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| May 08 • 12:00 | Kevin Anderson | | - | | Feliciano López | 2 | : | 0 |
| May 08 • 13:30 | Steve Johnson | | - | | Juan Mónaco | 0 | : | 2 |
| May 08 • 15:00 | Benoît Paire | | - | | Bernard Tomic | 0 | : | 0 |
| May 08 • 15:00 | Albert Ramos-Viñolas | | - | | Sam Querrey | 2 | : | 0 |
| May 08 • 16:30 | Teymuraz Gabashvili | | - | | Viktor Troicki | 0 | : | 2 |
| May 08 • 16:30 | Leonardo Mayer | | - | | David Goffin | 1 | : | 2 |
| May 09 • 11:00 | Richard Gasquet | | - | | Julien Benneteau | 2 | : | 0 |
| May 09 • 11:00 | Jack Sock | | - | | Guido Pella | 2 | : | 1 |
| May 09 • 12:00 | Milos Raonic | | - | | Marco Cecchinato | 2 | : | 1 |
| May 09 • 12:30 | Nick Kyrgios | | - | | Salvatore Caruso | 2 | : | 0 |
| May 09 • 12:30 | João Sousa | | - | | Lorenzo Sonego | 2 | : | 1 |
| May 09 • 14:00 | Andreas Seppi | | - | | Vasek Pospisil | 2 | : | 0 |
| May 09 • 14:00 | Ivo Karlović | | - | | Ernests Gulbis | 1 | : | 2 |
| May 09 • 15:00 | Fabio Fognini | | - | | Guillermo García López | 0 | : | 2 |
| May 09 • 16:30 | Alexandr Dolgopolov | | - | | Dominic Thiem | 1 | : | 2 |
| May 09 • 17:35 | Mikhail Kukushkin | | - | | Borna Ćorić | 2 | : | 1 |
| May 09 • 19:00 | Thomaz Bellucci | | - | | Gaël Monfils | 2 | : | 0 |
| May 09 • 19:30 | Alexander Zverev | | - | | Grigor Dimitrov | 2 | : | 0 |
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| May 10 • 11:00 | Pablo Cuevas | | - | | Nicolas Mahut | 1 | : | 2 |
| May 10 • 12:30 | Stéphane Robert | | - | | Aljaž Bedene | 2 | : | 0 |
| May 10 • 12:30 | Philipp Kohlschreiber | | - | | Inigo Cervantes | 2 | : | 0 |
| May 10 • 12:30 | Jérémy Chardy | | - | | Damir Džumhur | 2 | : | 1 |
| May 10 • 15:30 | Filippo Volandri | | - | | David Ferrer | 1 | : | 2 |
| May 10 • 15:45 | Roberto Bautista-Agut | | - | | Paolo Lorenzi | 2 | : | 0 |
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| May 10 • 11:00 | Tomáš Berdych | | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| May 10 • 14:00 | Viktor Troicki | | - | | Kei Nishikori | 1 | : | 2 |
| May 10 • 14:00 | Lucas Pouille | | - | | Ernests Gulbis | 2 | : | 1 |
| May 10 • 15:30 | Kevin Anderson | | - | | Juan Mónaco | 1 | : | 2 |
| May 10 • 19:00 | Jack Sock | | - | | David Goffin | 0 | : | 2 |
| May 10 • 21:00 | Benoît Paire | | - | | Stanislas Wawrinka | 1 | : | 2 |
| May 11 • 12:00 | Roger Federer | | - | | Alexander Zverev | 2 | : | 0 |
| May 11 • 12:20 | João Sousa | | - | | Dominic Thiem | 0 | : | 2 |
| May 11 • 13:30 | Novak Djokovic | | - | | Stéphane Robert | 2 | : | 0 |
| May 11 • 13:50 | Mikhail Kukushkin | | - | | Andy Murray | 0 | : | 2 |
| May 11 • 14:15 | Nicolas Mahut | | - | | Thomaz Bellucci | 0 | : | 2 |
| May 11 • 14:15 | Richard Gasquet | | - | | Andreas Seppi | 2 | : | 0 |
| May 11 • 15:45 | Milos Raonic | | - | | Nick Kyrgios | 0 | : | 2 |
| May 11 • 15:45 | Roberto Bautista-Agut | | - | | Jérémy Chardy | 0 | : | 2 |
| May 11 • 19:00 | Guillermo García López | | - | | David Ferrer | 0 | : | 2 |
| May 11 • 19:30 | Philipp Kohlschreiber | | - | | Rafael Nadal | 0 | : | 2 |
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| May 12 • 12:00 | Roger Federer | | - | | Dominic Thiem | 0 | : | 2 |
| May 12 • 12:30 | Richard Gasquet | | - | | Kei Nishikori | 0 | : | 2 |
| May 12 • 14:00 | Lucas Pouille | | - | | David Ferrer | 2 | : | 0 |
| May 12 • 14:00 | Juan Mónaco | | - | | Stanislas Wawrinka | 2 | : | 1 |
| May 12 • 16:10 | Nick Kyrgios | | - | | Rafael Nadal | 1 | : | 2 |
| May 12 • 17:00 | Jérémy Chardy | | - | | Andy Murray | 0 | : | 2 |
| May 12 • 19:15 | Tomáš Berdych | | - | | David Goffin | 0 | : | 2 |
| May 12 • 19:30 | Novak Djokovic | | - | | Thomaz Bellucci | 2 | : | 1 |
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| May 13 • 12:00 | Lucas Pouille | | - | | Juan Mónaco | 0 | : | 0 |
| May 13 • 14:00 | David Goffin | | - | | Andy Murray | 0 | : | 2 |
| May 13 • 15:30 | Novak Djokovic | | - | | Rafael Nadal | 2 | : | 0 |
| May 13 • 21:05 | Dominic Thiem | | - | | Kei Nishikori | 0 | : | 2 |
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| May 14 • 14:30 | Lucas Pouille | | - | | Andy Murray | 0 | : | 2 |
| May 14 • 20:00 | Novak Djokovic | | - | | Kei Nishikori | 2 | : | 1 |
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| May 15 • 17:00 | Novak Djokovic | | - | | Andy Murray | 0 | : | 2 |
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