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| Jul 03 • 12:00 | Andrey Rublev |  | - |  | Max Purcell | 3 | : | 0 |
| Jul 03 • 12:00 | Luca Van Assche |  | - | | Aslan Karatsev | 1 | : | 3 |
| Jul 03 • 12:00 | Sebastián Báez |  | - |  | Tomas Barrios Vera | 1 | : | 3 |
| Jul 03 • 12:00 | Lorenzo Musetti |  | - |  | Juan Pablo Varillas | 3 | : | 0 |
| Jul 03 • 12:00 | Jordan Thompson | | - |  | Brandon Nakashima | 3 | : | 2 |
| Jul 03 • 13:15 | Corentin Moutet | | - | | Richard Gasquet | 3 | : | 0 |
| Jul 03 • 13:15 | Liam Broady |  | - | | Constant Lestienne | 3 | : | 0 |
| Jul 03 • 13:15 | Jeffrey John Wolf | | - | | Enzo Couacaud | 3 | : | 0 |
| Jul 03 • 13:15 | Maximilian Marterer |  | - |  | Borna Gojo | 3 | : | 1 |
| Jul 03 • 13:15 | Michael Mmoh | | - |  | Felix Auger Aliassime | 3 | : | 1 |
| Jul 03 • 13:15 | John Isner | | - |  | Jaume Munar | 1 | : | 3 |
| Jul 03 • 13:15 | Albert Ramos-Viñolas | | - |  | Hubert Hurkacz | 0 | : | 3 |
| Jul 03 • 14:00 | David Goffin |  | - |  | Fábián Marozsán | 3 | : | 1 |
| Jul 03 • 14:30 | Jan Choinski | | - |  | Dušan Lajović | 3 | : | 1 |
| Jul 03 • 14:30 | Pedro Cachín | | - | | Novak Djokovic | 0 | : | 3 |
| Jul 03 • 15:15 | Mikael Ymer |  | - |  | Alex Molcan | 3 | : | 0 |
| Jul 03 • 15:15 | Laurent Lokoli | | - |  | Casper Ruud | 1 | : | 3 |
| Jul 03 • 18:25 | Dominik Koepfer | | - | | Oscar Otte | 0 | : | 3 |
| Jul 03 • 18:40 | Miomir Kecmanovic | | - | | Diego Schwartzman | 0 | : | 3 |
| Jul 03 • 18:45 | Alexander Bublik |  | - | | Mackenzie McDonald | 3 | : | 1 |
| Jul 03 • 18:50 | Roman Safiullin | | - | | Roberto Bautista-Agut | 3 | : | 2 |
| Jul 03 • 18:50 | Tomás Martín Etcheverry | | - | | Bernabe Zapata Miralles | 3 | : | 2 |
| Jul 03 • 19:00 | Aleksandar Vukic | | - | | Daniel Altmaier | 3 | : | 1 |
| Jul 03 • 19:00 | Yannick Hanfmann | | - | | Taylor Harry Fritz | 2 | : | 3 |
| Jul 03 • 19:30 | Emil Ruusuvuori |  | - |  | Stanislas Wawrinka | 0 | : | 3 |
| Jul 03 • 19:35 | Yoshihito Nishioka |  | - |  | Daniel Elahi Galán | 0 | : | 3 |
| Jul 03 • 20:30 | Quentin Halys | | - | | Daniel Evans | 3 | : | 1 |
| Jul 03 • 20:35 | Jannik Sinner | | - | | Juan Manuel Cerúndolo | 3 | : | 0 |
| Jul 03 • 20:45 | Borna Ćorić | | - | | Guido Pella | 2 | : | 3 |
| Jul 03 • 20:45 | Denis Shapovalov | | - |  | Radu Albot | 3 | : | 1 |
| Jul 03 • 20:50 | Benjamin Bonzi | | - | | Harold Mayot | 0 | : | 3 |
| Jul 04 • 12:00 | Alexandre Muller | | - | | Arthur Rinderknech | 3 | : | 1 |
| Jul 04 • 12:00 | Matteo Berrettini | | - | | Lorenzo Sonego | 3 | : | 1 |
| Jul 04 • 12:00 | George Loffhagen | | - |  | Holger Rune | 0 | : | 3 |
| Jul 04 • 12:00 | Marcos Giron | | - |  | Hugo Dellien | 3 | : | 0 |
| Jul 04 • 12:00 | Márton Fucsovics | | - |  | Tallon Griekspoor | 3 | : | 0 |
| Jul 04 • 12:00 | Christopher O'Connell | | - | | Hamad Medjedovic | 3 | : | 1 |
| Jul 04 • 12:00 | Ben Shelton | | - | | Taro Daniel | 3 | : | 2 |
| Jul 04 • 12:00 | Dominic Thiem |  | - |  | Stefanos Tsitsipas | 2 | : | 3 |
| Jul 04 • 14:00 | Carlos Alcaraz | | - | | Jérémy Chardy | 3 | : | 0 |
| Jul 04 • 16:00 | Ryan Peniston | | - | | Andy Murray | 0 | : | 3 |
| Jul 04 • 17:30 | Cameron Norrie | | - |  | Tomáš Macháč | 3 | : | 1 |
| Jul 05 • 12:00 | Frances Tiafoe | | - |  | Yibing Wu | 3 | : | 0 |
| Jul 05 • 12:00 | Dominic Stricker | | - | | Alexei Popyrin | 3 | : | 2 |
| Jul 05 • 12:00 | Sho Shimabukuro | | - |  | Grigor Dimitrov | 0 | : | 3 |
| Jul 05 • 12:00 | Francisco Cerundolo | | - |  | Nuno Borges | 3 | : | 1 |
| Jul 05 • 12:00 | Jiří Lehečka | | - | | Sebastian Ofner | 3 | : | 0 |
| Jul 05 • 12:00 | Milos Raonic | | - | | Dennis Novak | 3 | : | 1 |
| Jul 05 • 12:00 | Lloyd Harris |  | - | | Gregoire Barrere | 1 | : | 3 |
| Jul 05 • 14:00 | Daniil Medvedev | | - | | Arthur Fery | 3 | : | 0 |
| Jul 05 • 17:20 | Ilya Ivashka |  | - | | Federico Coria | 3 | : | 1 |
| Jul 05 • 17:50 | Shintaro Mochizuki | | - | | Tommy Paul | 0 | : | 3 |
| Jul 05 • 18:20 | Jiří Veselý | | - | | Sebastian Korda | 3 | : | 1 |
| Jul 05 • 18:30 | Christopher Eubanks | | - |  | Thiago Moura Monteiro | 3 | : | 1 |
| Jul 05 • 19:15 | Matteo Arnaldi | | - | | Roberto Carballés Baena | 1 | : | 3 |
| Jul 05 • 19:25 | Adrian Mannarino | | - | | Alexander Shevchenko | 3 | : | 0 |
| Jul 05 • 19:40 | Jason Kubler | | - | | Ugo Humbert | 3 | : | 2 |
| Jul 05 • 19:45 | Kimmer Coppejans | | - | | Alex De Minaur | 1 | : | 3 |
| Jul 05 • 20:00 | Marc-Andrea Hüsler | | - | | Yosuke Watanuki | 2 | : | 3 |
| Jul 05 • 20:20 | Maxime Cressy | | - | | Laslo Djere | 1 | : | 3 |
| Jul 05 • 21:10 | Marco Cecchinato | | - | | Nicolás Jarry | 1 | : | 3 |
| Jul 06 • 12:00 | Alejandro Davidovich Fokina | | - | | Arthur Fils | 3 | : | 0 |
| Jul 06 • 12:00 | Zhang Zhizhen | | - | | Botic van de Zandschulp | 2 | : | 3 |
| Jul 06 • 14:00 | Alexander Zverev | | - | | Gijs Brouwer | 3 | : | 0 |
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| Jul 05 • 18:15 | Jordan Thompson | | - | | Novak Djokovic | 0 | : | 3 |
| Jul 05 • 19:10 | Jannik Sinner | | - | | Diego Schwartzman | 3 | : | 0 |
| Jul 06 • 12:00 | Aleksandar Vukic | | - | | Quentin Halys | 0 | : | 3 |
| Jul 06 • 12:00 | Alexander Bublik | | - | | Jeffrey John Wolf | 3 | : | 0 |
| Jul 06 • 12:00 | Maximilian Marterer | | - | | Michael Mmoh | 3 | : | 0 |
| Jul 06 • 12:00 | Lorenzo Musetti | | - | | Jaume Munar | 3 | : | 0 |
| Jul 06 • 12:00 | Jan Choinski | | - | | Hubert Hurkacz | 0 | : | 3 |
| Jul 06 • 12:00 | Tomás Martín Etcheverry | | - | | Stanislas Wawrinka | 1 | : | 3 |
| Jul 06 • 13:15 | Denis Shapovalov | | - | | Gregoire Barrere | 3 | : | 0 |
| Jul 06 • 13:15 | Andrey Rublev | | - | | Aslan Karatsev | 3 | : | 1 |
| Jul 06 • 14:30 | Milos Raonic | | - | | Tommy Paul | 1 | : | 3 |
| Jul 06 • 14:30 | Liam Broady | | - | | Casper Ruud | 3 | : | 2 |
| Jul 06 • 15:30 | Daniel Elahi Galán | | - | | Oscar Otte | 3 | : | 1 |
| Jul 06 • 15:30 | Corentin Moutet | | - | | Roman Safiullin | 0 | : | 3 |
| Jul 06 • 16:00 | Francisco Cerundolo | | - | | Jiří Lehečka | 0 | : | 3 |
| Jul 06 • 16:00 | Tomas Barrios Vera | | - | | David Goffin | 1 | : | 3 |
| Jul 06 • 16:30 | Guido Pella | | - | | Harold Mayot | 3 | : | 1 |
| Jul 06 • 17:00 | Frances Tiafoe | | - | | Dominic Stricker | 3 | : | 0 |
| Jul 06 • 17:00 | Ilya Ivashka | | - | | Grigor Dimitrov | 0 | : | 3 |
| Jul 06 • 17:15 | Mikael Ymer | | - | | Taylor Harry Fritz | 3 | : | 2 |
| Jul 06 • 17:30 | Marcos Giron | | - | | Márton Fucsovics | 1 | : | 3 |
| Jul 06 • 17:55 | Ben Shelton | | - | | Laslo Djere | 1 | : | 3 |
| Jul 06 • 18:00 | Daniil Medvedev | | - | | Adrian Mannarino | 3 | : | 0 |
| Jul 06 • 19:00 | Andy Murray | | - | | Stefanos Tsitsipas | 2 | : | 3 |
| Jul 07 • 12:00 | Roberto Carballés Baena | | - | | Holger Rune | 0 | : | 3 |
| Jul 07 • 12:00 | Christopher O'Connell | | - | | Jiří Veselý | 3 | : | 0 |
| Jul 07 • 13:30 | Jason Kubler | | - | | Nicolás Jarry | 1 | : | 3 |
| Jul 07 • 13:30 | Matteo Berrettini | | - | | Alex De Minaur | 3 | : | 0 |
| Jul 07 • 13:30 | Alejandro Davidovich Fokina | | - | | Botic van de Zandschulp | 3 | : | 1 |
| Jul 07 • 14:00 | Alexander Zverev | | - | | Yosuke Watanuki | 3 | : | 1 |
| Jul 07 • 14:30 | Carlos Alcaraz | | - | | Alexandre Muller | 3 | : | 0 |
| Jul 07 • 15:30 | Cameron Norrie | | - | | Christopher Eubanks | 1 | : | 3 |
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| Jul 07 • 13:30 | Lorenzo Musetti | | - | | Hubert Hurkacz | 0 | : | 3 |
| Jul 07 • 14:00 | Jannik Sinner | | - | | Quentin Halys | 3 | : | 1 |
| Jul 07 • 15:00 | Daniel Elahi Galán | | - | | Mikael Ymer | 3 | : | 2 |
| Jul 07 • 15:00 | Guido Pella | | - | | Roman Safiullin | 0 | : | 3 |
| Jul 07 • 15:30 | Alexander Bublik | | - | | Maximilian Marterer | 3 | : | 0 |
| Jul 07 • 16:00 | Denis Shapovalov | | - | | Liam Broady | 3 | : | 1 |
| Jul 07 • 17:00 | Andrey Rublev | | - | | David Goffin | 3 | : | 1 |
| Jul 07 • 19:00 | Stanislas Wawrinka | | - | | Novak Djokovic | 0 | : | 3 |
| Jul 08 • 12:00 | Jiří Lehečka | | - | | Tommy Paul | 3 | : | 2 |
| Jul 08 • 13:30 | Alejandro Davidovich Fokina | | - | | Holger Rune | 2 | : | 3 |
| Jul 08 • 13:30 | Christopher Eubanks | | - | | Christopher O'Connell | 3 | : | 0 |
| Jul 08 • 14:00 | Daniil Medvedev | | - | | Márton Fucsovics | 3 | : | 1 |
| Jul 08 • 14:00 | Laslo Djere | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| Jul 08 • 14:30 | Carlos Alcaraz | | - | | Nicolás Jarry | 3 | : | 1 |
| Jul 08 • 19:05 | Frances Tiafoe | | - | | Grigor Dimitrov | 0 | : | 3 |
| Jul 08 • 19:15 | Alexander Zverev | | - | | Matteo Berrettini | 0 | : | 3 |
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| Jul 09 • 13:30 | Roman Safiullin | | - | | Denis Shapovalov | 3 | : | 1 |
| Jul 09 • 14:30 | Andrey Rublev | | - | | Alexander Bublik | 3 | : | 2 |
| Jul 09 • 15:30 | Jannik Sinner | | - | | Daniel Elahi Galán | 3 | : | 0 |
| Jul 09 • 18:00 | Hubert Hurkacz | | - | | Novak Djokovic | 1 | : | 3 |
| Jul 10 • 13:30 | Christopher Eubanks | | - | | Stefanos Tsitsipas | 3 | : | 2 |
| Jul 10 • 14:00 | Daniil Medvedev | | - | | Jiří Lehečka | 2 | : | 0 |
| Jul 10 • 17:30 | Carlos Alcaraz | | - | | Matteo Berrettini | 3 | : | 1 |
| Jul 10 • 17:30 | Grigor Dimitrov | | - | | Holger Rune | 1 | : | 3 |
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| Jul 11 • 15:30 | Jannik Sinner | | - | | Roman Safiullin | 3 | : | 1 |
| Jul 11 • 16:00 | Andrey Rublev | | - | | Novak Djokovic | 1 | : | 3 |
| Jul 12 • 15:15 | Daniil Medvedev | | - | | Christopher Eubanks | 3 | : | 2 |
| Jul 12 • 15:45 | Carlos Alcaraz | | - | | Holger Rune | 3 | : | 0 |
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| Jul 14 • 14:30 | Jannik Sinner | | - | | Novak Djokovic | 0 | : | 3 |
| Jul 14 • 16:30 | Carlos Alcaraz | | - | | Daniil Medvedev | 3 | : | 0 |
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| Jul 16 • 15:00 | Carlos Alcaraz | | - | | Novak Djokovic | 3 | : | 2 |
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