00 | Roberto Bautista-Agut | | - |  | Roger Federer | 0 | : | 2 |
| Aug 19 • 17:00 | Borna Ćorić | | - | | Stanislas Wawrinka | 1 | : | 2 |
| Aug 19 • 17:00 | Jared Donaldson | | - | | Jerzy Janowicz | 0 | : | 2 |
| Aug 19 • 17:00 | Thanasi Kokkinakis | | - | | Richard Gasquet | 0 | : | 2 |
| Aug 19 • 18:30 | Fernando Verdasco | | - | | David Goffin | 0 | : | 2 |
| Aug 19 • 18:30 | Sam Querrey | | - | | Tommy Robredo | 1 | : | 2 |
| Aug 19 • 20:00 | Kevin Anderson | | - | | Jack Sock | 2 | : | 0 |
| Aug 19 • 22:00 | Novak Djokovic | | - | | Benoît Paire | 2 | : | 0 |
| Aug 19 • 23:15 | Andreas Seppi | | - | | Feliciano López | 0 | : | 2 |
| Aug 20 • 01:00 | Mardy Fish | | - |  | Andy Murray | 0 | : | 2 |
| Aug 20 • 02:30 | Rafael Nadal | | - | | Jérémy Chardy | 2 | : | 0 |
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| Aug 20 • 17:00 | Ivo Karlović | | - | | Stanislas Wawrinka | 1 | : | 2 |
| Aug 20 • 17:00 | Alexandr Dolgopolov | | - | | Jerzy Janowicz | 2 | : | 1 |
| Aug 20 • 18:30 | Novak Djokovic | | - | | David Goffin | 2 | : | 1 |
| Aug 20 • 18:30 | Tommy Robredo | | - | | Tomáš Berdych | 0 | : | 2 |
| Aug 20 • 21:45 | Marin Čilić | | - | | Richard Gasquet | 0 | : | 2 |
| Aug 21 • 01:00 | Grigor Dimitrov | | - | | Andy Murray | 1 | : | 2 |
| Aug 21 • 01:00 | Rafael Nadal | | - | | Feliciano López | 1 | : | 2 |
| Aug 21 • 02:30 | Kevin Anderson | | - | | Roger Federer | 0 | : | 2 |
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| Aug 21 • 17:00 | Novak Djokovic | | - | | Stanislas Wawrinka | 2 | : | 0 |
| Aug 21 • 18:30 | Alexandr Dolgopolov | | - | | Tomáš Berdych | 2 | : | 0 |
| Aug 21 • 21:30 | Richard Gasquet | | - | | Andy Murray | 1 | : | 2 |
| Aug 22 • 01:00 | Feliciano López | | - | | Roger Federer | 0 | : | 2 |
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| Aug 22 • 19:00 | Novak Djokovic | | - | | Alexandr Dolgopolov | 2 | : | 1 |
| Aug 22 • 20:30 | Andy Murray | | - | | Roger Federer | 0 | : | 2 |
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| Aug 23 • 19:00 | Novak Djokovic | | - | | Roger Federer | 0 | : | 2 |
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