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| Jun 28 • 12:00 | Tomas Barrios Vera |  | - |  | Kevin Anderson | 1 | : | 3 |
| Jun 28 • 12:00 | Andreas Seppi |  | - |  | João Sousa | 3 | : | 1 |
| Jun 28 • 12:00 | Denis Kudla |  | - |  | Alejandro Davidovich Fokina | 3 | : | 2 |
| Jun 28 • 12:00 | Jiří Veselý |  | - |  | Yannick Hanfmann | 3 | : | 0 |
| Jun 28 • 12:00 | Márton Fucsovics |  | - | | Jannik Sinner | 3 | : | 1 |
| Jun 28 • 12:00 | Facundo Bagnis |  | - |  | Miomir Kecmanovic | 1 | : | 3 |
| Jun 28 • 12:00 | John Millman |  | - | | Roberto Bautista-Agut | 1 | : | 3 |
| Jun 28 • 13:30 | Federico Delbonis | | - |  | Andrey Rublev | 1 | : | 3 |
| Jun 28 • 13:30 | Mackenzie McDonald | | - | | Karen Khachanov | 1 | : | 3 |
| Jun 28 • 13:30 | Oscar Otte | | - |  | Arthur Rinderknech | 3 | : | 2 |
| Jun 28 • 13:30 | Reilly Opelka | | - | | Dominik Koepfer | 0 | : | 3 |
| Jun 28 • 14:30 | Novak Djokovic | | - |  | Jack Draper | 3 | : | 1 |
| Jun 28 • 15:30 | Stefanos Tsitsipas |  | - | | Frances Tiafoe | 0 | : | 3 |
| Jun 28 • 18:50 | Pedro Martínez | | - | | Stefano Travaglia | 3 | : | 1 |
| Jun 28 • 18:55 | Andy Murray | | - |  | Nikoloz Basilashvili | 3 | : | 1 |
| Jun 28 • 19:30 | Roberto Carballés Baena | | - |  | Vasek Pospisil | 0 | : | 3 |
| Jun 28 • 19:35 | Marco Cecchinato | | - | | Liam Broady | 0 | : | 3 |
| Jun 28 • 19:40 | Egor Gerasimov |  | - | | Jay Clarke | 3 | : | 1 |
| Jun 28 • 20:10 | Christopher O'Connell | | - | | Gaël Monfils | 2 | : | 3 |
| Jun 28 • 20:20 | Diego Schwartzman | | - | | Benoît Paire | 3 | : | 0 |
| Jun 28 • 20:30 | Fabio Fognini | | - | | Albert Ramos-Viñolas | 3 | : | 0 |
| Jun 28 • 20:30 | Lloyd Harris | | - |  | Ričardas Berankis | 3 | : | 0 |
| Jun 28 • 21:10 | Kwon Soon-woo |  | - | | Daniel Masur | 3 | : | 1 |
| Jun 29 • 12:00 | Daniel Evans | | - | | Feliciano López | 3 | : | 0 |
| Jun 29 • 12:00 | Dušan Lajović | | - | | Gilles Simon | 3 | : | 2 |
| Jun 29 • 12:00 | Zhang Zhizhen |  | - | | Antoine Hoang | 2 | : | 3 |
| Jun 29 • 12:00 | Sebastian Korda | | - | | Alex De Minaur | 3 | : | 1 |
| Jun 29 • 12:00 | Denis Shapovalov | | - | | Philipp Kohlschreiber | 3 | : | 2 |
| Jun 29 • 12:00 | Pierre-Hugues Herbert | | - | | Pablo Andújar | 2 | : | 3 |
| Jun 29 • 13:30 | Pablo Cuevas |  | - | | Laslo Djere | 1 | : | 3 |
| Jun 29 • 14:00 | Tallon Griekspoor |  | - | | Alexander Zverev | 0 | : | 3 |
| Jun 29 • 14:00 | Roger Federer |  | - | | Adrian Mannarino | 2 | : | 2 |
| Jun 29 • 14:00 | Richard Gasquet | | - |  | Yuichi Sugita | 3 | : | 1 |
| Jun 29 • 15:00 | Tennys Sandgren | | - |  | Norbert Gombos | 3 | : | 1 |
| Jun 29 • 18:20 | Jan-Lennard Struff | | - | | Daniil Medvedev | 1 | : | 3 |
| Jun 29 • 18:30 | Hubert Hurkacz |  | - | | Lorenzo Musetti | 3 | : | 0 |
| Jun 29 • 19:30 | Cristian Garín | | - | | Bernabe Zapata Miralles | 3 | : | 2 |
| Jun 29 • 19:30 | Marc Polmans | | - |  | Lu Yen-Hsun | 3 | : | 1 |
| Jun 29 • 19:45 | Juan Ignacio Londero | | - | | Gianluca Mager | 1 | : | 3 |
| Jun 29 • 20:00 | Filip Krajinović | | - | | Alex Bolt | 0 | : | 3 |
| Jun 29 • 20:30 | Marin Čilić |  | - | | Salvatore Caruso | 3 | : | 0 |
| Jun 29 • 20:50 | Lucas Pouille | | - | | Cameron Norrie | 1 | : | 3 |
| Jun 29 • 21:10 | Nick Kyrgios | | - | | Ugo Humbert | 3 | : | 2 |
| Jun 30 • 12:00 | Matteo Berrettini | | - | | Guido Pella | 3 | : | 1 |
| Jun 30 • 12:00 | Botic van de Zandschulp | | - | | Gregoire Barrere | 3 | : | 1 |
| Jun 30 • 12:00 | Corentin Moutet | | - |  | Aljaž Bedene | 0 | : | 3 |
| Jun 30 • 12:00 | Yoshihito Nishioka | | - | | John Isner | 3 | : | 2 |
| Jun 30 • 12:00 | Aslan Karatsev | | - | | Jérémy Chardy | 0 | : | 3 |
| Jun 30 • 12:00 | Jaume Munar | | - | | Ilya Ivashka | 0 | : | 3 |
| Jun 30 • 12:00 | Kei Nishikori | | - | | Alexei Popyrin | 3 | : | 0 |
| Jun 30 • 12:00 | Jordan Thompson | | - |  | Casper Ruud | 3 | : | 2 |
| Jun 30 • 13:30 | Jo-Wilfried Tsonga | | - |  | Mikael Ymer | 2 | : | 3 |
| Jun 30 • 13:30 | Sam Querrey | | - | | Pablo Carreño Busta | 3 | : | 0 |
| Jun 30 • 13:30 | Emil Ruusuvuori |  | - | | Marcos Giron | 2 | : | 3 |
| Jun 30 • 13:50 | Yasutaka Uchiyama | | - | | Carlos Alcaraz | 2 | : | 3 |
| Jun 30 • 13:55 | Daniel Elahi Galán |  | - | | Federico Coria | 3 | : | 1 |
| Jun 30 • 14:00 | James Duckworth | | - |  | Radu Albot | 3 | : | 0 |
| Jun 30 • 15:30 | Felix Auger Aliassime | | - |  | Thiago Moura Monteiro | 3 | : | 0 |
| Jun 30 • 15:30 | Taylor Harry Fritz | | - | | Brandon Nakashima | 3 | : | 1 |
| Jun 30 • 15:30 | Steve Johnson | | - |  | Dennis Novak | 3 | : | 0 |
| Jun 30 • 15:30 | Lorenzo Sonego | | - | | Pedro Sousa | 3 | : | 0 |
| Jun 30 • 15:30 | Mikhail Kukushkin |  | - | | Alexander Bublik | 0 | : | 3 |
| Jun 30 • 15:30 | Fernando Verdasco | | - |  | Grigor Dimitrov | 1 | : | 3 |
| Jun 30 • 15:30 | Marco Trungelliti | | - | | Benjamin Bonzi | 2 | : | 3 |
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| Jun 30 • 14:30 | Novak Djokovic | | - | | Kevin Anderson | 3 | : | 0 |
| Jun 30 • 15:00 | Denis Shapovalov | | - | | Pablo Andújar | 0 | : | 0 |
| Jun 30 • 15:30 | Daniel Evans | | - | | Dušan Lajović | 3 | : | 0 |
| Jun 30 • 16:00 | Diego Schwartzman | | - | | Liam Broady | 3 | : | 1 |
| Jun 30 • 16:30 | Andreas Seppi | | - | | Denis Kudla | 0 | : | 3 |
| Jun 30 • 17:00 | Jiří Veselý | | - | | Márton Fucsovics | 0 | : | 1 |
| Jun 30 • 17:00 | Fabio Fognini | | - | | Laslo Djere | 3 | : | 1 |
| Jun 30 • 17:00 | Frances Tiafoe | | - | | Vasek Pospisil | 3 | : | 0 |
| Jun 30 • 17:00 | Egor Gerasimov | | - | | Karen Khachanov | 0 | : | 3 |
| Jun 30 • 17:00 | Antoine Hoang | | - | | Sebastian Korda | 0 | : | 3 |
| Jun 30 • 17:30 | Miomir Kecmanovic | | - | | Roberto Bautista-Agut | 2 | : | 3 |
| Jun 30 • 18:00 | Oscar Otte | | - | | Andy Murray | 2 | : | 3 |
| Jun 30 • 19:00 | Dominik Koepfer | | - | | Kwon Soon-woo | 3 | : | 2 |
| Jun 30 • 20:15 | Lloyd Harris | | - | | Andrey Rublev | 0 | : | 3 |
| Jul 01 • 12:00 | Cristian Garín | | - | | Marc Polmans | 3 | : | 1 |
| Jul 01 • 12:00 | Aljaž Bedene | | - | | Yoshihito Nishioka | 3 | : | 0 |
| Jul 01 • 12:00 | Tennys Sandgren | | - | | Alexander Zverev | 0 | : | 3 |
| Jul 01 • 13:30 | Matteo Berrettini | | - | | Botic van de Zandschulp | 3 | : | 0 |
| Jul 01 • 13:30 | James Duckworth | | - | | Sam Querrey | 3 | : | 1 |
| Jul 01 • 13:45 | Pedro Martínez | | - | | Gaël Monfils | 3 | : | 1 |
| Jul 01 • 14:00 | Alex Bolt | | - | | Cameron Norrie | 0 | : | 3 |
| Jul 01 • 14:25 | Kei Nishikori | | - | | Jordan Thompson | 1 | : | 3 |
| Jul 01 • 14:30 | Jérémy Chardy | | - | | Ilya Ivashka | 1 | : | 3 |
| Jul 01 • 14:45 | Lorenzo Sonego | | - | | Daniel Elahi Galán | 3 | : | 1 |
| Jul 01 • 15:15 | Taylor Harry Fritz | | - | | Steve Johnson | 3 | : | 2 |
| Jul 01 • 15:30 | Alexander Bublik | | - | | Grigor Dimitrov | 3 | : | 0 |
| Jul 01 • 16:05 | Carlos Alcaraz | | - | | Daniil Medvedev | 0 | : | 3 |
| Jul 01 • 16:45 | Hubert Hurkacz | | - | | Marcos Giron | 3 | : | 0 |
| Jul 01 • 16:50 | Marin Čilić | | - | | Benjamin Bonzi | 3 | : | 1 |
| Jul 01 • 17:00 | Felix Auger Aliassime | | - | | Mikael Ymer | 3 | : | 1 |
| Jul 01 • 17:45 | Gianluca Mager | | - | | Nick Kyrgios | 0 | : | 3 |
| Jul 01 • 17:45 | Roger Federer | | - | | Richard Gasquet | 3 | : | 0 |
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| Jul 02 • 12:00 | Fabio Fognini | | - | | Andrey Rublev | 1 | : | 3 |
| Jul 02 • 12:00 | Frances Tiafoe | | - | | Karen Khachanov | 0 | : | 3 |
| Jul 02 • 13:30 | Cristian Garín | | - | | Pedro Martínez | 3 | : | 1 |
| Jul 02 • 14:30 | Diego Schwartzman | | - | | Márton Fucsovics | 1 | : | 3 |
| Jul 02 • 15:20 | Dominik Koepfer | | - | | Roberto Bautista-Agut | 0 | : | 3 |
| Jul 02 • 15:50 | Novak Djokovic | | - | | Denis Kudla | 3 | : | 0 |
| Jul 02 • 16:00 | Daniel Evans | | - | | Sebastian Korda | 1 | : | 3 |
| Jul 02 • 18:00 | Denis Shapovalov | | - | | Andy Murray | 3 | : | 0 |
| Jul 03 • 12:00 | Matteo Berrettini | | - | | Aljaž Bedene | 3 | : | 0 |
| Jul 03 • 12:00 | Ilya Ivashka | | - | | Jordan Thompson | 3 | : | 0 |
| Jul 03 • 12:00 | Lorenzo Sonego | | - | | James Duckworth | 3 | : | 0 |
| Jul 03 • 12:00 | Hubert Hurkacz | | - | | Alexander Bublik | 3 | : | 0 |
| Jul 03 • 13:30 | Taylor Harry Fritz | | - | | Alexander Zverev | 1 | : | 3 |
| Jul 03 • 15:30 | Felix Auger Aliassime | | - | | Nick Kyrgios | 1 | : | 1 |
| Jul 03 • 16:00 | Roger Federer | | - | | Cameron Norrie | 3 | : | 1 |
| Jul 03 • 17:30 | Marin Čilić | | - | | Daniil Medvedev | 2 | : | 3 |
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| Jul 05 • 12:00 | Karen Khachanov | | - | | Sebastian Korda | 3 | : | 2 |
| Jul 05 • 12:00 | Matteo Berrettini | | - | | Ilya Ivashka | 3 | : | 0 |
| Jul 05 • 13:30 | Márton Fucsovics | | - | | Andrey Rublev | 3 | : | 2 |
| Jul 05 • 13:30 | Denis Shapovalov | | - | | Roberto Bautista-Agut | 3 | : | 0 |
| Jul 05 • 14:30 | Novak Djokovic | | - | | Cristian Garín | 3 | : | 0 |
| Jul 05 • 15:30 | Felix Auger Aliassime | | - | | Alexander Zverev | 3 | : | 2 |
| Jul 05 • 15:30 | Hubert Hurkacz | | - | | Daniil Medvedev | 3 | : | 2 |
| Jul 05 • 18:30 | Roger Federer | | - | | Lorenzo Sonego | 3 | : | 0 |
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| Jul 07 • 14:00 | Karen Khachanov | | - | | Denis Shapovalov | 2 | : | 3 |
| Jul 07 • 14:30 | Novak Djokovic | | - | | Márton Fucsovics | 3 | : | 0 |
| Jul 07 • 16:00 | Matteo Berrettini | | - | | Felix Auger Aliassime | 3 | : | 1 |
| Jul 07 • 16:30 | Roger Federer | | - | | Hubert Hurkacz | 0 | : | 3 |
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| Jul 09 • 14:30 | Matteo Berrettini | | - | | Hubert Hurkacz | 3 | : | 1 |
| Jul 09 • 16:30 | Novak Djokovic | | - | | Denis Shapovalov | 3 | : | 0 |
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| Jul 11 • 15:00 | Novak Djokovic | | - | | Matteo Berrettini | 3 | : | 1 |
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