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| Jul 11 • 12:00 | Paul-Henri Mathieu |  | - |  | Gerald Melzer | 2 | : | 0 |
| Jul 11 • 13:00 | Nicolás Kicker |  | - |  | Thomas Fabbiano | 2 | : | 1 |
| Jul 11 • 13:00 | Pablo Cuevas |  | - |  | Florian Mayer | 2 | : | 0 |
| Jul 11 • 13:30 | Marvin Möller | | - |  | Grega Žemlja | 0 | : | 2 |
| Jul 11 • 14:30 | Jan Šátral |  | - |  | Nicolás Almagro | 1 | : | 2 |
| Jul 11 • 15:30 | Máximo González | | - | | Jérémy Chardy | 2 | : | 1 |
| Jul 11 • 16:00 | Thiago Moura Monteiro |  | - | | Mischa Zverev | 2 | : | 0 |
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| Jul 12 • 11:00 | Mikhail Youzhny |  | - | | Renzo Olivo | 1 | : | 2 |
| Jul 12 • 11:00 | Leonardo Mayer | | - | | Stéphane Robert | 0 | : | 2 |
| Jul 12 • 11:00 | Martin Kližan |  | - |  | Igor Sijsling | 2 | : | 1 |
| Jul 12 • 11:00 | Daniel Gimeno-Traver | | - | | Benoît Paire | 2 | : | 1 |
| Jul 12 • 12:30 | Guillermo García López | | - | | Kenny de Schepper | 2 | : | 1 |
| Jul 12 • 13:00 | Philipp Kohlschreiber | | - | | Carlos Berlocq | 2 | : | 1 |
| Jul 12 • 14:00 | Steven Diez |  | - | | Louis Wessels | 1 | : | 2 |
| Jul 12 • 14:30 | Inigo Cervantes | | - | | Alexander Zverev | 2 | : | 0 |
| Jul 12 • 16:30 | Jan-Lennard Struff | | - | | Daniil Medvedev | 1 | : | 2 |
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| Jul 13 • 11:00 | Renzo Olivo | | - | | Máximo González | 2 | : | 0 |
| Jul 13 • 13:00 | Pablo Cuevas | | - | | Thiago Moura Monteiro | 2 | : | 0 |
| Jul 13 • 14:30 | Philipp Kohlschreiber | | - | | Nicolás Kicker | 2 | : | 1 |
| Jul 13 • 18:00 | Paul-Henri Mathieu | | - | | Nicolás Almagro | 2 | : | 1 |
| Jul 14 • 11:00 | Stéphane Robert | | - | | Inigo Cervantes | 2 | : | 1 |
| Jul 14 • 13:00 | Guillermo García López | | - | | Grega Žemlja | 2 | : | 0 |
| Jul 14 • 14:30 | Martin Kližan | | - | | Louis Wessels | 2 | : | 0 |
| Jul 14 • 16:00 | Daniil Medvedev | | - | | Daniel Gimeno-Traver | 1 | : | 2 |
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| Jul 15 • 11:00 | Pablo Cuevas | | - | | Paul-Henri Mathieu | 2 | : | 0 |
| Jul 15 • 12:30 | Guillermo García López | | - | | Stéphane Robert | 1 | : | 2 |
| Jul 15 • 14:00 | Philipp Kohlschreiber | | - | | Renzo Olivo | 1 | : | 2 |
| Jul 15 • 16:15 | Martin Kližan | | - | | Daniel Gimeno-Traver | 2 | : | 0 |
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| Jul 16 • 15:00 | Renzo Olivo | | - | | Pablo Cuevas | 0 | : | 2 |
| Jul 16 • 16:30 | Stéphane Robert | | - | | Martin Kližan | 0 | : | 2 |
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| Jul 17 • 15:00 | Pablo Cuevas | | - | | Martin Kližan | 0 | : | 2 |
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