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| Feb 14 • 19:30 | Pablo Cuevas |  | - |  | Pablo Andújar | 0 | : | 2 |
| Feb 14 • 20:30 | Shang Juncheng |  | - | | Pedro Martínez | 0 | : | 2 |
| Feb 14 • 23:00 | Jaume Munar | | - | | Carlos Alcaraz | 1 | : | 2 |
| Feb 15 • 00:20 | Felipe Meligeni Alves |  | - |  | Miomir Kecmanovic | 0 | : | 2 |
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| Feb 15 • 20:30 | Daniel Elahi Galán |  | - |  | Federico Delbonis | 1 | : | 2 |
| Feb 15 • 20:30 | Fernando Verdasco | | - | | Dušan Lajović | 2 | : | 0 |
| Feb 15 • 20:30 | Federico Coria | | - |  | Cristian Garín | 2 | : | 0 |
| Feb 15 • 21:50 | Facundo Bagnis | | - |  | Fabio Fognini | 0 | : | 2 |
| Feb 15 • 21:50 | Albert Ramos-Viñolas | | - | | Juan Ignacio Londero | 2 | : | 0 |
| Feb 15 • 23:00 | Sebastián Báez | | - | | Thiago Moura Monteiro | 1 | : | 2 |
| Feb 15 • 23:10 | Lorenzo Sonego | | - | | Laslo Djere | 2 | : | 0 |
| Feb 16 • 00:20 | Francisco Cerundolo | | - |  | Benoît Paire | 2 | : | 1 |
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| Feb 16 • 20:30 | Fernando Verdasco | | - | | Federico Coria | 1 | : | 2 |
| Feb 16 • 21:50 | Albert Ramos-Viñolas | | - | | Pablo Andújar | 1 | : | 2 |
| Feb 16 • 23:00 | Pablo Carreño Busta | | - | | Fabio Fognini | 1 | : | 2 |
| Feb 17 • 00:20 | Pedro Martínez | | - | | Diego Schwartzman | 0 | : | 2 |
| Feb 17 • 20:30 | Lorenzo Sonego | | - | | Miomir Kecmanovic | 0 | : | 2 |
| Feb 17 • 20:30 | Francisco Cerundolo | | - | | Roberto Carballés Baena | 2 | : | 0 |
| Feb 17 • 23:00 | Federico Delbonis | | - | | Carlos Alcaraz | 0 | : | 2 |
| Feb 18 • 18:30 | Matteo Berrettini | | - | | Thiago Moura Monteiro | 2 | : | 1 |
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| Feb 19 • 16:00 | Pablo Andújar | | - | | Diego Schwartzman | 1 | : | 2 |
| Feb 19 • 16:00 | Miomir Kecmanovic | | - | | Francisco Cerundolo | 1 | : | 2 |
| Feb 19 • 17:20 | Fabio Fognini | | - | | Federico Coria | 2 | : | 0 |
| Feb 19 • 19:00 | Matteo Berrettini | | - | | Carlos Alcaraz | 1 | : | 2 |
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| Feb 20 • 00:15 | Diego Schwartzman | | - | | Francisco Cerundolo | 2 | : | 0 |
| Feb 20 • 02:30 | Carlos Alcaraz | | - | | Fabio Fognini | 2 | : | 0 |
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| Feb 20 • 21:30 | Carlos Alcaraz | | - | | Diego Schwartzman | 2 | : | 0 |
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