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| Oct 24 • 15:00 | Brandon Nakashima |  | - |  | David Goffin | 2 | : | 1 |
| Oct 24 • 18:30 | Aslan Karatsev |  | - |  | Alexander Bublik | 0 | : | 2 |
| Oct 24 • 19:00 | Carlos Alcaraz |  | - |  | Jack Draper | 2 | : | 1 |
| Oct 24 • 20:20 | Arthur Rinderknech |  | - |  | Marin Čilić | 2 | : | 1 |
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| Oct 25 • 13:00 | Sebastián Báez |  | - | | Pablo Carreño Busta | 0 | : | 2 |
| Oct 25 • 14:20 | Alex Molcan |  | - | | Mackenzie McDonald | 2 | : | 1 |
| Oct 25 • 15:00 | Roman Safiullin | | - | | Andy Murray | 1 | : | 2 |
| Oct 25 • 15:55 | Botic van de Zandschulp |  | - | | Adrian Mannarino | 2 | : | 1 |
| Oct 25 • 16:30 | Maxime Cressy | | - |  | Dominic Stricker | 0 | : | 2 |
| Oct 25 • 19:30 | Stanislas Wawrinka | | - |  | Casper Ruud | 2 | : | 0 |
| Oct 25 • 21:15 | Roberto Bautista-Agut | | - |  | Laslo Djere | 2 | : | 0 |
| Oct 25 • 21:30 | Alejandro Davidovich Fokina | | - | | Miomir Kecmanovic | 1 | : | 2 |
| Oct 26 • 13:00 | Alex De Minaur |  | - |  | Holger Rune | 0 | : | 2 |
| Oct 26 • 13:00 | Jenson Brooksby | | - | | Ugo Humbert | 0 | : | 2 |
| Oct 26 • 15:00 | Albert Ramos-Viñolas | | - |  | Lorenzo Musetti | 2 | : | 1 |
| Oct 26 • 16:30 | Felix Auger Aliassime |  | - | | Marc-Andrea Hüsler | 2 | : | 1 |
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| Oct 26 • 19:00 | Carlos Alcaraz | | - | | Botic van de Zandschulp | 2 | : | 0 |
| Oct 26 • 19:20 | Alex Molcan | | - | | Arthur Rinderknech | 0 | : | 2 |
| Oct 26 • 20:20 | Dominic Stricker | | - | | Pablo Carreño Busta | 1 | : | 2 |
| Oct 27 • 15:00 | Alexander Bublik | | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| Oct 27 • 15:00 | Roberto Bautista-Agut | | - | | Andy Murray | 2 | : | 0 |
| Oct 27 • 16:20 | Felix Auger Aliassime | | - | | Miomir Kecmanovic | 2 | : | 0 |
| Oct 27 • 19:00 | Brandon Nakashima | | - | | Stanislas Wawrinka | 1 | : | 2 |
| Oct 27 • 20:20 | Holger Rune | | - | | Ugo Humbert | 2 | : | 0 |
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| Oct 28 • 15:00 | Felix Auger Aliassime | | - | | Alexander Bublik | 2 | : | 0 |
| Oct 28 • 16:20 | Carlos Alcaraz | | - | | Pablo Carreño Busta | 2 | : | 0 |
| Oct 28 • 19:00 | Roberto Bautista-Agut | | - | | Stanislas Wawrinka | 2 | : | 0 |
| Oct 28 • 20:20 | Holger Rune | | - | | Arthur Rinderknech | 2 | : | 0 |
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| Oct 29 • 14:30 | Carlos Alcaraz | | - | | Felix Auger Aliassime | 0 | : | 2 |
| Oct 29 • 16:00 | Holger Rune | | - | | Roberto Bautista-Agut | 2 | : | 0 |
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| Oct 30 • 15:00 | Felix Auger Aliassime | | - | | Holger Rune | 2 | : | 0 |
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