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| May 27 • 11:00 | Mohamed Safwat |  | - |  | Grigor Dimitrov | 0 | : | 3 |
| May 27 • 11:00 | Damir Džumhur |  | - |  | Denis Kudla | 3 | : | 0 |
| May 27 • 11:00 | Gregoire Barrere |  | - |  | Radu Albot | 2 | : | 3 |
| May 27 • 12:40 | Martin Kližan |  | - |  | Laslo Djere | 3 | : | 1 |
| May 27 • 12:40 | Elliot Benchetrit |  | - | | Gaël Monfils | 1 | : | 3 |
| May 27 • 12:40 | Jozef Kovalík | | - |  | Pablo Carreño Busta | 1 | : | 3 |
| May 27 • 12:40 | Nicolás Jarry |  | - | | Jared Donaldson | 2 | : | 3 |
| May 27 • 12:40 | Kei Nishikori |  | - | | Maxime Janvier | 3 | : | 0 |
| May 27 • 14:40 | Ivo Karlović |  | - | | Corentin Moutet | 0 | : | 3 |
| May 27 • 14:45 | Oscar Otte |  | - |  | Matteo Berrettini | 1 | : | 3 |
| May 27 • 14:55 | Guido Andreozzi |  | - | | Taylor Harry Fritz | 3 | : | 2 |
| May 27 • 15:00 | Lucas Pouille | | - |  | Daniil Medvedev | 3 | : | 0 |
| May 27 • 15:10 | Fernando Verdasco | | - | | Yoshihito Nishioka | 3 | : | 2 |
| May 27 • 17:00 | Ričardas Berankis |  | - | | Alexander Zverev | 0 | : | 3 |
| May 27 • 18:00 | David Goffin |  | - |  | Robin Haase | 3 | : | 2 |
| May 27 • 18:00 | Federico Delbonis | | - |  | Thomaz Bellucci | 3 | : | 1 |
| May 28 • 11:00 | Marco Cecchinato | | - |  | Marius Copil | 3 | : | 2 |
| May 28 • 11:00 | Stefanos Tsitsipas |  | - | | Carlos Taberner | 3 | : | 1 |
| May 28 • 11:00 | Ernests Gulbis |  | - |  | Gilles Müller | 3 | : | 1 |
| May 28 • 11:00 | Benoît Paire | | - | | Roberto Carballés Baena | 3 | : | 1 |
| May 28 • 11:00 | Karen Khachanov | | - |  | Andreas Haider-Maurer | 3 | : | 0 |
| May 28 • 11:00 | Guillermo García López | | - |  | Stanislas Wawrinka | 3 | : | 2 |
| May 28 • 11:15 | Marco Trungelliti | | - |  | Bernard Tomic | 3 | : | 1 |
| May 28 • 12:30 | Roberto Bautista-Agut | | - |  | Denis Istomin | 3 | : | 2 |
| May 28 • 12:30 | Jaume Munar | | - | | David Ferrer | 3 | : | 2 |
| May 28 • 12:30 | Rogério Dutra da Silva | | - | | Novak Djokovic | 0 | : | 3 |
| May 28 • 12:30 | Peter Gojowczyk | | - |  | Cameron Norrie | 0 | : | 1 |
| May 28 • 12:30 | Dušan Lajović | | - |  | Jiří Veselý | 3 | : | 0 |
| May 28 • 13:45 | Borna Ćorić | | - | | Philipp Kohlschreiber | 3 | : | 1 |
| May 28 • 14:15 | Dominic Thiem | | - |  | Ilya Ivashka | 3 | : | 0 |
| May 28 • 14:30 | Mirza Basic | | - | | Adam Pavlásek | 1 | : | 3 |
| May 28 • 14:30 | Jordan Thompson | | - |  | Casper Ruud | 2 | : | 3 |
| May 28 • 14:30 | Marcos Baghdatis |  | - |  | Santiago Giraldo | 0 | : | 0 |
| May 28 • 14:40 | Nikoloz Basilashvili |  | - | | Gilles Simon | 1 | : | 3 |
| May 28 • 15:15 | Malek Jaziri |  | - | | Mikhail Youzhny | 3 | : | 2 |
| May 28 • 15:15 | Albert Ramos-Viñolas | | - |  | Mikhail Kukushkin | 3 | : | 0 |
| May 28 • 16:15 | Frances Tiafoe | | - | | Sam Querrey | 0 | : | 3 |
| May 28 • 16:30 | Diego Schwartzman | | - | | Calvin Hemery | 3 | : | 0 |
| May 28 • 16:35 | Matthew Ebden | | - | | Thomas Fabbiano | 2 | : | 3 |
| May 28 • 17:30 | Andreas Seppi | | - | | Richard Gasquet | 0 | : | 3 |
| May 28 • 17:30 | Horacio Zeballos | | - | | Yuichi Sugita | 3 | : | 1 |
| May 28 • 17:45 | Rafael Nadal | | - | | Simone Bolelli | 3 | : | 0 |
| May 28 • 17:45 | John Isner | | - | | Noah Rubin | 3 | : | 0 |
| May 28 • 18:30 | João Sousa |  | - | | Guido Pella | 0 | : | 3 |
| May 29 • 11:00 | Denis Shapovalov |  | - | | John Millman | 3 | : | 0 |
| May 29 • 11:00 | Ryan Harrison | | - | | Maximilian Marterer | 0 | : | 3 |
| May 29 • 11:00 | Aljaž Bedene |  | - |  | Pablo Cuevas | 0 | : | 3 |
| May 29 • 11:00 | Paolo Lorenzi | | - |  | Kevin Anderson | 0 | : | 3 |
| May 29 • 11:00 | Marin Čilić | | - | | James Duckworth | 3 | : | 0 |
| May 29 • 11:00 | Hubert Hurkacz |  | - | | Tennys Sandgren | 3 | : | 1 |
| May 29 • 11:00 | Evgeny Donskoy | | - | | Jan-Lennard Struff | 0 | : | 3 |
| May 29 • 12:30 | Steve Johnson | | - | | Adrian Mannarino | 3 | : | 0 |
| May 29 • 12:30 | Alex De Minaur | | - | | Kyle Edmund | 0 | : | 3 |
| May 29 • 13:00 | Yuki Bhambri |  | - | | Ruben Bemelmans | 0 | : | 3 |
| May 29 • 13:00 | Fabio Fognini | | - | | Pablo Andújar | 3 | : | 0 |
| May 29 • 13:00 | Vasek Pospisil | | - |  | Márton Fucsovics | 0 | : | 3 |
| May 29 • 13:30 | Jurgen Zopp |  | - | | Jack Sock | 3 | : | 2 |
| May 29 • 13:30 | Dudi Sela |  | - |  | Elias Ymer | 0 | : | 3 |
| May 29 • 15:50 | Mischa Zverev | | - | | Florian Mayer | 3 | : | 0 |
| May 29 • 17:45 | Peter Polansky | | - | | Pierre-Hugues Herbert | 1 | : | 3 |
| May 29 • 17:45 | Jérémy Chardy | | - | | Tomáš Berdych | 3 | : | 2 |
| May 29 • 18:00 | Feliciano López | | - |  | Sergiy Stakhovsky | 0 | : | 3 |
| May 29 • 18:00 | Nicolas Mahut | | - | | Juan Martín del Potro | 1 | : | 3 |
| May 29 • 18:30 | Leonardo Mayer | | - | | Julien Benneteau | 1 | : | 3 |
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| May 30 • 11:00 | Marco Trungelliti | | - | | Marco Cecchinato | 0 | : | 3 |
| May 30 • 11:00 | Federico Delbonis | | - | | Pablo Carreño Busta | 1 | : | 3 |
| May 30 • 12:30 | Roberto Bautista-Agut | | - | | Santiago Giraldo | 3 | : | 0 |
| May 30 • 12:30 | Jaume Munar | | - | | Novak Djokovic | 0 | : | 3 |
| May 30 • 12:30 | Fernando Verdasco | | - | | Guido Andreozzi | 3 | : | 0 |
| May 30 • 12:30 | Jared Donaldson | | - | | Grigor Dimitrov | 2 | : | 3 |
| May 30 • 12:30 | Kei Nishikori | | - | | Benoît Paire | 3 | : | 2 |
| May 30 • 12:30 | Damir Džumhur | | - | | Radu Albot | 3 | : | 2 |
| May 30 • 12:30 | Dušan Lajović | | - | | Alexander Zverev | 2 | : | 3 |
| May 30 • 14:00 | David Goffin | | - | | Corentin Moutet | 3 | : | 0 |
| May 30 • 14:00 | Martin Kližan | | - | | Gaël Monfils | 0 | : | 3 |
| May 30 • 14:00 | Dominic Thiem | | - | | Stefanos Tsitsipas | 3 | : | 1 |
| May 30 • 14:00 | Matteo Berrettini | | - | | Ernests Gulbis | 3 | : | 1 |
| May 30 • 14:00 | Gilles Simon | | - | | Sam Querrey | 3 | : | 1 |
| May 30 • 16:30 | Karen Khachanov | | - | | Guillermo García López | 3 | : | 1 |
| May 30 • 17:30 | Lucas Pouille | | - | | Cameron Norrie | 3 | : | 1 |
| May 31 • 11:00 | Denis Shapovalov | | - | | Maximilian Marterer | 1 | : | 3 |
| May 31 • 11:00 | Ruben Bemelmans | | - | | Jurgen Zopp | 2 | : | 3 |
| May 31 • 11:00 | Marin Čilić | | - | | Hubert Hurkacz | 3 | : | 1 |
| May 31 • 11:00 | Jan-Lennard Struff | | - | | Steve Johnson | 1 | : | 3 |
| May 31 • 11:00 | Fabio Fognini | | - | | Elias Ymer | 3 | : | 0 |
| May 31 • 12:30 | Malek Jaziri | | - | | Richard Gasquet | 1 | : | 3 |
| May 31 • 12:30 | Sergiy Stakhovsky | | - | | Mischa Zverev | 1 | : | 3 |
| May 31 • 12:30 | Márton Fucsovics | | - | | Kyle Edmund | 1 | : | 3 |
| May 31 • 13:00 | Pablo Cuevas | | - | | Kevin Anderson | 1 | : | 3 |
| May 31 • 14:00 | Albert Ramos-Viñolas | | - | | Casper Ruud | 3 | : | 0 |
| May 31 • 14:30 | Rafael Nadal | | - | | Guido Pella | 3 | : | 0 |
| May 31 • 14:30 | Diego Schwartzman | | - | | Adam Pavlásek | 3 | : | 0 |
| May 31 • 14:30 | Thomas Fabbiano | | - | | Borna Ćorić | 1 | : | 3 |
| May 31 • 14:30 | Pierre-Hugues Herbert | | - | | Jérémy Chardy | 3 | : | 2 |
| May 31 • 15:30 | John Isner | | - | | Horacio Zeballos | 3 | : | 1 |
| May 31 • 15:30 | Julien Benneteau | | - | | Juan Martín del Potro | 0 | : | 3 |
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| Jun 01 • 11:00 | Fernando Verdasco | | - | | Grigor Dimitrov | 3 | : | 0 |
| Jun 01 • 11:00 | Damir Džumhur | | - | | Alexander Zverev | 2 | : | 3 |
| Jun 01 • 12:30 | Roberto Bautista-Agut | | - | | Novak Djokovic | 1 | : | 3 |
| Jun 01 • 12:30 | Kei Nishikori | | - | | Gilles Simon | 3 | : | 0 |
| Jun 01 • 14:30 | David Goffin | | - | | Gaël Monfils | 3 | : | 2 |
| Jun 01 • 14:30 | Marco Cecchinato | | - | | Pablo Carreño Busta | 3 | : | 1 |
| Jun 01 • 14:30 | Dominic Thiem | | - | | Matteo Berrettini | 3 | : | 1 |
| Jun 01 • 14:30 | Lucas Pouille | | - | | Karen Khachanov | 0 | : | 3 |
| Jun 02 • 11:00 | Mischa Zverev | | - | | Kevin Anderson | 1 | : | 3 |
| Jun 02 • 11:00 | Fabio Fognini | | - | | Kyle Edmund | 3 | : | 2 |
| Jun 02 • 12:30 | Maximilian Marterer | | - | | Jurgen Zopp | 3 | : | 0 |
| Jun 02 • 12:30 | Diego Schwartzman | | - | | Borna Ćorić | 3 | : | 0 |
| Jun 02 • 13:00 | Marin Čilić | | - | | Steve Johnson | 3 | : | 0 |
| Jun 02 • 14:00 | Rafael Nadal | | - | | Richard Gasquet | 3 | : | 0 |
| Jun 02 • 16:00 | John Isner | | - | | Pierre-Hugues Herbert | 3 | : | 0 |
| Jun 02 • 16:00 | Albert Ramos-Viñolas | | - | | Juan Martín del Potro | 0 | : | 3 |
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| Jun 03 • 11:00 | Karen Khachanov | | - | | Alexander Zverev | 2 | : | 3 |
| Jun 03 • 12:30 | Dominic Thiem | | - | | Kei Nishikori | 3 | : | 1 |
| Jun 03 • 14:30 | David Goffin | | - | | Marco Cecchinato | 1 | : | 3 |
| Jun 03 • 16:00 | Novak Djokovic | | - | | Fernando Verdasco | 3 | : | 0 |
| Jun 04 • 11:00 | Diego Schwartzman | | - | | Kevin Anderson | 3 | : | 2 |
| Jun 04 • 12:30 | Rafael Nadal | | - | | Maximilian Marterer | 3 | : | 0 |
| Jun 04 • 14:30 | John Isner | | - | | Juan Martín del Potro | 0 | : | 3 |
| Jun 04 • 16:00 | Marin Čilić | | - | | Fabio Fognini | 3 | : | 2 |
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| Jun 05 • 14:00 | Dominic Thiem | | - | | Alexander Zverev | 3 | : | 0 |
| Jun 05 • 15:30 | Marco Cecchinato | | - | | Novak Djokovic | 3 | : | 1 |
| Jun 06 • 15:30 | Rafael Nadal | | - | | Diego Schwartzman | 3 | : | 1 |
| Jun 06 • 15:30 | Marin Čilić | | - | | Juan Martín del Potro | 1 | : | 3 |
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| Jun 08 • 13:00 | Marco Cecchinato | | - | | Dominic Thiem | 0 | : | 3 |
| Jun 08 • 15:30 | Rafael Nadal | | - | | Juan Martín del Potro | 3 | : | 0 |
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| Jun 10 • 15:00 | Rafael Nadal | | - | | Dominic Thiem | 3 | : | 0 |
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