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| Nov 17 • 15:00 | Nalón CF |  | - |  | SD Solares-Medio Cudeyo | 1 | : | 1 |
| Nov 17 • 19:00 | CD Utrillas |  | - |  | CD Injerto | 2 | : | 0 |
| Nov 17 • 19:30 | CD Aldeano |  | - |  | Unami CP | 1 | : | 3 |
| Nov 17 • 19:30 | Victoria CF |  | - |  | CD Hernani | 1 | : | 0 |
| Nov 17 • 20:00 | CF San Agustín de Guadalix |  | - |  | Mora CF | 6 | : | 2 |
| Nov 17 • 20:30 | CFJ Mollerussa |  | - |  | SE Penya Independent | 1 | : | 0 |
| Nov 17 • 20:30 | CFI Alicante |  | - |  | CD Ceuta 6 de Junio | 7 | : | 1 |
| Nov 17 • 20:30 | CD Villa de Fortuna |  | - |  | CD Atlético Espeleño | 1 | : | 0 |
| Nov 17 • 21:00 | CD Huracán Melilla |  | - |  | Atarfe Industrial CF | 2 | : | 1 |
| Nov 17 • 21:30 | CD Laguna |  | - |  | CF Jaraíz | 4 | : | 1 |
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| Nov 30 • 16:00 | CD Cayón |  | - |  | SD Huesca | 0 | : | 2 |
| Nov 30 • 16:00 | CD Marchamalo |  | - |  | Real Valladolid | 0 | : | 1 |
| Nov 30 • 18:30 | Naxara CD |  | - |  | Andorra CF | 0 | : | 1 |
| Nov 30 • 19:00 | Victoria CF | | - |  | Villarreal CF | 0 | : | 8 |
| Nov 30 • 19:00 | CD Laguna | | - |  | Granada CF | 0 | : | 7 |
| Nov 30 • 19:00 | Unami CP | | - |  | Deportivo Alavés | 0 | : | 3 |
| Nov 30 • 20:00 | CD Teruel |  | - |  | AD Alcorcón | 0 | : | 1 |
| Nov 30 • 20:00 | UC Ceares |  | - |  | Sporting de Gijon | 0 | : | 1 |
| Nov 30 • 20:00 | Racing Rioja CF |  | - |  | FC Cartagena | 0 | : | 2 |
| Nov 30 • 20:30 | Atlético Sanluqueño CF |  | - |  | CE Sabadell | 2 | : | 0 |
| Nov 30 • 21:00 | CFJ Mollerussa | | - |  | Getafe CF | 1 | : | 5 |
| Nov 30 • 21:00 | CD Ebro |  | - |  | Celta de Vigo | 0 | : | 5 |
| Nov 30 • 21:00 | UD Montijo |  | - |  | Burgos CF | 0 | : | 1 |
| Nov 30 • 21:00 | Águilas FC |  | - |  | UD Almeria | 1 | : | 1 |
| Nov 30 • 21:00 | Albacete Balompié |  | - |  | Racing de Ferrol | 2 | : | 1 |
| Nov 30 • 21:00 | CD Badajoz |  | - |  | CD Alcoyano | 0 | : | 3 |
| Dec 01 • 16:30 | CD Mensajero |  | - |  | Real Zaragoza | 0 | : | 1 |
| Dec 01 • 18:30 | Bergantiños FC |  | - |  | CD Tudelano | 2 | : | 0 |
| Dec 01 • 19:00 | SD Solares-Medio Cudeyo | | - |  | RCD Espanyol | 2 | : | 3 |
| Dec 01 • 19:00 | Córdoba CF |  | - |  | Sevilla FC | 0 | : | 1 |
| Dec 01 • 19:00 | Gimnástica Segoviana |  | - |  | RCD Mallorca | 0 | : | 2 |
| Dec 01 • 19:00 | CD Brea |  | - |  | UD Ibiza | 0 | : | 2 |
| Dec 01 • 19:00 | Algeciras CF |  | - |  | UD Salamanca | 1 | : | 2 |
| Dec 01 • 20:00 | UD Alzira |  | - |  | CF Fuenlabrada | 0 | : | 1 |
| Dec 01 • 20:00 | CE Andratx |  | - |  | Real Oviedo | 2 | : | 1 |
| Dec 01 • 20:00 | AD San Juan |  | - |  | UD San Sebastián de los Reyes | 1 | : | 2 |
| Dec 01 • 20:00 | Atlético Mancha Real |  | - |  | Inter de Madrid | 2 | : | 1 |
| Dec 01 • 20:00 | UCAM Murcia |  | - |  | Deportivo La Coruña | 3 | : | 4 |
| Dec 01 • 20:15 | CF Talavera de la Reina |  | - |  | UE Cornellà | 2 | : | 0 |
| Dec 01 • 20:30 | CE Europa |  | - |  | SD Amorebieta | 0 | : | 1 |
| Dec 01 • 20:30 | CP Cacereño |  | - |  | SD Ponferradina | 1 | : | 2 |
| Dec 01 • 20:30 | CD Arenteiro |  | - |  | SD Logroñés | 2 | : | 1 |
| Dec 01 • 20:30 | CD Calahorra |  | - |  | Atlético Baleares | 1 | : | 1 |
| Dec 01 • 20:30 | Extremadura UD |  | - |  | Zamora CF | 1 | : | 4 |
| Dec 01 • 20:30 | Linares Deportivo |  | - |  | Gimnàstic de Tarragona | 0 | : | 0 |
| Dec 01 • 20:30 | San Fernando CD |  | - |  | Cultural Leonesa | 2 | : | 3 |
| Dec 01 • 21:00 | CFI Alicante | | - |  | Real Betis | 0 | : | 4 |
| Dec 01 • 21:00 | CF Panaderia Pulido |  | - |  | Real Sociedad | 0 | : | 4 |
| Dec 01 • 21:00 | CD San Roque de Lepe |  | - |  | CD Mirandés | 0 | : | 3 |
| Dec 02 • 16:00 | Velez CF |  | - |  | UD Las Palmas | 2 | : | 3 |
| Dec 02 • 19:00 | CD Huracán Melilla | | - |  | Levante UD | 0 | : | 8 |
| Dec 02 • 19:00 | CF San Agustín de Guadalix | | - |  | CA Osasuna | 0 | : | 4 |
| Dec 02 • 19:00 | CD Guijuelo |  | - |  | Rayo Vallecano | 1 | : | 1 |
| Dec 02 • 19:00 | Gernika Club |  | - |  | SD Eibar | 1 | : | 2 |
| Dec 02 • 19:30 | CD Utrillas | | - |  | Valencia CF | 0 | : | 3 |
| Dec 02 • 19:30 | Peña Sport |  | - |  | Málaga CF | 0 | : | 3 |
| Dec 02 • 20:00 | SD Leioa |  | - |  | Elche CF | 0 | : | 2 |
| Dec 02 • 20:00 | CD Puertollano |  | - |  | Girona FC | 1 | : | 5 |
| Dec 02 • 20:00 | CD Cristo Atletico |  | - |  | Real Unión | 2 | : | 0 |
| Dec 02 • 20:00 | CA Pulpileño |  | - |  | CD Castellón | 0 | : | 1 |
| Dec 02 • 20:00 | UD Llanera |  | - |  | UD Logroñés | 2 | : | 1 |
| Dec 02 • 20:15 | Unión Adarve |  | - |  | CD Lugo | 2 | : | 2 |
| Dec 02 • 20:30 | CD Eldense |  | - |  | Rayo Majadahonda | 0 | : | 1 |
| Dec 02 • 20:45 | Xerez Deportivo FC |  | - |  | CD Leganés | 1 | : | 2 |
| Dec 02 • 21:00 | CD Villa de Fortuna | | - |  | Cádiz CF | 0 | : | 7 |
| Dec 02 • 21:00 | CD Ibiza Islas Pitiusas |  | - |  | CD Tenerife | 1 | : | 2 |
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| Dec 14 • 19:00 | Andorra CF | | - | | Celta de Vigo | 1 | : | 2 |
| Dec 14 • 19:00 | UD San Sebastián de los Reyes | | - | | CF Fuenlabrada | 0 | : | 0 |
| Dec 14 • 20:00 | SD Huesca | | - | | Girona FC | 0 | : | 1 |
| Dec 14 • 20:00 | Real Zaragoza | | - | | Burgos CF | 2 | : | 0 |
| Dec 14 • 20:00 | Rayo Majadahonda | | - | | Málaga CF | 1 | : | 0 |
| Dec 14 • 21:00 | CD Cristo Atletico | | - | | RCD Espanyol | 1 | : | 2 |
| Dec 14 • 21:00 | CD Alcoyano | | - | | Levante UD | 3 | : | 3 |
| Dec 14 • 21:00 | Linares Deportivo | | - | | Deportivo Alavés | 2 | : | 1 |
| Dec 15 • 19:00 | Bergantiños FC | | - | | Rayo Vallecano | 1 | : | 3 |
| Dec 15 • 19:00 | CE Andratx | | - | | Sevilla FC | 1 | : | 1 |
| Dec 15 • 19:00 | Zamora CF | | - | | Real Sociedad | 0 | : | 3 |
| Dec 15 • 19:30 | Cultural Leonesa | | - | | CD Leganés | 2 | : | 3 |
| Dec 15 • 20:00 | Sporting de Gijon | | - | | AD Alcorcón | 2 | : | 1 |
| Dec 15 • 20:00 | SD Ponferradina | | - | | UD Ibiza | 2 | : | 1 |
| Dec 15 • 20:00 | Real Valladolid | | - | | UD Las Palmas | 3 | : | 1 |
| Dec 15 • 20:00 | CD Castellón | | - | | FC Cartagena | 1 | : | 2 |
| Dec 15 • 21:00 | UD Salamanca | | - | | Elche CF | 0 | : | 1 |
| Dec 15 • 21:00 | CD Tenerife | | - | | SD Eibar | 1 | : | 2 |
| Dec 15 • 21:00 | Atlético Sanluqueño CF | | - | | Villarreal CF | 1 | : | 7 |
| Dec 16 • 19:00 | CF Talavera de la Reina | | - | | Real Betis | 2 | : | 4 |
| Dec 16 • 19:00 | UD Llanera | | - | | RCD Mallorca | 0 | : | 6 |
| Dec 16 • 19:00 | CD Arenteiro | | - | | Valencia CF | 1 | : | 3 |
| Dec 16 • 19:00 | SD Amorebieta | | - | | UD Almeria | 1 | : | 2 |
| Dec 16 • 20:00 | CD Lugo | | - | | CD Mirandés | 1 | : | 2 |
| Dec 16 • 21:00 | Deportivo La Coruña | | - | | CA Osasuna | 1 | : | 2 |
| Dec 16 • 21:00 | Atlético Mancha Real | | - | | Granada CF | 1 | : | 0 |
| Dec 16 • 21:00 | Albacete Balompié | | - | | Cádiz CF | 0 | : | 1 |
| Dec 16 • 21:00 | Atlético Baleares | | - | | Getafe CF | 5 | : | 0 |
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| Jan 04 • 21:00 | SD Ponferradina | | - | | RCD Espanyol | 1 | : | 1 |
| Jan 05 • 16:00 | SD Eibar | | - | | RCD Mallorca | 1 | : | 2 |
| Jan 05 • 16:00 | CD Leganés | | - | | Real Sociedad | 2 | : | 3 |
| Jan 05 • 16:00 | FC Cartagena | | - | | Valencia CF | 1 | : | 2 |
| Jan 05 • 19:30 | Linares Deportivo | | - |  | FC Barcelona | 1 | : | 2 |
| Jan 05 • 20:00 | Atlético Baleares | | - | | Celta de Vigo | 2 | : | 1 |
| Jan 05 • 20:00 | CD Mirandés | | - | | Rayo Vallecano | 0 | : | 1 |
| Jan 05 • 20:00 | Real Valladolid | | - | | Real Betis | 0 | : | 3 |
| Jan 05 • 21:30 | CD Alcoyano | | - |  | Real Madrid | 1 | : | 3 |
| Jan 06 • 16:00 | CF Fuenlabrada | | - | | Cádiz CF | 0 | : | 1 |
| Jan 06 • 16:00 | Girona FC | | - | | CA Osasuna | 1 | : | 0 |
| Jan 06 • 18:00 | Sporting de Gijon | | - | | Villarreal CF | 2 | : | 1 |
| Jan 06 • 18:00 | Real Zaragoza | | - | | Sevilla FC | 0 | : | 2 |
| Jan 06 • 20:00 | UD Almeria | | - | | Elche CF | 1 | : | 2 |
| Jan 06 • 20:00 | Atlético Mancha Real | | - |  | Athletic Bilbao | 0 | : | 2 |
| Jan 06 • 21:30 | Rayo Majadahonda | | - |  | Atlético Madrid | 0 | : | 5 |
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| Jan 15 • 16:00 | RCD Mallorca | | - | | RCD Espanyol | 2 | : | 1 |
| Jan 15 • 18:30 | Sporting de Gijon | | - | | Cádiz CF | 0 | : | 0 |
| Jan 15 • 18:30 | Girona FC | | - | | Rayo Vallecano | 1 | : | 2 |
| Jan 15 • 21:30 | Real Betis | | - | | Sevilla FC | 2 | : | 1 |
| Jan 16 • 12:00 | Atlético Baleares | | - | | Valencia CF | 0 | : | 1 |
| Jan 19 • 21:00 | Real Sociedad | | - | | Atlético Madrid | 2 | : | 0 |
| Jan 20 • 19:00 | Elche CF | | - | | Real Madrid | 1 | : | 2 |
| Jan 20 • 21:30 | Athletic Bilbao | | - | | FC Barcelona | 3 | : | 2 |
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| Feb 02 • 20:00 | Rayo Vallecano | | - | | RCD Mallorca | 1 | : | 0 |
| Feb 02 • 21:00 | Valencia CF | | - | | Cádiz CF | 2 | : | 1 |
| Feb 03 • 20:00 | Real Sociedad | | - | | Real Betis | 0 | : | 4 |
| Feb 03 • 21:30 | Athletic Bilbao | | - | | Real Madrid | 1 | : | 0 |
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| Feb 09 • 21:00 | Rayo Vallecano | | - | | Real Betis | 1 | : | 2 |
| Feb 10 • 21:30 | Athletic Bilbao | | - | | Valencia CF | 1 | : | 1 |
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| Mar 02 • 21:30 | Valencia CF | | - | | Athletic Bilbao | 1 | : | 0 |
| Mar 03 • 21:00 | Real Betis | | - | | Rayo Vallecano | 1 | : | 1 |
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| Apr 23 • 22:00 | Real Betis | | - | | Valencia CF | 1 | : | 1 |
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