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| Aug 29 • 17:00 | Quentin Halys |  | - | | Arthur Rinderknech | 1 | : | 3 |
| Aug 29 • 17:00 | Alejandro Tabilo |  | - |  | Kamil Majchrzak | 3 | : | 1 |
| Aug 29 • 17:00 | Jeffrey John Wolf |  | - |  | Roberto Bautista-Agut | 3 | : | 0 |
| Aug 29 • 17:00 | Yoshihito Nishioka |  | - | | Alejandro Davidovich Fokina | 0 | : | 3 |
| Aug 29 • 17:00 | Francisco Cerundolo |  | - |  | Andy Murray | 0 | : | 3 |
| Aug 29 • 17:00 | John Millman |  | - | | Emilio Nava | 2 | : | 3 |
| Aug 29 • 17:00 | Tommy Paul | | - | | Bernabe Zapata Miralles | 3 | : | 2 |
| Aug 29 • 17:00 | Sebastian Korda | | - | | Facundo Bagnis | 3 | : | 1 |
| Aug 29 • 17:00 | Zhang Zhizhen |  | - |  | Tim van Rijthoven | 2 | : | 3 |
| Aug 29 • 18:00 | Daniil Medvedev |  | - | | Stefan Kozlov | 3 | : | 0 |
| Aug 29 • 18:45 | Márton Fucsovics |  | - | | Maxime Cressy | 1 | : | 1 |
| Aug 29 • 18:45 | Nicolás Jarry | | - |  | Matteo Berrettini | 0 | : | 3 |
| Aug 29 • 18:50 | Kyle Edmund | | - |  | Casper Ruud | 0 | : | 3 |
| Aug 29 • 19:00 | Yibing Wu | | - |  | Nikoloz Basilashvili | 3 | : | 0 |
| Aug 29 • 19:00 | Tomás Martín Etcheverry | | - | | Hugo Grenier | 1 | : | 3 |
| Aug 29 • 19:35 | Stanislas Wawrinka |  | - | | Corentin Moutet | 0 | : | 2 |
| Aug 29 • 19:45 | Ben Shelton | | - |  | Nuno Borges | 2 | : | 3 |
| Aug 29 • 20:20 | Filip Krajinović |  | - | | Alex De Minaur | 0 | : | 3 |
| Aug 29 • 20:30 | Alex Molcan |  | - |  | Thiago Moura Monteiro | 1 | : | 3 |
| Aug 29 • 20:30 | Tomáš Macháč |  | - | | Botic van de Zandschulp | 2 | : | 3 |
| Aug 29 • 20:40 | Cristian Garín | | - | | Jiří Lehečka | 3 | : | 1 |
| Aug 29 • 20:50 | Pablo Carreño Busta | | - |  | Dominic Thiem | 3 | : | 1 |
| Aug 29 • 20:55 | Alexander Ritschard | | - |  | Felix Auger Aliassime | 1 | : | 3 |
| Aug 29 • 21:00 | Karen Khachanov | | - | | Denis Kudla | 3 | : | 1 |
| Aug 29 • 22:00 | Benjamin Bonzi | | - | | Ugo Humbert | 3 | : | 2 |
| Aug 29 • 22:00 | Alexander Bublik |  | - | | Hugo Gaston | 3 | : | 0 |
| Aug 29 • 22:00 | Jack Draper | | - |  | Emil Ruusuvuori | 3 | : | 0 |
| Aug 29 • 22:00 | Lorenzo Sonego | | - | | Jordan Thompson | 2 | : | 3 |
| Aug 29 • 22:00 | Taylor Harry Fritz | | - | | Brandon Holt | 1 | : | 3 |
| Aug 29 • 22:00 | Aljaž Bedene |  | - | | Pedro Cachín | 2 | : | 3 |
| Aug 30 • 01:00 | Stefanos Tsitsipas |  | - |  | Daniel Elahi Galán | 1 | : | 3 |
| Aug 30 • 02:30 | Nick Kyrgios | | - | | Thanasi Kokkinakis | 3 | : | 0 |
| Aug 30 • 17:00 | Grigor Dimitrov |  | - | | Steve Johnson | 3 | : | 0 |
| Aug 30 • 17:00 | Brandon Nakashima | | - | | Pavel Kotov | 3 | : | 0 |
| Aug 30 • 17:00 | Cameron Norrie | | - | | Benoît Paire | 3 | : | 0 |
| Aug 30 • 17:00 | João Sousa | | - | | Mackenzie McDonald | 3 | : | 1 |
| Aug 30 • 17:00 | Taro Daniel | | - | | Richard Gasquet | 1 | : | 3 |
| Aug 30 • 18:00 | Sebastián Báez | | - | | Carlos Alcaraz Garfia | 0 | : | 2 |
| Aug 30 • 18:30 | James Duckworth | | - | | Christopher O'Connell | 3 | : | 1 |
| Aug 30 • 18:30 | Jiří Veselý | | - | | Daniel Evans | 0 | : | 3 |
| Aug 30 • 18:30 | John Isner | | - | | Federico Delbonis | 3 | : | 0 |
| Aug 30 • 18:30 | Fernando Verdasco | | - |  | Kwon Soon-woo | 1 | : | 3 |
| Aug 30 • 19:25 | Peter Gojowczyk |  | - |  | Holger Rune | 0 | : | 3 |
| Aug 30 • 19:25 | Laslo Djere | | - | | Andrey Rublev | 2 | : | 3 |
| Aug 30 • 19:35 | Tallon Griekspoor | | - | | Federico Coria | 0 | : | 3 |
| Aug 30 • 19:45 | Miomir Kecmanovic | | - | | Learner Tien | 3 | : | 1 |
| Aug 30 • 20:45 | Pedro Martínez | | - | | Christopher Eubanks | 0 | : | 3 |
| Aug 30 • 20:55 | Marin Čilić |  | - | | Maximilian Marterer | 3 | : | 0 |
| Aug 30 • 20:55 | Borna Ćorić | | - | | Enzo Couacaud | 3 | : | 2 |
| Aug 30 • 21:10 | Daniel Altmaier | | - | | Jannik Sinner | 2 | : | 3 |
| Aug 30 • 21:50 | David Goffin |  | - | | Lorenzo Musetti | 2 | : | 3 |
| Aug 30 • 22:15 | Norbert Gombos | | - | | Albert Ramos-Viñolas | 0 | : | 3 |
| Aug 30 • 22:15 | Jenson Brooksby | | - | | Dušan Lajović | 2 | : | 0 |
| Aug 30 • 22:30 | Adrian Mannarino | | - | | Gijs Brouwer | 0 | : | 3 |
| Aug 30 • 23:20 | Sam Querrey | | - |  | Ilya Ivashka | 1 | : | 3 |
| Aug 30 • 23:30 | Hubert Hurkacz | | - | | Oscar Otte | 3 | : | 0 |
| Aug 30 • 23:30 | Marcos Giron | | - | | Frances Tiafoe | 0 | : | 3 |
| Aug 30 • 23:30 | Fabio Fognini | | - | | Aslan Karatsev | 3 | : | 2 |
| Aug 30 • 23:45 | Alexei Popyrin | | - |  | Tseng Chun-hsin | 3 | : | 0 |
| Aug 30 • 23:45 | Jason Kubler | | - |  | Mikael Ymer | 3 | : | 1 |
| Aug 31 • 00:00 | Denis Shapovalov | | - | | Marc-Andrea Hüsler | 3 | : | 2 |
| Aug 31 • 00:00 | Jaume Munar | | - | | Roberto Carballés Baena | 1 | : | 3 |
| Aug 31 • 01:00 | Rinky Hijikata | | - | | Rafael Nadal | 1 | : | 3 |
| Aug 31 • 02:30 | Diego Schwartzman | | - | | Jack Sock | 0 | : | 0 |
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| Aug 31 • 17:00 | Pablo Carreño Busta | | - | | Alexander Bublik | 3 | : | 1 |
| Aug 31 • 17:00 | Cristian Garín | | - | | Alex De Minaur | 1 | : | 3 |
| Aug 31 • 17:00 | Brandon Holt | | - | | Pedro Cachín | 2 | : | 3 |
| Aug 31 • 17:00 | Corentin Moutet | | - | | Botic van de Zandschulp | 3 | : | 1 |
| Aug 31 • 18:30 | Andy Murray | | - | | Emilio Nava | 3 | : | 1 |
| Aug 31 • 18:30 | Hugo Grenier | | - | | Matteo Berrettini | 1 | : | 3 |
| Aug 31 • 21:30 | Alejandro Tabilo | | - | | Jeffrey John Wolf | 1 | : | 3 |
| Aug 31 • 21:45 | Nick Kyrgios | | - | | Benjamin Bonzi | 3 | : | 1 |
| Aug 31 • 21:45 | Daniel Elahi Galán | | - | | Jordan Thompson | 3 | : | 2 |
| Aug 31 • 22:00 | Tim van Rijthoven | | - | | Casper Ruud | 1 | : | 3 |
| Aug 31 • 22:10 | Tommy Paul | | - | | Sebastian Korda | 3 | : | 2 |
| Aug 31 • 22:30 | Alejandro Davidovich Fokina | | - | | Márton Fucsovics | 3 | : | 2 |
| Aug 31 • 23:10 | Nuno Borges | | - | | Yibing Wu | 2 | : | 3 |
| Aug 31 • 23:45 | Karen Khachanov | | - | | Thiago Moura Monteiro | 3 | : | 1 |
| Sep 01 • 01:00 | Jack Draper | | - | | Felix Auger Aliassime | 3 | : | 0 |
| Sep 01 • 02:30 | Daniil Medvedev | | - | | Arthur Rinderknech | 3 | : | 0 |
| Sep 01 • 16:00 | John Isner | | - | | Holger Rune | 0 | : | 0 |
| Sep 01 • 17:00 | Marin Čilić | | - | | Albert Ramos-Viñolas | 3 | : | 0 |
| Sep 01 • 17:00 | James Duckworth | | - | | Daniel Evans | 1 | : | 3 |
| Sep 01 • 17:00 | Borna Ćorić | | - | | Jenson Brooksby | 0 | : | 3 |
| Sep 01 • 18:30 | Christopher Eubanks | | - | | Jannik Sinner | 0 | : | 3 |
| Sep 01 • 19:40 | Federico Coria | | - | | Carlos Alcaraz Garfia | 0 | : | 3 |
| Sep 01 • 20:10 | Cameron Norrie | | - | | João Sousa | 3 | : | 0 |
| Sep 01 • 20:15 | Gijs Brouwer | | - | | Lorenzo Musetti | 1 | : | 3 |
| Sep 01 • 20:30 | Kwon Soon-woo | | - | | Andrey Rublev | 0 | : | 3 |
| Sep 01 • 21:00 | Grigor Dimitrov | | - | | Brandon Nakashima | 0 | : | 3 |
| Sep 01 • 21:15 | Diego Schwartzman | | - | | Alexei Popyrin | 3 | : | 0 |
| Sep 01 • 22:15 | Denis Shapovalov | | - | | Roberto Carballés Baena | 3 | : | 1 |
| Sep 01 • 22:35 | Miomir Kecmanovic | | - | | Richard Gasquet | 1 | : | 3 |
| Sep 01 • 23:00 | Hubert Hurkacz | | - | | Ilya Ivashka | 1 | : | 3 |
| Sep 01 • 23:00 | Jason Kubler | | - | | Frances Tiafoe | 0 | : | 3 |
| Sep 02 • 02:30 | Fabio Fognini | | - | | Rafael Nadal | 1 | : | 3 |
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| Sep 02 • 17:00 | Daniel Elahi Galán | | - | | Alejandro Davidovich Fokina | 1 | : | 3 |
| Sep 02 • 18:00 | Andy Murray | | - | | Matteo Berrettini | 1 | : | 3 |
| Sep 02 • 19:35 | Tommy Paul | | - | | Casper Ruud | 2 | : | 3 |
| Sep 02 • 20:15 | Karen Khachanov | | - | | Jack Draper | 1 | : | 1 |
| Sep 02 • 20:15 | Pedro Cachín | | - | | Corentin Moutet | 1 | : | 3 |
| Sep 02 • 22:15 | Pablo Carreño Busta | | - | | Alex De Minaur | 3 | : | 1 |
| Sep 03 • 02:30 | Daniil Medvedev | | - | | Yibing Wu | 3 | : | 0 |
| Sep 03 • 02:30 | Nick Kyrgios | | - | | Jeffrey John Wolf | 3 | : | 0 |
| Sep 03 • 17:00 | Cameron Norrie | | - | | Holger Rune | 3 | : | 0 |
| Sep 03 • 19:00 | Denis Shapovalov | | - | | Andrey Rublev | 2 | : | 3 |
| Sep 03 • 19:30 | Jenson Brooksby | | - | | Carlos Alcaraz Garfia | 0 | : | 3 |
| Sep 03 • 20:00 | Marin Čilić | | - | | Daniel Evans | 3 | : | 1 |
| Sep 03 • 20:00 | Diego Schwartzman | | - | | Frances Tiafoe | 0 | : | 3 |
| Sep 03 • 22:00 | Ilya Ivashka | | - | | Lorenzo Musetti | 3 | : | 1 |
| Sep 04 • 01:00 | Richard Gasquet | | - | | Rafael Nadal | 0 | : | 3 |
| Sep 04 • 02:30 | Brandon Nakashima | | - | | Jannik Sinner | 1 | : | 3 |
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| Sep 04 • 17:00 | Alejandro Davidovich Fokina | | - | | Matteo Berrettini | 2 | : | 3 |
| Sep 04 • 18:00 | Corentin Moutet | | - | | Casper Ruud | 1 | : | 3 |
| Sep 04 • 22:15 | Pablo Carreño Busta | | - | | Karen Khachanov | 2 | : | 3 |
| Sep 05 • 01:00 | Daniil Medvedev | | - | | Nick Kyrgios | 1 | : | 3 |
| Sep 05 • 17:00 | Cameron Norrie | | - | | Andrey Rublev | 0 | : | 3 |
| Sep 05 • 19:30 | Frances Tiafoe | | - | | Rafael Nadal | 3 | : | 1 |
| Sep 05 • 23:15 | Ilya Ivashka | | - | | Jannik Sinner | 2 | : | 3 |
| Sep 06 • 01:30 | Marin Čilić | | - | | Carlos Alcaraz Garfia | 2 | : | 3 |
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| Sep 06 • 18:00 | Matteo Berrettini | | - | | Casper Ruud | 0 | : | 3 |
| Sep 07 • 02:30 | Nick Kyrgios | | - | | Karen Khachanov | 2 | : | 3 |
| Sep 07 • 19:15 | Andrey Rublev | | - | | Frances Tiafoe | 0 | : | 3 |
| Sep 08 • 02:15 | Jannik Sinner | | - | | Carlos Alcaraz Garfia | 2 | : | 3 |
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| Sep 09 • 21:00 | Karen Khachanov | | - | | Casper Ruud | 1 | : | 3 |
| Sep 10 • 01:00 | Carlos Alcaraz Garfia | | - | | Frances Tiafoe | 3 | : | 2 |
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| Sep 11 • 22:00 | Casper Ruud | | - | | Carlos Alcaraz Garfia | 1 | : | 3 |
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