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| Sep 27 • 11:00 | Kamilla Rakhimova |  | - |  | Shelby Rogers | 2 | : | 0 |
| Sep 27 • 11:00 | Ajla Tomljanović |  | - |  | Maria Sakkari | 0 | : | 2 |
| Sep 27 • 11:00 | Anna Blinkova | | - | | Astra Sharma | 1 | : | 2 |
| Sep 27 • 11:00 | Maddison Inglis | | - | | Ekaterina Alexandrova | 0 | : | 2 |
| Sep 27 • 11:00 | Marie Bouzkova |  | - |  | Kaia Kanepi | 1 | : | 2 |
| Sep 27 • 11:00 | Margarita Gasparyan | | - |  | Elise Mertens | 0 | : | 2 |
| Sep 27 • 11:00 | Victoria Azarenka |  | - |  | Danka Kovinić | 2 | : | 0 |
| Sep 27 • 12:30 | Anna Karolína Schmiedlová |  | - | | Venus Williams | 2 | : | 0 |
| Sep 27 • 13:00 | Simona Halep |  | - |  | Sara Sorribes Tormo | 2 | : | 0 |
| Sep 27 • 13:00 | Aliaksandra Sasnovich | | - |  | Anna-Lena Friedsam | 2 | : | 1 |
| Sep 27 • 14:50 | Barbora Strýcová | | - | | Varvara Lepchenko | 2 | : | 0 |
| Sep 27 • 14:55 | Anett Kontaveit | | - |  | Caroline Garcia | 0 | : | 2 |
| Sep 27 • 15:00 | Irina-Camelia Begu | | - |  | Jil Belen Teichmann | 2 | : | 1 |
| Sep 27 • 16:15 | Johanna Konta |  | - | | Cori Gauff | 0 | : | 2 |
| Sep 27 • 17:05 | Camila Giorgi |  | - | | Martina Trevisan | 0 | : | 1 |
| Sep 27 • 17:40 | Anna Kalinskaya | | - |  | Eugenie Bouchard | 0 | : | 2 |
| Sep 27 • 18:10 | Nina Stojanović |  | - | | Barbora Krejčíková | 0 | : | 2 |
| Sep 27 • 18:25 | Greet Minnen | | - |  | Nadia Podoroska | 0 | : | 2 |
| Sep 27 • 18:25 | Kirsten Flipkens | | - |  | Yulia Putintseva | 0 | : | 2 |
| Sep 27 • 18:55 | Dayana Yastremska |  | - | | Daria Gavrilova | 0 | : | 2 |
| Sep 28 • 11:00 | Catherine Bellis | | - | | Bernarda Pera | 0 | : | 2 |
| Sep 28 • 11:00 | Kateřina Siniaková | | - | | Lauren Davis | 2 | : | 0 |
| Sep 28 • 11:00 | Mónica Puig |  | - | | Sara Errani | 0 | : | 2 |
| Sep 28 • 11:00 | Katarina Zavatska | | - |  | Kiki Bertens | 1 | : | 2 |
| Sep 28 • 11:00 | Tsvetana Pironkova |  | - | | Andrea Petkovic | 2 | : | 0 |
| Sep 28 • 11:00 | Petra Kvitova | | - | | Océane Dodin | 2 | : | 0 |
| Sep 28 • 11:00 | Aliona Bolsova | | - | | Jasmine Paolini | 0 | : | 2 |
| Sep 28 • 12:30 | Svetlana Kuznetsova | | - | | Anastasia Pavlyuchenkova | 1 | : | 2 |
| Sep 28 • 12:30 | Elina Svitolina | | - | | Varvara Gracheva | 2 | : | 0 |
| Sep 28 • 12:30 | Christina McHale | | - | | Karolina Muchova | 2 | : | 0 |
| Sep 28 • 13:00 | Tamara Korpatsch | | - | | Amanda Anisimova | 0 | : | 2 |
| Sep 28 • 13:00 | Barbara Haas |  | - |  | Su-Wei Hsieh | 0 | : | 2 |
| Sep 28 • 13:00 | Iga Świątek |  | - | | Markéta Vondroušová | 2 | : | 0 |
| Sep 28 • 13:00 | Renata Zarazúa |  | - | | Elsa Jacquemot | 2 | : | 0 |
| Sep 28 • 13:00 | Tamara Zidansek |  | - | | Garbine Muguruza | 1 | : | 2 |
| Sep 28 • 13:00 | Angelique Kerber | | - | | Kaja Juvan | 0 | : | 2 |
| Sep 28 • 14:30 | Kristie Ahn | | - | | Serena Williams | 0 | : | 2 |
| Sep 28 • 14:30 | Viktória Kužmová | | - | | Kristyna Pliskova | 0 | : | 2 |
| Sep 28 • 14:30 | Stefanie Vögele | | - | | Patricia Maria Țig | 0 | : | 2 |
| Sep 28 • 14:30 | Shuai Zhang |  | - | | Madison Keys | 2 | : | 0 |
| Sep 28 • 16:30 | Diane Parry | | - | | Polona Hercog | 0 | : | 2 |
| Sep 28 • 16:30 | Leylah Fernandez | | - | | Magda Linette | 2 | : | 1 |
| Sep 28 • 16:30 | Arantxa Rus | | - | | Clara Burel | 1 | : | 2 |
| Sep 28 • 16:30 | Chloé Paquet | | - | | Alize Cornet | 0 | : | 2 |
| Sep 29 • 11:00 | Nao Hibino |  | - | | Marta Kostyuk | 2 | : | 0 |
| Sep 29 • 11:00 | Jennifer Brady | | - |  | Clara Tauson | 1 | : | 2 |
| Sep 29 • 11:00 | Monica Niculescu | | - | | Danielle Collins | 1 | : | 2 |
| Sep 29 • 11:00 | Alison Van Uytvanck | | - |  | Rebecca Peterson | 2 | : | 1 |
| Sep 29 • 11:00 | Tímea Babos |  | - | | Ana Bogdan | 0 | : | 2 |
| Sep 29 • 11:00 | Jeļena Ostapenko |  | - | | Madison Brengle | 2 | : | 0 |
| Sep 29 • 11:00 | Mayar Sherif |  | - | | Karolina Pliskova | 1 | : | 2 |
| Sep 29 • 12:50 | Elena Rybakina | | - | | Sorana Cirstea | 2 | : | 0 |
| Sep 29 • 13:10 | Donna Vekic |  | - | | Irina Maria Bara | 0 | : | 2 |
| Sep 29 • 13:10 | Liudmila Samsonova | | - | | Sofia Kenin | 1 | : | 2 |
| Sep 29 • 13:15 | Laura Siegemund | | - | | Kristina Mladenovic | 2 | : | 0 |
| Sep 29 • 13:20 | Fiona Ferro | | - | | Heather Watson | 2 | : | 0 |
| Sep 29 • 13:40 | Zarina Diyas | | - |  | Ons Jabeur | 1 | : | 2 |
| Sep 29 • 14:00 | Julia Görges | | - | | Alison Riske-Amritraj | 2 | : | 1 |
| Sep 29 • 14:00 | Kateryna Kozlova | | - | | Paula Badosa | 1 | : | 2 |
| Sep 29 • 15:55 | Sloane Stephens | | - | | Vitalia Diatchenko | 2 | : | 0 |
| Sep 29 • 16:20 | Daria Kasatkina | | - | | Harmony Tan | 2 | : | 0 |
| Sep 29 • 16:50 | Aryna Sabalenka | | - | | Jessica Pegula | 2 | : | 0 |
| Sep 29 • 17:00 | Petra Martic | | - | | Misaki Doi | 2 | : | 0 |
| Sep 29 • 20:10 | Pauline Parmentier | | - | | Veronika Kudermetova | 0 | : | 2 |
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| Sep 30 • 11:00 | Sara Errani | | - | | Kiki Bertens | 1 | : | 2 |
| Sep 30 • 11:00 | Elina Svitolina | | - | | Renata Zarazúa | 2 | : | 1 |
| Sep 30 • 11:00 | Astra Sharma | | - | | Ekaterina Alexandrova | 0 | : | 2 |
| Sep 30 • 11:00 | Victoria Azarenka | | - | | Anna Karolína Schmiedlová | 0 | : | 2 |
| Sep 30 • 11:00 | Nadia Podoroska | | - | | Yulia Putintseva | 2 | : | 1 |
| Sep 30 • 11:00 | Barbora Strýcová | | - | | Barbora Krejčíková | 1 | : | 2 |
| Sep 30 • 12:30 | Bernarda Pera | | - | | Amanda Anisimova | 0 | : | 2 |
| Sep 30 • 12:30 | Daria Gavrilova | | - | | Eugenie Bouchard | 1 | : | 2 |
| Sep 30 • 12:30 | Tsvetana Pironkova | | - | | Serena Williams | 0 | : | 0 |
| Sep 30 • 13:00 | Su-Wei Hsieh | | - | | Iga Świątek | 0 | : | 2 |
| Sep 30 • 13:00 | Anastasia Pavlyuchenkova | | - | | Kateřina Siniaková | 0 | : | 2 |
| Sep 30 • 15:30 | Simona Halep | | - | | Irina-Camelia Begu | 2 | : | 0 |
| Sep 30 • 15:30 | Kamilla Rakhimova | | - | | Maria Sakkari | 0 | : | 2 |
| Sep 30 • 15:30 | Kaia Kanepi | | - | | Elise Mertens | 0 | : | 2 |
| Sep 30 • 17:00 | Caroline Garcia | | - | | Aliaksandra Sasnovich | 2 | : | 0 |
| Sep 30 • 17:30 | Cori Gauff | | - | | Martina Trevisan | 1 | : | 2 |
| Oct 01 • 11:00 | Clara Tauson | | - | | Danielle Collins | 0 | : | 2 |
| Oct 01 • 11:00 | Petra Kvitova | | - | | Jasmine Paolini | 2 | : | 0 |
| Oct 01 • 11:00 | Jeļena Ostapenko | | - | | Karolina Pliskova | 2 | : | 0 |
| Oct 01 • 12:30 | Aryna Sabalenka | | - | | Daria Kasatkina | 2 | : | 0 |
| Oct 01 • 12:30 | Ana Bogdan | | - | | Sofia Kenin | 1 | : | 2 |
| Oct 01 • 12:30 | Polona Hercog | | - | | Leylah Fernandez | 1 | : | 2 |
| Oct 01 • 13:00 | Nao Hibino | | - | | Ons Jabeur | 0 | : | 2 |
| Oct 01 • 13:00 | Kristyna Pliskova | | - | | Garbine Muguruza | 0 | : | 2 |
| Oct 01 • 13:00 | Kaja Juvan | | - | | Clara Burel | 0 | : | 2 |
| Oct 01 • 13:00 | Sloane Stephens | | - | | Paula Badosa | 1 | : | 2 |
| Oct 01 • 14:40 | Laura Siegemund | | - | | Julia Görges | 2 | : | 1 |
| Oct 01 • 14:55 | Irina Maria Bara | | - | | Alison Van Uytvanck | 1 | : | 0 |
| Oct 01 • 15:25 | Patricia Maria Țig | | - | | Christina McHale | 2 | : | 0 |
| Oct 01 • 15:30 | Alize Cornet | | - | | Shuai Zhang | 0 | : | 2 |
| Oct 01 • 16:10 | Petra Martic | | - | | Veronika Kudermetova | 2 | : | 1 |
| Oct 01 • 19:20 | Elena Rybakina | | - | | Fiona Ferro | 1 | : | 2 |
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| Oct 02 • 11:00 | Eugenie Bouchard | | - | | Iga Świątek | 0 | : | 2 |
| Oct 02 • 11:00 | Elina Svitolina | | - | | Ekaterina Alexandrova | 2 | : | 0 |
| Oct 02 • 12:30 | Anna Karolína Schmiedlová | | - | | Nadia Podoroska | 0 | : | 2 |
| Oct 02 • 13:00 | Simona Halep | | - | | Amanda Anisimova | 2 | : | 0 |
| Oct 02 • 15:00 | Barbora Krejčíková | | - | | Tsvetana Pironkova | 2 | : | 1 |
| Oct 02 • 15:15 | Caroline Garcia | | - | | Elise Mertens | 2 | : | 1 |
| Oct 02 • 17:00 | Martina Trevisan | | - | | Maria Sakkari | 2 | : | 1 |
| Oct 02 • 17:25 | Kateřina Siniaková | | - | | Kiki Bertens | 0 | : | 2 |
| Oct 03 • 12:30 | Aryna Sabalenka | | - | | Ons Jabeur | 1 | : | 2 |
| Oct 03 • 13:00 | Irina Maria Bara | | - | | Sofia Kenin | 0 | : | 2 |
| Oct 03 • 13:00 | Clara Burel | | - | | Shuai Zhang | 0 | : | 2 |
| Oct 03 • 14:30 | Fiona Ferro | | - | | Patricia Maria Țig | 2 | : | 1 |
| Oct 03 • 14:30 | Petra Kvitova | | - | | Leylah Fernandez | 2 | : | 0 |
| Oct 03 • 14:30 | Petra Martic | | - | | Laura Siegemund | 1 | : | 2 |
| Oct 03 • 17:00 | Danielle Collins | | - | | Garbine Muguruza | 2 | : | 1 |
| Oct 03 • 17:00 | Paula Badosa | | - | | Jeļena Ostapenko | 2 | : | 0 |
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| Oct 04 • 11:00 | Simona Halep | | - | | Iga Świątek | 0 | : | 2 |
| Oct 04 • 11:00 | Martina Trevisan | | - | | Kiki Bertens | 2 | : | 0 |
| Oct 04 • 12:30 | Nadia Podoroska | | - | | Barbora Krejčíková | 2 | : | 1 |
| Oct 04 • 14:30 | Elina Svitolina | | - | | Caroline Garcia | 2 | : | 0 |
| Oct 05 • 11:00 | Petra Kvitova | | - | | Shuai Zhang | 2 | : | 0 |
| Oct 05 • 11:00 | Laura Siegemund | | - | | Paula Badosa | 2 | : | 0 |
| Oct 05 • 16:30 | Fiona Ferro | | - | | Sofia Kenin | 1 | : | 2 |
| Oct 06 • 11:00 | Ons Jabeur | | - | | Danielle Collins | 1 | : | 2 |
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| Oct 06 • 12:50 | Elina Svitolina | | - | | Nadia Podoroska | 0 | : | 2 |
| Oct 06 • 16:45 | Iga Świątek | | - | | Martina Trevisan | 2 | : | 0 |
| Oct 07 • 12:00 | Petra Kvitova | | - | | Laura Siegemund | 2 | : | 0 |
| Oct 07 • 13:30 | Danielle Collins | | - | | Sofia Kenin | 1 | : | 2 |
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| Oct 08 • 15:00 | Iga Świątek | | - | | Nadia Podoroska | 2 | : | 0 |
| Oct 08 • 16:30 | Sofia Kenin | | - | | Petra Kvitova | 2 | : | 0 |
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| Oct 10 • 15:00 | Iga Świątek | | - | | Sofia Kenin | 2 | : | 0 |
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