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| Oct 25 • 14:00 | Nikoloz Basilashvili |  | - |  | Pablo Carreño Busta | 2 | : | 1 |
| Oct 25 • 15:20 | Carlos Alcaraz | | - |  | Daniel Evans | 2 | : | 0 |
| Oct 25 • 16:40 | Alex De Minaur |  | - |  | Kevin Anderson | 2 | : | 0 |
| Oct 25 • 17:30 | Hubert Hurkacz |  | - | | Andy Murray | 1 | : | 2 |
| Oct 25 • 18:50 | Alexei Popyrin | | - |  | Matteo Berrettini | 0 | : | 2 |
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| Oct 26 • 13:00 | Felix Auger Aliassime |  | - |  | Ričardas Berankis | 2 | : | 0 |
| Oct 26 • 14:00 | Casper Ruud |  | - | | Lloyd Harris | 2 | : | 0 |
| Oct 26 • 14:20 | Cameron Norrie | | - |  | Márton Fucsovics | 2 | : | 0 |
| Oct 26 • 15:20 | Stefanos Tsitsipas |  | - |  | Grigor Dimitrov | 2 | : | 0 |
| Oct 26 • 15:40 | Dušan Lajović |  | - |  | Frances Tiafoe | 0 | : | 2 |
| Oct 26 • 17:30 | Filip Krajinović | | - |  | Alexander Zverev | 0 | : | 2 |
| Oct 26 • 18:50 | Dennis Novak |  | - | | Gianluca Mager | 2 | : | 0 |
| Oct 27 • 13:30 | Lorenzo Sonego | | - | | Dominik Koepfer | 2 | : | 0 |
| Oct 27 • 14:00 | Reilly Opelka | | - | | Jannik Sinner | 0 | : | 2 |
| Oct 27 • 14:40 | Fabio Fognini | | - |  | Diego Schwartzman | 0 | : | 2 |
| Oct 27 • 15:20 | Gaël Monfils |  | - | | Lorenzo Musetti | 2 | : | 0 |
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| Oct 27 • 17:30 | Andy Murray | | - | | Carlos Alcaraz | 0 | : | 2 |
| Oct 27 • 18:50 | Nikoloz Basilashvili | | - | | Matteo Berrettini | 1 | : | 2 |
| Oct 28 • 13:00 | Felix Auger Aliassime | | - | | Cameron Norrie | 2 | : | 1 |
| Oct 28 • 14:00 | Gaël Monfils | | - | | Diego Schwartzman | 1 | : | 2 |
| Oct 28 • 14:20 | Casper Ruud | | - | | Lorenzo Sonego | 2 | : | 1 |
| Oct 28 • 15:20 | Dennis Novak | | - | | Jannik Sinner | 0 | : | 2 |
| Oct 28 • 17:30 | Alex De Minaur | | - | | Alexander Zverev | 1 | : | 2 |
| Oct 28 • 19:50 | Stefanos Tsitsipas | | - | | Frances Tiafoe | 1 | : | 2 |
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| Oct 29 • 14:00 | Carlos Alcaraz | | - | | Matteo Berrettini | 2 | : | 1 |
| Oct 29 • 15:30 | Felix Auger Aliassime | | - | | Alexander Zverev | 1 | : | 2 |
| Oct 29 • 17:30 | Frances Tiafoe | | - | | Diego Schwartzman | 2 | : | 0 |
| Oct 29 • 18:50 | Casper Ruud | | - | | Jannik Sinner | 0 | : | 2 |
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| Oct 30 • 14:00 | Carlos Alcaraz | | - | | Alexander Zverev | 0 | : | 2 |
| Oct 30 • 15:30 | Frances Tiafoe | | - | | Jannik Sinner | 2 | : | 1 |
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| Oct 31 • 14:00 | Frances Tiafoe | | - | | Alexander Zverev | 0 | : | 2 |
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