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| Oct 29 • 11:00 | Karen Khachanov |  | - |  | Filip Krajinović | 2 | : | 0 |
| Oct 29 • 11:00 | Nikoloz Basilashvili |  | - |  | John Millman | 1 | : | 0 |
| Oct 29 • 11:00 | Peter Gojowczyk |  | - |  | Damir Džumhur | 0 | : | 2 |
| Oct 29 • 12:30 | Philipp Kohlschreiber | | - |  | Robin Haase | 2 | : | 1 |
| Oct 29 • 12:30 | Roberto Bautista-Agut |  | - |  | Steve Johnson | 2 | : | 0 |
| Oct 29 • 14:00 | Adrian Mannarino |  | - | | Ugo Humbert | 2 | : | 0 |
| Oct 29 • 14:00 | Marco Cecchinato |  | - |  | João Sousa | 0 | : | 2 |
| Oct 29 • 16:15 | Feliciano López | | - | | Alex De Minaur | 2 | : | 1 |
| Oct 29 • 19:30 | Richard Gasquet | | - |  | Denis Shapovalov | 2 | : | 0 |
| Oct 29 • 21:00 | Frances Tiafoe | | - | | Nicolas Mahut | 2 | : | 0 |
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| Oct 30 • 11:00 | Fernando Verdasco | | - | | Jérémy Chardy | 2 | : | 0 |
| Oct 30 • 11:00 | Daniil Medvedev | | - | | Pablo Carreño Busta | 2 | : | 0 |
| Oct 30 • 12:30 | Pierre-Hugues Herbert | | - |  | Mikhail Kukushkin | 1 | : | 2 |
| Oct 30 • 13:30 | Márton Fucsovics |  | - | | Benoît Paire | 2 | : | 0 |
| Oct 30 • 14:25 | Gilles Simon | | - | | Lucas Pouille | 2 | : | 0 |
| Oct 30 • 15:45 | Milos Raonic | | - | | Jo-Wilfried Tsonga | 2 | : | 1 |
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| Oct 30 • 12:30 | Matthew Ebden | | - | | Karen Khachanov | 0 | : | 1 |
| Oct 30 • 15:00 | Stefanos Tsitsipas |  | - | | Damir Džumhur | 0 | : | 2 |
| Oct 30 • 19:30 | João Sousa | | - | | Novak Djokovic | 0 | : | 2 |
| Oct 30 • 21:00 | Marin Čilić |  | - | | Philipp Kohlschreiber | 2 | : | 0 |
| Oct 31 • 11:00 | Mikhail Kukushkin | | - | | John Isner | 1 | : | 2 |
| Oct 31 • 11:00 | Adrian Mannarino | | - |  | Kei Nishikori | 0 | : | 2 |
| Oct 31 • 12:30 | Alexander Zverev | | - | | Frances Tiafoe | 2 | : | 0 |
| Oct 31 • 12:30 | Roberto Bautista-Agut | | - |  | Grigor Dimitrov | 0 | : | 2 |
| Oct 31 • 14:25 | Richard Gasquet | | - | | Jack Sock | 0 | : | 2 |
| Oct 31 • 15:10 | Kevin Anderson |  | - | | Nikoloz Basilashvili | 2 | : | 1 |
| Oct 31 • 16:30 | Malek Jaziri |  | - | | Fernando Verdasco | 2 | : | 1 |
| Oct 31 • 16:40 | Feliciano López | | - |  | Diego Schwartzman | 1 | : | 2 |
| Oct 31 • 18:00 | Fabio Fognini | | - | | Márton Fucsovics | 0 | : | 0 |
| Oct 31 • 19:30 | Milos Raonic | | - |  | Roger Federer | 0 | : | 0 |
| Oct 31 • 19:50 | Borna Ćorić | | - | | Daniil Medvedev | 2 | : | 0 |
| Oct 31 • 19:50 | Gilles Simon | | - |  | Dominic Thiem | 0 | : | 2 |
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| Nov 01 • 11:00 | Marin Čilić | | - | | Grigor Dimitrov | 2 | : | 0 |
| Nov 01 • 12:30 | Damir Džumhur | | - | | Novak Djokovic | 0 | : | 1 |
| Nov 01 • 13:00 | Karen Khachanov | | - | | John Isner | 2 | : | 1 |
| Nov 01 • 14:00 | Alexander Zverev | | - | | Diego Schwartzman | 2 | : | 0 |
| Nov 01 • 14:30 | Malek Jaziri | | - | | Jack Sock | 0 | : | 2 |
| Nov 01 • 16:00 | Borna Ćorić | | - | | Dominic Thiem | 1 | : | 2 |
| Nov 01 • 19:30 | Fabio Fognini | | - | | Roger Federer | 0 | : | 2 |
| Nov 01 • 20:30 | Kevin Anderson | | - | | Kei Nishikori | 0 | : | 2 |
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| Nov 02 • 14:00 | Alexander Zverev | | - | | Karen Khachanov | 0 | : | 2 |
| Nov 02 • 15:30 | Jack Sock | | - | | Dominic Thiem | 1 | : | 2 |
| Nov 02 • 19:30 | Marin Čilić | | - | | Novak Djokovic | 1 | : | 2 |
| Nov 02 • 21:00 | Kei Nishikori | | - | | Roger Federer | 0 | : | 2 |
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| Nov 03 • 14:00 | Dominic Thiem | | - | | Karen Khachanov | 0 | : | 2 |
| Nov 03 • 16:30 | Roger Federer | | - | | Novak Djokovic | 1 | : | 2 |
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| Nov 04 • 15:00 | Karen Khachanov | | - | | Novak Djokovic | 2 | : | 0 |
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