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| Oct 26 • 14:30 | Viktor Troicki |  | - |  | Adrian Mannarino | 1 | : | 2 |
| Oct 26 • 18:45 | Lukáš Rosol |  | - |  | Rafael Nadal | 1 | : | 2 |
| Oct 26 • 18:45 | Dominic Thiem |  | - |  | Robin Haase | 2 | : | 1 |
| Oct 26 • 20:00 | Henri Laaksonen |  | - |  | Donald Young | 1 | : | 2 |
| Oct 27 • 14:00 | Andreas Seppi |  | - |  | David Goffin | 1 | : | 2 |
| Oct 27 • 15:30 | Jerzy Janowicz |  | - |  | Philipp Kohlschreiber | 1 | : | 2 |
| Oct 27 • 16:00 | Sergiy Stakhovsky |  | - |  | Grigor Dimitrov | 0 | : | 2 |
| Oct 27 • 18:00 | Roger Federer | | - |  | Mikhail Kukushkin | 2 | : | 0 |
| Oct 27 • 20:00 | Ernests Gulbis |  | - | | John Isner | 0 | : | 2 |
| Oct 27 • 21:30 | Richard Gasquet | | - | | Jiří Veselý | 2 | : | 1 |
| Oct 27 • 21:30 | Alexandr Dolgopolov | | - | | Dušan Lajović | 0 | : | 1 |
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| Oct 28 • 14:00 | Denis Kudla | | - | | Jack Sock | 0 | : | 2 |
| Oct 28 • 14:00 | Marin Čilić |  | - | | Marco Chiudinelli | 2 | : | 0 |
| Oct 28 • 15:30 | Teymuraz Gabashvili |  | - |  | Leonardo Mayer | 2 | : | 1 |
| Oct 28 • 16:00 | Kevin Anderson |  | - | | Borna Ćorić | 2 | : | 0 |
| Oct 28 • 18:00 | Ivo Karlović | | - | | Stanislas Wawrinka | 2 | : | 1 |
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| Oct 28 • 18:30 | Adrian Mannarino | | - | | David Goffin | 0 | : | 2 |
| Oct 28 • 19:30 | Grigor Dimitrov | | - | | Rafael Nadal | 1 | : | 2 |
| Oct 29 • 14:00 | Kevin Anderson | | - | | Donald Young | 0 | : | 2 |
| Oct 29 • 14:00 | Marin Čilić | | - | | Teymuraz Gabashvili | 2 | : | 0 |
| Oct 29 • 15:30 | Dušan Lajović | | - | | Ivo Karlović | 0 | : | 2 |
| Oct 29 • 16:00 | Jack Sock | | - | | John Isner | 2 | : | 0 |
| Oct 29 • 18:00 | Richard Gasquet | | - | | Dominic Thiem | 2 | : | 0 |
| Oct 29 • 20:10 | Roger Federer | | - | | Philipp Kohlschreiber | 2 | : | 1 |
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| Oct 30 • 14:00 | Richard Gasquet | | - | | Ivo Karlović | 2 | : | 1 |
| Oct 30 • 16:00 | Donald Young | | - | | Jack Sock | 1 | : | 2 |
| Oct 30 • 18:40 | Marin Čilić | | - | | Rafael Nadal | 1 | : | 2 |
| Oct 30 • 20:40 | Roger Federer | | - | | David Goffin | 2 | : | 1 |
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| Oct 31 • 14:30 | Rafael Nadal | | - | | Richard Gasquet | 2 | : | 0 |
| Oct 31 • 16:00 | Roger Federer | | - | | Jack Sock | 2 | : | 0 |
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| Nov 01 • 14:30 | Roger Federer | | - | | Rafael Nadal | 2 | : | 1 |
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