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| Oct 31 • 11:00 | Aslan Karatsev |  | - |  | Yoshihito Nishioka | 0 | : | 2 |
| Oct 31 • 11:00 | John Isner |  | - |  | Oscar Otte | 2 | : | 0 |
| Oct 31 • 11:00 | Miomir Kecmanovic |  | - |  | Cameron Norrie | 0 | : | 2 |
| Oct 31 • 12:20 | Taylor Harry Fritz | | - |  | Alejandro Davidovich Fokina | 2 | : | 0 |
| Oct 31 • 12:20 | Sebastián Báez |  | - | | Karen Khachanov | 0 | : | 2 |
| Oct 31 • 12:20 | Nikoloz Basilashvili |  | - |  | Quentin Halys | 2 | : | 0 |
| Oct 31 • 13:40 | Marin Čilić |  | - |  | Lorenzo Musetti | 0 | : | 2 |
| Oct 31 • 13:40 | Alex Molcan |  | - | | Richard Gasquet | 0 | : | 2 |
| Oct 31 • 15:45 | Diego Schwartzman | | - | | Maxime Cressy | 0 | : | 2 |
| Oct 31 • 16:00 | Marc-Andrea Hüsler |  | - | | Jannik Sinner | 2 | : | 0 |
| Oct 31 • 17:40 | Lorenzo Sonego | | - | | Frances Tiafoe | 0 | : | 2 |
| Oct 31 • 19:00 | Alexander Bublik |  | - |  | Mikael Ymer | 1 | : | 2 |
| Oct 31 • 19:30 | Andy Murray | | - | | Gilles Simon | 1 | : | 2 |
| Oct 31 • 20:50 | Sebastian Korda | | - |  | Alex De Minaur | 1 | : | 2 |
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| Nov 01 • 11:00 | Daniel Evans | | - | | Brandon Nakashima | 2 | : | 1 |
| Nov 01 • 11:00 | Corentin Moutet | | - | | Borna Ćorić | 2 | : | 1 |
| Nov 01 • 12:20 | Arthur Fils | | - | | Fabio Fognini | 1 | : | 2 |
| Nov 01 • 12:20 | Arthur Rinderknech | | - | | Jack Draper | 0 | : | 2 |
| Nov 01 • 12:20 | Pablo Carreño Busta | | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| Nov 01 • 13:40 | Botic van de Zandschulp |  | - |  | Grigor Dimitrov | 0 | : | 2 |
| Nov 01 • 13:40 | Hubert Hurkacz |  | - | | Adrian Mannarino | 2 | : | 0 |
| Nov 01 • 13:40 | Roberto Bautista-Agut | | - | | Tommy Paul | 0 | : | 2 |
| Nov 01 • 17:30 | Denis Shapovalov |  | - | | Francisco Cerundolo | 2 | : | 1 |
| Nov 01 • 19:00 | Holger Rune |  | - | | Stanislas Wawrinka | 2 | : | 1 |
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| Nov 01 • 11:00 | John Isner | | - | | Andrey Rublev | 0 | : | 2 |
| Nov 01 • 15:00 | Novak Djokovic | | - | | Maxime Cressy | 2 | : | 0 |
| Nov 01 • 19:30 | Richard Gasquet | | - |  | Casper Ruud | 0 | : | 2 |
| Nov 01 • 20:50 | Karen Khachanov | | - | | Marc-Andrea Hüsler | 2 | : | 1 |
| Nov 02 • 11:00 | Jack Draper | | - | | Frances Tiafoe | 0 | : | 2 |
| Nov 02 • 11:00 | Lorenzo Musetti | | - | | Nikoloz Basilashvili | 2 | : | 0 |
| Nov 02 • 11:00 | Stefanos Tsitsipas |  | - | | Daniel Evans | 2 | : | 0 |
| Nov 02 • 12:30 | Daniil Medvedev | | - | | Alex De Minaur | 1 | : | 2 |
| Nov 02 • 12:30 | Mikael Ymer | | - | | Felix Auger Aliassime | 1 | : | 2 |
| Nov 02 • 14:20 | Carlos Alcaraz | | - | | Yoshihito Nishioka | 2 | : | 0 |
| Nov 02 • 14:30 | Grigor Dimitrov | | - | | Fabio Fognini | 2 | : | 0 |
| Nov 02 • 17:30 | Taylor Harry Fritz | | - | | Gilles Simon | 1 | : | 2 |
| Nov 02 • 18:00 | Hubert Hurkacz | | - | | Holger Rune | 0 | : | 2 |
| Nov 02 • 19:30 | Pablo Carreño Busta | | - | | Denis Shapovalov | 2 | : | 1 |
| Nov 02 • 19:30 | Tommy Paul | | - | | Rafael Nadal | 2 | : | 1 |
| Nov 02 • 22:25 | Corentin Moutet | | - | | Cameron Norrie | 2 | : | 1 |
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| Nov 03 • 11:00 | Lorenzo Musetti | | - | | Casper Ruud | 2 | : | 1 |
| Nov 03 • 12:30 | Alex De Minaur | | - | | Frances Tiafoe | 0 | : | 2 |
| Nov 03 • 13:30 | Carlos Alcaraz | | - | | Grigor Dimitrov | 2 | : | 0 |
| Nov 03 • 13:50 | Holger Rune | | - | | Andrey Rublev | 2 | : | 0 |
| Nov 03 • 15:00 | Gilles Simon | | - | | Felix Auger Aliassime | 0 | : | 2 |
| Nov 03 • 16:30 | Novak Djokovic | | - | | Karen Khachanov | 2 | : | 0 |
| Nov 03 • 19:30 | Stefanos Tsitsipas | | - | | Corentin Moutet | 2 | : | 0 |
| Nov 03 • 21:40 | Pablo Carreño Busta | | - | | Tommy Paul | 0 | : | 2 |
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| Nov 04 • 14:00 | Frances Tiafoe | | - | | Felix Auger Aliassime | 0 | : | 2 |
| Nov 04 • 15:20 | Carlos Alcaraz | | - | | Holger Rune | 0 | : | 1 |
| Nov 04 • 19:30 | Novak Djokovic | | - | | Lorenzo Musetti | 2 | : | 0 |
| Nov 04 • 20:50 | Stefanos Tsitsipas | | - | | Tommy Paul | 2 | : | 0 |
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| Nov 05 • 14:00 | Holger Rune | | - | | Felix Auger Aliassime | 2 | : | 0 |
| Nov 05 • 16:30 | Novak Djokovic | | - | | Stefanos Tsitsipas | 2 | : | 1 |
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| Nov 06 • 15:00 | Holger Rune | | - | | Novak Djokovic | 2 | : | 1 |
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