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| Oct 19 • 19:30 | CD Amigó |  | - |  | CD Fuentes | 0 | : | 3 |
| Oct 19 • 19:30 | CD Ceuta 6 de Junio |  | - |  | CD l'Alcora | 0 | : | 3 |
| Oct 19 • 20:00 | Velarde CF |  | - |  | Turégano CF | 1 | : | 0 |
| Oct 19 • 20:00 | CD Autol |  | - |  | Dinamo San Juan | 1 | : | 1 |
| Oct 19 • 20:00 | CD Algar |  | - |  | Melilla CD | 4 | : | 1 |
| Oct 19 • 20:00 | CD Santa Amalia |  | - |  | Universitario FC | 2 | : | 1 |
| Oct 19 • 20:30 | UD Barbadás |  | - |  | Atlético de Lugones | 2 | : | 1 |
| Oct 19 • 20:30 | CFJ Mollerussa |  | - |  | CE Cardassar | 4 | : | 2 |
| Oct 19 • 20:30 | Montilla CF |  | - |  | CD Rincón | 0 | : | 0 |
| Oct 19 • 20:30 | CD Cazalegas |  | - |  | CD Los Yébenes-San Bruno | 2 | : | 1 |
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| Nov 12 • 16:00 | CD Fuentes | | - |  | CA Osasuna | 1 | : | 4 |
| Nov 12 • 16:00 | UD Barbadás | | - |  | Real Valladolid | 0 | : | 2 |
| Nov 12 • 16:00 | CE Manacor |  | - |  | Andorra CF | 1 | : | 3 |
| Nov 12 • 17:00 | Atlético Saguntino |  | - |  | SD Amorebieta | 1 | : | 0 |
| Nov 12 • 17:00 | CDA Navalcarnero |  | - |  | UD Logroñés | 1 | : | 3 |
| Nov 12 • 17:00 | UE Olot |  | - |  | Levante UD | 0 | : | 4 |
| Nov 12 • 17:00 | CD Guijuelo |  | - |  | Deportivo La Coruña | 2 | : | 0 |
| Nov 12 • 18:00 | CD Huétor Tájar |  | - |  | Albacete Balompié | 0 | : | 3 |
| Nov 12 • 18:00 | CD Guadalajara |  | - |  | SD Ponferradina | 2 | : | 1 |
| Nov 12 • 18:00 | Gernika Club |  | - |  | CD Leganés | 0 | : | 0 |
| Nov 12 • 18:00 | Arenas Club de Getxo |  | - |  | CD Lugo | 1 | : | 0 |
| Nov 12 • 18:00 | SD Beasain |  | - |  | Sporting de Gijon | 2 | : | 3 |
| Nov 12 • 18:00 | Racing Rioja CF |  | - |  | Gimnàstic de Tarragona | 0 | : | 2 |
| Nov 12 • 18:00 | Sestao River Club |  | - |  | Racing de Ferrol | 1 | : | 0 |
| Nov 12 • 18:00 | CD Utrera |  | - |  | AD Ceuta FC | 0 | : | 1 |
| Nov 12 • 18:30 | CD l'Alcora | | - |  | Elche CF | 0 | : | 3 |
| Nov 12 • 18:30 | CD Autol | | - |  | RCD Mallorca | 0 | : | 6 |
| Nov 12 • 20:00 | CD Cristo Atletico |  | - |  | UD Ibiza | 0 | : | 2 |
| Nov 12 • 20:00 | CD Coria |  | - |  | CF Fuenlabrada | 2 | : | 0 |
| Nov 12 • 20:00 | CP Cacereño |  | - |  | Córdoba CF | 3 | : | 0 |
| Nov 12 • 21:00 | CD Santa Amalia | | - |  | Villarreal CF | 0 | : | 9 |
| Nov 12 • 21:00 | CD Rincón | | - |  | RCD Espanyol | 0 | : | 3 |
| Nov 12 • 22:00 | SD Almazán |  | - |  | Atlético Madrid | 0 | : | 2 |
| Nov 13 • 12:00 | CFJ Mollerussa | | - |  | Rayo Vallecano | 1 | : | 3 |
| Nov 13 • 12:00 | CD Quintanar del Rey |  | - |  | Girona FC | 1 | : | 2 |
| Nov 13 • 12:00 | CF Vimenor |  | - |  | CD Mirandés | 0 | : | 2 |
| Nov 13 • 12:00 | CD Lealtad |  | - |  | CD Tenerife | 0 | : | 2 |
| Nov 13 • 12:00 | Las Rozas CF |  | - |  | SD Eibar | 0 | : | 3 |
| Nov 13 • 12:00 | SCR Peña Deportiva |  | - |  | Málaga CF | 1 | : | 1 |
| Nov 13 • 12:00 | CD Alfaro |  | - |  | FC Cartagena | 0 | : | 1 |
| Nov 13 • 12:00 | Recreativo Huelva |  | - |  | Burgos CF | 0 | : | 0 |
| Nov 13 • 12:00 | Gimnástica de Torrelavega |  | - |  | Real Oviedo | 2 | : | 3 |
| Nov 13 • 12:00 | CD Colegios Diocesanos |  | - |  | Real Zaragoza | 1 | : | 0 |
| Nov 13 • 12:00 | Juventud de Torremolinos CF |  | - |  | SD Huesca | 2 | : | 2 |
| Nov 13 • 12:00 | CD Atlético Paso |  | - |  | Real Murcia | 1 | : | 1 |
| Nov 13 • 12:00 | CE Manresa |  | - |  | Pontevedra CF | 1 | : | 3 |
| Nov 13 • 12:00 | CD Arnedo |  | - |  | Atlético Baleares | 1 | : | 1 |
| Nov 13 • 12:00 | Unión Adarve |  | - |  | Linares Deportivo | 1 | : | 2 |
| Nov 13 • 12:00 | CD Ibiza Islas Pitiusas |  | - |  | Rayo Majadahonda | 3 | : | 1 |
| Nov 13 • 12:00 | Hércules CF |  | - |  | CF La Nucía | 2 | : | 4 |
| Nov 13 • 16:00 | Velarde CF | | - |  | Sevilla FC | 0 | : | 2 |
| Nov 13 • 16:00 | CD Algar | | - |  | Celta de Vigo | 1 | : | 6 |
| Nov 13 • 16:00 | CA Cirbonero |  | - |  | CF Intercity Sant Joan d'Alacant | 0 | : | 1 |
| Nov 13 • 16:30 | CD Teruel |  | - |  | UD Las Palmas | 0 | : | 1 |
| Nov 13 • 17:00 | Coruxo FC |  | - |  | CD Eldense | 2 | : | 2 |
| Nov 13 • 17:00 | AD San Juan |  | - |  | CD Numancia | 0 | : | 2 |
| Nov 13 • 17:00 | Ourense CF |  | - |  | AD Alcorcón | 1 | : | 1 |
| Nov 13 • 17:00 | Yeclano Deportivo |  | - |  | Granada CF | 2 | : | 3 |
| Nov 13 • 18:00 | Lleida CF |  | - |  | Deportivo Alavés | 0 | : | 1 |
| Nov 13 • 18:00 | Utebo FC |  | - |  | Mérida AD | 2 | : | 2 |
| Nov 13 • 18:30 | Real Unión |  | - |  | Cádiz CF | 3 | : | 2 |
| Nov 13 • 18:30 | CD San Roque de Lepe |  | - |  | Getafe CF | 2 | : | 3 |
| Nov 13 • 19:00 | CD Cazalegas | | - |  | Real Sociedad | 1 | : | 4 |
| Nov 13 • 21:00 | CD Arenteiro |  | - |  | UD Almeria | 2 | : | 0 |
| Nov 13 • 21:00 | UD Alzira |  | - |  | Athletic Bilbao | 0 | : | 2 |
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| Dec 20 • 19:00 | CD Guadalajara | | - | | Elche CF | 0 | : | 3 |
| Dec 20 • 19:00 | CD Colegios Diocesanos | | - | | Getafe CF | 0 | : | 2 |
| Dec 20 • 19:00 | CF Intercity Sant Joan d'Alacant | | - | | CD Mirandés | 2 | : | 0 |
| Dec 20 • 21:00 | Real Unión | | - | | RCD Mallorca | 0 | : | 1 |
| Dec 20 • 21:00 | Sestao River Club | | - | | Athletic Bilbao | 0 | : | 1 |
| Dec 20 • 21:00 | CD Guijuelo | | - | | Villarreal CF | 1 | : | 2 |
| Dec 20 • 21:00 | AD Alcorcón | | - | | FC Cartagena | 1 | : | 1 |
| Dec 20 • 22:00 | CD Atlético Paso | | - | | RCD Espanyol | 0 | : | 1 |
| Dec 21 • 19:00 | Atlético Saguntino | | - | | Rayo Vallecano | 0 | : | 0 |
| Dec 21 • 19:00 | CD Ibiza Islas Pitiusas | | - | | SD Eibar | 1 | : | 0 |
| Dec 21 • 19:00 | Mérida AD | | - | | Deportivo Alavés | 0 | : | 1 |
| Dec 21 • 19:00 | CD Numancia | | - | | Sporting de Gijon | 0 | : | 3 |
| Dec 21 • 19:00 | Levante UD | | - | | Andorra CF | 2 | : | 1 |
| Dec 21 • 21:00 | Arenas Club de Getxo | | - | | Real Valladolid | 1 | : | 5 |
| Dec 21 • 21:00 | Juventud de Torremolinos CF | | - | | Sevilla FC | 0 | : | 3 |
| Dec 21 • 21:00 | CD Arnedo | | - | | CA Osasuna | 1 | : | 3 |
| Dec 21 • 21:00 | CD Coria | | - | | Real Sociedad | 0 | : | 5 |
| Dec 21 • 21:00 | UD Logroñés | | - | | Albacete Balompié | 0 | : | 0 |
| Dec 21 • 21:00 | AD Ceuta FC | | - | | UD Ibiza | 3 | : | 2 |
| Dec 21 • 21:00 | Pontevedra CF | | - | | CD Tenerife | 2 | : | 1 |
| Dec 22 • 19:00 | CP Cacereño | | - | | Girona FC | 2 | : | 1 |
| Dec 22 • 19:00 | Linares Deportivo | | - |  | Racing Santander | 1 | : | 0 |
| Dec 22 • 19:00 | CD Eldense | | - | | Burgos CF | 1 | : | 0 |
| Dec 22 • 19:00 | Gernika Club | | - | | Celta de Vigo | 0 | : | 3 |
| Dec 22 • 21:00 | CD Arenteiro | | - | | Atlético Madrid | 1 | : | 3 |
| Dec 22 • 21:00 | Gimnàstic de Tarragona | | - | | Málaga CF | 2 | : | 1 |
| Dec 22 • 21:00 | CF La Nucía | | - | | UD Las Palmas | 0 | : | 0 |
| Dec 22 • 21:00 | Real Oviedo | | - | | Granada CF | 1 | : | 0 |
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| Jan 03 • 19:00 | FC Cartagena | | - | | Villarreal CF | 1 | : | 5 |
| Jan 03 • 19:00 | RCD Espanyol | | - | | Celta de Vigo | 3 | : | 1 |
| Jan 03 • 19:00 | CF La Nucía | | - |  | Valencia CF | 0 | : | 3 |
| Jan 03 • 21:00 | CP Cacereño | | - |  | Real Madrid | 0 | : | 1 |
| Jan 03 • 21:00 | AD Ceuta FC | | - | | Elche CF | 1 | : | 0 |
| Jan 03 • 21:00 | Sporting de Gijon | | - | | Rayo Vallecano | 2 | : | 0 |
| Jan 03 • 21:00 | Levante UD | | - | | Getafe CF | 3 | : | 2 |
| Jan 04 • 19:00 | Linares Deportivo | | - | | Sevilla FC | 0 | : | 5 |
| Jan 04 • 19:00 | Pontevedra CF | | - | | RCD Mallorca | 0 | : | 2 |
| Jan 04 • 19:00 | UD Logroñés | | - | | Real Sociedad | 0 | : | 1 |
| Jan 04 • 20:00 | Real Oviedo | | - | | Atlético Madrid | 0 | : | 2 |
| Jan 04 • 21:00 | Deportivo Alavés | | - | | Real Valladolid | 1 | : | 0 |
| Jan 04 • 21:00 | CF Intercity Sant Joan d'Alacant | | - |  | FC Barcelona | 3 | : | 4 |
| Jan 05 • 16:00 | CD Ibiza Islas Pitiusas | | - |  | Real Betis | 1 | : | 4 |
| Jan 05 • 16:00 | Gimnàstic de Tarragona | | - | | CA Osasuna | 1 | : | 2 |
| Jan 05 • 21:00 | CD Eldense | | - | | Athletic Bilbao | 1 | : | 6 |
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| Jan 17 • 19:00 | Real Sociedad | | - | | RCD Mallorca | 1 | : | 0 |
| Jan 17 • 21:00 | Deportivo Alavés | | - | | Sevilla FC | 0 | : | 1 |
| Jan 18 • 19:00 | Sporting de Gijon | | - | | Valencia CF | 0 | : | 4 |
| Jan 18 • 20:00 | Athletic Bilbao | | - | | RCD Espanyol | 1 | : | 0 |
| Jan 18 • 21:00 | Levante UD | | - | | Atlético Madrid | 0 | : | 2 |
| Jan 18 • 21:00 | Real Betis | | - | | CA Osasuna | 2 | : | 2 |
| Jan 19 • 20:00 | AD Ceuta FC | | - | | FC Barcelona | 0 | : | 5 |
| Jan 19 • 21:00 | Villarreal CF | | - | | Real Madrid | 2 | : | 3 |
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| Jan 25 • 21:00 | FC Barcelona | | - | | Real Sociedad | 1 | : | 0 |
| Jan 25 • 22:00 | CA Osasuna | | - | | Sevilla FC | 2 | : | 1 |
| Jan 26 • 20:00 | Valencia CF | | - | | Athletic Bilbao | 1 | : | 3 |
| Jan 26 • 21:00 | Real Madrid | | - | | Atlético Madrid | 3 | : | 1 |
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| Mar 01 • 21:00 | CA Osasuna | | - | | Athletic Bilbao | 1 | : | 0 |
| Mar 02 • 21:00 | Real Madrid | | - | | FC Barcelona | 0 | : | 1 |
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| Apr 04 • 21:00 | Athletic Bilbao | | - | | CA Osasuna | 1 | : | 1 |
| Apr 05 • 21:00 | FC Barcelona | | - | | Real Madrid | 0 | : | 4 |
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| May 06 • 22:00 | CA Osasuna | | - | | Real Madrid | 1 | : | 2 |
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