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| Apr 10 • 13:00 | Alejandro Davidovich Fokina |  | - |  | Marcos Giron | 2 | : | 0 |
| Apr 10 • 13:40 | Márton Fucsovics |  | - |  | Lloyd Harris | 2 | : | 1 |
| Apr 10 • 14:20 | Grigor Dimitrov |  | - |  | Nikoloz Basilashvili | 1 | : | 0 |
| Apr 10 • 16:00 | Dušan Lajović |  | - | | Filip Krajinović | 2 | : | 0 |
| Apr 11 • 11:00 | Sebastian Korda | | - |  | Botic van de Zandschulp | 2 | : | 0 |
| Apr 11 • 11:00 | Albert Ramos-Viñolas | | - | | Tallon Griekspoor | 2 | : | 1 |
| Apr 11 • 11:00 | Fabio Fognini |  | - |  | Arthur Rinderknech | 2 | : | 1 |
| Apr 11 • 12:20 | Alex De Minaur |  | - | | Bernabe Zapata Miralles | 2 | : | 0 |
| Apr 11 • 12:20 | Stanislas Wawrinka |  | - |  | Alexander Bublik | 1 | : | 2 |
| Apr 11 • 12:20 | Jaume Munar | | - |  | Federico Delbonis | 1 | : | 2 |
| Apr 11 • 12:40 | Karen Khachanov |  | - | | Diego Schwartzman | 1 | : | 2 |
| Apr 11 • 14:30 | Pablo Carreño Busta | | - | | Sebastián Báez | 2 | : | 1 |
| Apr 11 • 15:20 | Borna Ćorić |  | - | | Jannik Sinner | 1 | : | 2 |
| Apr 11 • 16:00 | Hubert Hurkacz |  | - |  | Hugo Dellien | 2 | : | 0 |
| Apr 11 • 16:30 | Jo-Wilfried Tsonga | | - | | Marin Čilić | 0 | : | 2 |
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| Apr 12 • 11:00 | Daniel Evans |  | - | | Benjamin Bonzi | 2 | : | 0 |
| Apr 12 • 11:00 | Pedro Martínez | | - | | Ugo Humbert | 2 | : | 0 |
| Apr 12 • 11:00 | Lorenzo Sonego | | - |  | Ilya Ivashka | 2 | : | 0 |
| Apr 12 • 11:00 | Emil Ruusuvuori |  | - |  | Oscar Otte | 2 | : | 0 |
| Apr 12 • 12:00 | Maxime Cressy | | - | | Laslo Djere | 1 | : | 2 |
| Apr 12 • 12:30 | Taylor Harry Fritz | | - |  | Lucas Catarina | 2 | : | 1 |
| Apr 12 • 12:30 | Lorenzo Musetti | | - | | Benoît Paire | 2 | : | 1 |
| Apr 12 • 14:15 | Holger Rune |  | - | | Aslan Karatsev | 2 | : | 1 |
| Apr 12 • 15:15 | David Goffin |  | - |  | Jiří Lehečka | 2 | : | 0 |
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| Apr 12 • 14:30 | Novak Djokovic | | - | | Alejandro Davidovich Fokina | 1 | : | 2 |
| Apr 12 • 16:00 | Fabio Fognini | | - |  | Stefanos Tsitsipas | 0 | : | 2 |
| Apr 12 • 17:30 | Dušan Lajović | | - | | Grigor Dimitrov | 1 | : | 2 |
| Apr 13 • 11:00 | Sebastian Korda | | - | | Carlos Alcaraz | 2 | : | 1 |
| Apr 13 • 11:00 | Albert Ramos-Viñolas | | - | | Cameron Norrie | 2 | : | 1 |
| Apr 13 • 11:00 | Lorenzo Sonego | | - | | Laslo Djere | 0 | : | 2 |
| Apr 13 • 12:20 | Taylor Harry Fritz | | - | | Marin Čilić | 2 | : | 1 |
| Apr 13 • 12:20 | Hubert Hurkacz | | - | | Pedro Martínez | 2 | : | 1 |
| Apr 13 • 12:30 | Casper Ruud |  | - | | Holger Rune | 2 | : | 0 |
| Apr 13 • 13:00 | David Goffin | | - | | Daniel Evans | 2 | : | 0 |
| Apr 13 • 14:00 | Pablo Carreño Busta | | - | | Alexander Bublik | 1 | : | 1 |
| Apr 13 • 14:20 | Márton Fucsovics | | - | | Diego Schwartzman | 0 | : | 2 |
| Apr 13 • 14:20 | Emil Ruusuvuori | | - | | Jannik Sinner | 0 | : | 2 |
| Apr 13 • 14:30 | Felix Auger Aliassime |  | - | | Lorenzo Musetti | 0 | : | 2 |
| Apr 13 • 15:00 | Andrey Rublev | | - | | Alex De Minaur | 2 | : | 1 |
| Apr 13 • 15:00 | Federico Delbonis | | - | | Alexander Zverev | 0 | : | 2 |
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| Apr 14 • 11:00 | Taylor Harry Fritz | | - | | Sebastian Korda | 2 | : | 0 |
| Apr 14 • 11:00 | Casper Ruud | | - | | Grigor Dimitrov | 0 | : | 2 |
| Apr 14 • 12:00 | Alejandro Davidovich Fokina | | - | | David Goffin | 2 | : | 0 |
| Apr 14 • 12:30 | Lorenzo Musetti | | - | | Diego Schwartzman | 1 | : | 2 |
| Apr 14 • 12:30 | Laslo Djere | | - | | Stefanos Tsitsipas | 0 | : | 2 |
| Apr 14 • 14:00 | Hubert Hurkacz | | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| Apr 14 • 14:00 | Pablo Carreño Busta | | - | | Alexander Zverev | 0 | : | 2 |
| Apr 14 • 15:30 | Andrey Rublev | | - | | Jannik Sinner | 1 | : | 2 |
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| Apr 15 • 11:00 | Alejandro Davidovich Fokina | | - | | Taylor Harry Fritz | 2 | : | 1 |
| Apr 15 • 12:30 | Grigor Dimitrov | | - | | Hubert Hurkacz | 2 | : | 1 |
| Apr 15 • 13:40 | Jannik Sinner | | - | | Alexander Zverev | 1 | : | 2 |
| Apr 15 • 17:45 | Diego Schwartzman | | - | | Stefanos Tsitsipas | 1 | : | 2 |
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| Apr 16 • 13:30 | Alejandro Davidovich Fokina | | - | | Grigor Dimitrov | 2 | : | 1 |
| Apr 16 • 15:30 | Stefanos Tsitsipas | | - | | Alexander Zverev | 2 | : | 0 |
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| Apr 17 • 14:30 | Alejandro Davidovich Fokina | | - | | Stefanos Tsitsipas | 0 | : | 2 |
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Monte Carlo Masters 2022
