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| Aug 30 • 17:00 | Feliciano López |  | - | | Bernabe Zapata Miralles | 2 | : | 3 |
| Aug 30 • 17:00 | Evgeny Donskoy |  | - |  | Felix Auger Aliassime | 1 | : | 3 |
| Aug 30 • 17:00 | Henri Laaksonen |  | - |  | John Millman | 3 | : | 0 |
| Aug 30 • 17:00 | Dušan Lajović |  | - |  | Benoît Paire | 3 | : | 1 |
| Aug 30 • 17:00 | Peter Gojowczyk |  | - | | Ugo Humbert | 3 | : | 2 |
| Aug 30 • 17:00 | Facundo Bagnis |  | - |  | Taro Daniel | 3 | : | 0 |
| Aug 30 • 17:00 | Jiří Veselý |  | - |  | Kevin Anderson | 2 | : | 3 |
| Aug 30 • 17:00 | Ričardas Berankis |  | - | | Diego Schwartzman | 0 | : | 3 |
| Aug 30 • 17:00 | Thiago Moura Monteiro |  | - |  | Daniel Evans | 1 | : | 3 |
| Aug 30 • 18:30 | Marin Čilić |  | - | | Philipp Kohlschreiber | 2 | : | 2 |
| Aug 30 • 19:00 | Andrey Rublev | | - | | Ivo Karlović | 3 | : | 0 |
| Aug 30 • 19:15 | Pedro Martínez | | - | | James Duckworth | 3 | : | 2 |
| Aug 30 • 19:15 | Cristian Garín |  | - |  | Norbert Gombos | 3 | : | 1 |
| Aug 30 • 19:40 | Mikhail Kukushkin |  | - | | Pablo Andújar | 2 | : | 3 |
| Aug 30 • 19:45 | John Isner |  | - | | Brandon Nakashima | 0 | : | 3 |
| Aug 30 • 20:00 | Marcos Giron | | - | | Antoine Hoang | 3 | : | 0 |
| Aug 30 • 20:25 | Pierre-Hugues Herbert | | - | | Adrian Mannarino | 2 | : | 3 |
| Aug 30 • 20:40 | Andy Murray | | - |  | Stefanos Tsitsipas | 2 | : | 3 |
| Aug 30 • 20:55 | Casper Ruud |  | - | | Yuichi Sugita | 3 | : | 0 |
| Aug 30 • 21:15 | Grigor Dimitrov |  | - | | Sam Riffice | 3 | : | 0 |
| Aug 30 • 21:50 | Marco Trungelliti | | - | | Alejandro Davidovich Fokina | 3 | : | 2 |
| Aug 30 • 22:45 | Alex Molcan | | - |  | Cem Ilkel | 3 | : | 1 |
| Aug 30 • 23:05 | Botic van de Zandschulp |  | - | | Carlos Taberner | 3 | : | 2 |
| Aug 30 • 23:15 | Kamil Majchrzak |  | - |  | Emil Ruusuvuori | 1 | : | 3 |
| Aug 30 • 23:35 | Miomir Kecmanovic | | - | | Arthur Rinderknech | 2 | : | 3 |
| Aug 30 • 23:50 | Alexei Popyrin | | - |  | Radu Albot | 3 | : | 1 |
| Aug 31 • 00:30 | Dominik Koepfer | | - | | Quentin Halys | 3 | : | 2 |
| Aug 31 • 00:40 | Cameron Norrie | | - | | Carlos Alcaraz | 0 | : | 3 |
| Aug 31 • 01:00 | Frances Tiafoe | | - | | Christopher Eubanks | 3 | : | 1 |
| Aug 31 • 01:00 | Guido Pella | | - | | Filip Krajinović | 3 | : | 1 |
| Aug 31 • 02:15 | Roberto Bautista-Agut | | - | | Nick Kyrgios | 3 | : | 0 |
| Aug 31 • 02:45 | Richard Gasquet | | - | | Daniil Medvedev | 0 | : | 3 |
| Aug 31 • 17:00 | Salvatore Caruso |  | - | | Kei Nishikori | 1 | : | 3 |
| Aug 31 • 17:00 | Mackenzie McDonald | | - |  | David Goffin | 3 | : | 0 |
| Aug 31 • 17:00 | Aslan Karatsev | | - | | Jaume Munar | 3 | : | 1 |
| Aug 31 • 17:00 | Denis Kudla | | - | | Laslo Djere | 3 | : | 1 |
| Aug 31 • 17:00 | Albert Ramos-Viñolas | | - | | Lucas Pouille | 3 | : | 2 |
| Aug 31 • 17:00 | Lorenzo Musetti | | - | | Emilio Nava | 3 | : | 1 |
| Aug 31 • 17:00 | Kwon Soon-woo |  | - | | Reilly Opelka | 0 | : | 3 |
| Aug 31 • 17:00 | Karen Khachanov | | - | | Lloyd Harris | 2 | : | 3 |
| Aug 31 • 17:00 | Pablo Cuevas |  | - | | Ernesto Escobedo | 0 | : | 3 |
| Aug 31 • 18:00 | Alexander Zverev | | - | | Sam Querrey | 3 | : | 0 |
| Aug 31 • 18:15 | Hubert Hurkacz | | - |  | Egor Gerasimov | 3 | : | 0 |
| Aug 31 • 18:15 | Andreas Seppi | | - |  | Márton Fucsovics | 3 | : | 2 |
| Aug 31 • 18:15 | Yannick Hanfmann | | - | | Alexander Bublik | 1 | : | 3 |
| Aug 31 • 20:00 | Jérémy Chardy | | - | | Matteo Berrettini | 0 | : | 3 |
| Aug 31 • 20:15 | Oscar Otte | | - | | Lorenzo Sonego | 3 | : | 1 |
| Aug 31 • 20:20 | Pablo Carreño Busta | | - | | Maxime Cressy | 2 | : | 3 |
| Aug 31 • 20:35 | Max Purcell | | - | | Jannik Sinner | 1 | : | 3 |
| Aug 31 • 20:40 | Federico Delbonis | | - | | Denis Shapovalov | 0 | : | 3 |
| Aug 31 • 20:50 | Jordan Thompson | | - | | Gianluca Mager | 3 | : | 2 |
| Aug 31 • 20:50 | Sebastian Korda | | - |  | Nikoloz Basilashvili | 0 | : | 1 |
| Aug 31 • 21:05 | Corentin Moutet | | - | | Stefano Travaglia | 3 | : | 0 |
| Aug 31 • 21:05 | Roberto Carballés Baena | | - | | Tommy Paul | 3 | : | 1 |
| Aug 31 • 21:15 | Gaël Monfils | | - | | Federico Coria | 3 | : | 0 |
| Aug 31 • 21:30 | Tallon Griekspoor | | - | | Jan-Lennard Struff | 3 | : | 2 |
| Aug 31 • 22:00 | Yoshihito Nishioka | | - | | Jack Sock | 1 | : | 3 |
| Aug 31 • 22:05 | Steve Johnson | | - | | Maximilian Marterer | 3 | : | 1 |
| Aug 31 • 23:20 | Fabio Fognini | | - | | Vasek Pospisil | 2 | : | 3 |
| Aug 31 • 23:20 | Tennys Sandgren | | - | | Ilya Ivashka | 0 | : | 3 |
| Aug 31 • 23:20 | Marco Cecchinato | | - | | Zachary Svajda | 1 | : | 3 |
| Aug 31 • 23:55 | Jenson Brooksby | | - |  | Mikael Ymer | 3 | : | 1 |
| Sep 01 • 01:00 | Novak Djokovic | | - |  | Holger Rune | 3 | : | 1 |
| Sep 01 • 02:15 | Taylor Harry Fritz | | - | | Alex De Minaur | 3 | : | 1 |
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| Sep 01 • 17:00 | Andrey Rublev | | - | | Pedro Martínez | 3 | : | 1 |
| Sep 01 • 17:00 | Cristian Garín | | - | | Henri Laaksonen | 1 | : | 3 |
| Sep 01 • 17:00 | Dušan Lajović | | - | | Peter Gojowczyk | 2 | : | 3 |
| Sep 01 • 17:00 | Carlos Alcaraz | | - | | Arthur Rinderknech | 3 | : | 1 |
| Sep 01 • 17:00 | Casper Ruud | | - | | Botic van de Zandschulp | 1 | : | 3 |
| Sep 01 • 17:00 | Facundo Bagnis | | - | | Marco Trungelliti | 3 | : | 1 |
| Sep 01 • 17:00 | Brandon Nakashima | | - | | Alex Molcan | 2 | : | 3 |
| Sep 01 • 17:00 | Grigor Dimitrov | | - | | Alexei Popyrin | 0 | : | 2 |
| Sep 01 • 17:00 | Marcos Giron | | - | | Daniel Evans | 1 | : | 3 |
| Sep 01 • 17:00 | Philipp Kohlschreiber | | - | | Pablo Andújar | 0 | : | 3 |
| Sep 01 • 19:40 | Dominik Koepfer | | - | | Daniil Medvedev | 0 | : | 3 |
| Sep 01 • 20:00 | Bernabe Zapata Miralles | | - | | Felix Auger Aliassime | 0 | : | 3 |
| Sep 01 • 20:35 | Roberto Bautista-Agut | | - | | Emil Ruusuvuori | 3 | : | 0 |
| Sep 01 • 21:00 | Frances Tiafoe | | - | | Guido Pella | 3 | : | 0 |
| Sep 02 • 01:00 | Kevin Anderson | | - | | Diego Schwartzman | 0 | : | 3 |
| Sep 02 • 02:15 | Adrian Mannarino | | - | | Stefanos Tsitsipas | 1 | : | 3 |
| Sep 02 • 17:00 | Lorenzo Musetti | | - | | Reilly Opelka | 0 | : | 3 |
| Sep 02 • 19:40 | Aslan Karatsev | | - | | Jordan Thompson | 3 | : | 2 |
| Sep 02 • 19:45 | Corentin Moutet | | - | | Matteo Berrettini | 1 | : | 3 |
| Sep 02 • 19:45 | Maxime Cressy | | - | | Nikoloz Basilashvili | 0 | : | 3 |
| Sep 02 • 19:50 | Vasek Pospisil | | - | | Ilya Ivashka | 0 | : | 3 |
| Sep 02 • 20:05 | Alexander Zverev | | - | | Albert Ramos-Viñolas | 3 | : | 0 |
| Sep 02 • 20:30 | Hubert Hurkacz | | - | | Andreas Seppi | 1 | : | 3 |
| Sep 02 • 20:55 | Denis Kudla | | - | | Oscar Otte | 0 | : | 3 |
| Sep 02 • 21:15 | Gaël Monfils | | - | | Steve Johnson | 3 | : | 1 |
| Sep 02 • 21:30 | Lloyd Harris | | - | | Ernesto Escobedo | 3 | : | 0 |
| Sep 02 • 22:15 | Kei Nishikori | | - | | Mackenzie McDonald | 3 | : | 2 |
| Sep 02 • 22:40 | Zachary Svajda | | - | | Jannik Sinner | 1 | : | 3 |
| Sep 02 • 23:15 | Jenson Brooksby | | - | | Taylor Harry Fritz | 3 | : | 1 |
| Sep 02 • 23:15 | Jack Sock | | - | | Alexander Bublik | 3 | : | 2 |
| Sep 03 • 01:00 | Novak Djokovic | | - | | Tallon Griekspoor | 3 | : | 0 |
| Sep 03 • 02:30 | Roberto Carballés Baena | | - | | Denis Shapovalov | 0 | : | 3 |
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| Sep 03 • 17:00 | Henri Laaksonen | | - | | Peter Gojowczyk | 1 | : | 3 |
| Sep 03 • 18:30 | Alexei Popyrin | | - | | Daniel Evans | 2 | : | 3 |
| Sep 03 • 19:50 | Pablo Andújar | | - | | Daniil Medvedev | 0 | : | 3 |
| Sep 03 • 20:15 | Carlos Alcaraz | | - | | Stefanos Tsitsipas | 3 | : | 2 |
| Sep 03 • 21:40 | Botic van de Zandschulp | | - | | Facundo Bagnis | 3 | : | 1 |
| Sep 03 • 23:00 | Alex Molcan | | - | | Diego Schwartzman | 0 | : | 3 |
| Sep 04 • 01:00 | Roberto Bautista-Agut | | - | | Felix Auger Aliassime | 2 | : | 3 |
| Sep 04 • 02:30 | Andrey Rublev | | - | | Frances Tiafoe | 2 | : | 3 |
| Sep 04 • 17:00 | Ilya Ivashka | | - | | Matteo Berrettini | 2 | : | 3 |
| Sep 04 • 18:00 | Andreas Seppi | | - | | Oscar Otte | 1 | : | 3 |
| Sep 04 • 19:30 | Novak Djokovic | | - | | Kei Nishikori | 3 | : | 1 |
| Sep 04 • 20:00 | Gaël Monfils | | - | | Jannik Sinner | 2 | : | 3 |
| Sep 04 • 22:20 | Aslan Karatsev | | - | | Jenson Brooksby | 2 | : | 3 |
| Sep 04 • 23:00 | Nikoloz Basilashvili | | - | | Reilly Opelka | 0 | : | 3 |
| Sep 05 • 01:00 | Lloyd Harris | | - | | Denis Shapovalov | 3 | : | 0 |
| Sep 05 • 02:30 | Alexander Zverev | | - | | Jack Sock | 2 | : | 1 |
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| Sep 05 • 17:00 | Botic van de Zandschulp | | - | | Diego Schwartzman | 3 | : | 2 |
| Sep 05 • 19:30 | Daniel Evans | | - | | Daniil Medvedev | 0 | : | 3 |
| Sep 06 • 00:00 | Peter Gojowczyk | | - | | Carlos Alcaraz | 2 | : | 3 |
| Sep 06 • 01:10 | Frances Tiafoe | | - | | Felix Auger Aliassime | 1 | : | 3 |
| Sep 06 • 18:00 | Alexander Zverev | | - | | Jannik Sinner | 3 | : | 0 |
| Sep 06 • 19:00 | Reilly Opelka | | - | | Lloyd Harris | 1 | : | 3 |
| Sep 06 • 21:40 | Oscar Otte | | - | | Matteo Berrettini | 1 | : | 3 |
| Sep 07 • 01:00 | Novak Djokovic | | - | | Jenson Brooksby | 3 | : | 1 |
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| Sep 07 • 18:00 | Botic van de Zandschulp | | - | | Daniil Medvedev | 1 | : | 3 |
| Sep 08 • 02:30 | Felix Auger Aliassime | | - | | Carlos Alcaraz | 1 | : | 0 |
| Sep 08 • 19:30 | Alexander Zverev | | - | | Lloyd Harris | 3 | : | 0 |
| Sep 09 • 02:30 | Novak Djokovic | | - | | Matteo Berrettini | 3 | : | 1 |
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| Sep 10 • 21:00 | Felix Auger Aliassime | | - | | Daniil Medvedev | 0 | : | 3 |
| Sep 11 • 00:00 | Novak Djokovic | | - | | Alexander Zverev | 3 | : | 2 |
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| Sep 12 • 22:00 | Novak Djokovic | | - | | Daniil Medvedev | 0 | : | 3 |
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