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| May 26 • 11:00 | Andrey Rublev |  | - |  | Taro Daniel | 3 | : | 1 |
| May 26 • 11:00 | Pedro Martínez |  | - |  | Thiago Agustín Tirante | 3 | : | 2 |
| May 26 • 11:00 | Ugo Humbert |  | - |  | Lorenzo Sonego | 1 | : | 3 |
| May 26 • 11:00 | Zhang Zhizhen |  | - |  | Aleksandar Vukic | 3 | : | 1 |
| May 26 • 11:00 | Nicolas Moreno de Alboran |  | - | | Brandon Nakashima | 1 | : | 3 |
| May 26 • 12:30 | Jack Draper |  | - |  | Jesper de Jong | 2 | : | 3 |
| May 26 • 12:30 | Hubert Hurkacz |  | - | | Shintaro Mochizuki | 3 | : | 2 |
| May 26 • 13:15 | Aleksandar Kovacevic | | - |  | Grigor Dimitrov | 0 | : | 3 |
| May 26 • 13:30 | Jeffrey John Wolf | | - | | Carlos Alcaraz Garfia | 0 | : | 3 |
| May 26 • 13:45 | Jordan Thompson | | - |  | Maximilian Marterer | 0 | : | 3 |
| May 26 • 14:00 | Kei Nishikori | | - |  | Gabriel Diallo | 3 | : | 2 |
| May 26 • 14:30 | Luca Nardi | | - | | Alexandre Muller | 0 | : | 3 |
| May 26 • 14:30 | Richard Gasquet | | - |  | Borna Ćorić | 3 | : | 0 |
| May 26 • 18:00 | Alejandro Tabilo |  | - |  | Zizou Bergs | 1 | : | 3 |
| May 26 • 18:00 | Fábián Marozsán |  | - |  | Mikhail Kukushkin | 3 | : | 0 |
| May 26 • 19:00 | Sebastian Korda | | - | | Harold Mayot | 3 | : | 0 |
| May 26 • 20:00 | Laslo Djere |  | - | | Daniel Altmaier | 2 | : | 3 |
| May 26 • 20:00 | Nicolás Jarry | | - | | Corentin Moutet | 1 | : | 3 |
| May 26 • 20:00 | Terence Atmane | | - |  | Sebastian Ofner | 2 | : | 3 |
| May 26 • 20:15 | Stanislas Wawrinka |  | - | | Andy Murray | 3 | : | 0 |
| May 27 • 11:00 | Ben Shelton | | - | | Hugo Gaston | 3 | : | 1 |
| May 27 • 11:00 | Max Purcell | | - | | Henri Squire | 2 | : | 3 |
| May 27 • 11:00 | Yoshihito Nishioka | | - | | Felix Auger Aliassime | 0 | : | 3 |
| May 27 • 11:00 | Emil Ruusuvuori |  | - |  | Kwon Soon-woo | 0 | : | 3 |
| May 27 • 11:00 | Alexander Shevchenko | | - | | Aslan Karatsev | 3 | : | 2 |
| May 27 • 11:00 | Christopher Eubanks | | - | | Jannik Sinner | 0 | : | 3 |
| May 27 • 12:15 | Karen Khachanov | | - |  | Sumit Nagal | 3 | : | 0 |
| May 27 • 12:15 | Jozef Kovalík |  | - | | Marcos Giron | 3 | : | 1 |
| May 27 • 12:15 | Matteo Arnaldi | | - | | Arthur Fils | 3 | : | 1 |
| May 27 • 12:15 | Gustavo Heide |  | - | | Sebastián Báez | 2 | : | 3 |
| May 27 • 13:00 | Márton Fucsovics | | - |  | Stefanos Tsitsipas | 0 | : | 3 |
| May 27 • 15:00 | Cameron Norrie | | - | | Pavel Kotov | 2 | : | 3 |
| May 27 • 15:15 | Francisco Cerundolo | | - | | Yannick Hanfmann | 3 | : | 0 |
| May 27 • 15:15 | Alexander Zverev | | - | | Rafael Nadal | 3 | : | 0 |
| May 27 • 18:15 | Filip Misolic | | - | | Otto Virtanen | 3 | : | 2 |
| May 27 • 18:20 | Daniel Elahi Galán |  | - | | Lorenzo Musetti | 0 | : | 3 |
| May 27 • 18:20 | Mattia Bellucci | | - | | Frances Tiafoe | 2 | : | 3 |
| May 27 • 18:40 | Pedro Cachín | | - | | Tommy Paul | 0 | : | 3 |
| May 27 • 19:20 | Luca Van Assche | | - | | Denis Shapovalov | 0 | : | 3 |
| May 27 • 19:40 | Thiago Moura Monteiro | | - | | Miomir Kecmanovic | 1 | : | 3 |
| May 27 • 20:10 | Dušan Lajović | | - | | Roman Safiullin | 3 | : | 2 |
| May 27 • 20:15 | Gaël Monfils | | - | | Thiago Seyboth Wild | 3 | : | 1 |
| May 27 • 20:30 | Fabio Fognini | | - | | Botic van de Zandschulp | 3 | : | 0 |
| May 27 • 20:30 | Dominik Koepfer | | - | | Daniil Medvedev | 1 | : | 3 |
| May 28 • 11:00 | Arthur Rinderknech | | - | | Adam Walton | 3 | : | 0 |
| May 28 • 11:00 | Alex De Minaur | | - | | Alex Michelsen | 3 | : | 0 |
| May 28 • 11:00 | Jaume Munar | | - | | Roberto Bautista-Agut | 3 | : | 1 |
| May 28 • 11:00 | Mariano Navone | | - | | Pablo Carreño Busta | 3 | : | 1 |
| May 28 • 11:00 | Nuno Borges |  | - |  | Tomáš Macháč | 0 | : | 3 |
| May 28 • 12:30 | Tomás Martín Etcheverry | | - | | Arthur Cazaux | 3 | : | 1 |
| May 28 • 12:30 | Valentin Vacherot | | - | | Alejandro Davidovich Fokina | 1 | : | 3 |
| May 28 • 13:30 | Felipe Meligeni Alves | | - |  | Casper Ruud | 0 | : | 3 |
| May 28 • 16:25 | Taylor Harry Fritz | | - | | Federico Coria | 3 | : | 1 |
| May 28 • 18:00 | David Goffin | | - | | Giovanni Mpetshi Perricard | 3 | : | 2 |
| May 28 • 18:05 | Flavio Cobolli | | - | | Hamad Medjedovic | 3 | : | 1 |
| May 28 • 18:25 | Roman Andres Burruchaga | | - | | Jan-Lennard Struff | 0 | : | 3 |
| May 28 • 18:30 | Giulio Zeppieri | | - | | Adrian Mannarino | 3 | : | 1 |
| May 28 • 18:30 | Rinky Hijikata | | - | | Luciano Darderi | 0 | : | 3 |
| May 28 • 18:30 | Mackenzie McDonald | | - | | Tallon Griekspoor | 1 | : | 3 |
| May 28 • 18:30 | Daniel Evans | | - |  | Holger Rune | 0 | : | 3 |
| May 28 • 18:45 | Roberto Carballés Baena | | - | | Constant Lestienne | 3 | : | 1 |
| May 28 • 19:00 | Alexei Popyrin | | - | | Thanasi Kokkinakis | 2 | : | 3 |
| May 28 • 20:15 | Novak Djokovic | | - | | Pierre-Hugues Herbert | 3 | : | 0 |
| May 28 • 20:45 | Gregoire Barrere | | - | | Alexander Bublik | 0 | : | 3 |
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| May 29 • 11:00 | Daniel Altmaier | | - | | Stefanos Tsitsipas | 1 | : | 3 |
| May 29 • 12:00 | Alexandre Muller | | - | | Matteo Arnaldi | 0 | : | 3 |
| May 29 • 12:00 | Lorenzo Sonego | | - | | Zhang Zhizhen | 1 | : | 3 |
| May 29 • 12:00 | Ben Shelton | | - | | Kei Nishikori | 2 | : | 0 |
| May 29 • 12:00 | Sebastian Korda | | - | | Kwon Soon-woo | 3 | : | 1 |
| May 29 • 12:00 | Hubert Hurkacz | | - | | Brandon Nakashima | 3 | : | 1 |
| May 29 • 13:30 | Jesper de Jong | | - | | Carlos Alcaraz Garfia | 1 | : | 3 |
| May 29 • 14:30 | Andrey Rublev | | - | | Pedro Martínez | 3 | : | 0 |
| May 29 • 20:15 | Richard Gasquet | | - | | Jannik Sinner | 0 | : | 3 |
| May 29 • 20:30 | Pavel Kotov | | - | | Stanislas Wawrinka | 3 | : | 1 |
| May 30 • 11:00 | Miomir Kecmanovic | | - | | Daniil Medvedev | 0 | : | 1 |
| May 30 • 11:00 | Henri Squire | | - | | Felix Auger Aliassime | 1 | : | 3 |
| May 30 • 11:00 | Denis Shapovalov | | - | | Frances Tiafoe | 3 | : | 1 |
| May 30 • 11:00 | Zizou Bergs | | - | | Maximilian Marterer | 3 | : | 1 |
| May 30 • 11:00 | Fábián Marozsán | | - | | Grigor Dimitrov | 0 | : | 3 |
| May 30 • 11:00 | Sebastian Ofner | | - | | Sebastián Báez | 3 | : | 2 |
| May 30 • 12:30 | Luciano Darderi | | - | | Tallon Griekspoor | 0 | : | 3 |
| May 30 • 12:30 | Corentin Moutet | | - | | Alexander Shevchenko | 3 | : | 1 |
| May 30 • 13:00 | Mariano Navone | | - | | Tomáš Macháč | 2 | : | 3 |
| May 30 • 13:30 | Fabio Fognini | | - | | Tommy Paul | 0 | : | 3 |
| May 30 • 14:00 | Francisco Cerundolo | | - | | Filip Misolic | 3 | : | 0 |
| May 30 • 14:00 | Thanasi Kokkinakis | | - | | Giulio Zeppieri | 3 | : | 2 |
| May 30 • 14:00 | Flavio Cobolli | | - | | Holger Rune | 2 | : | 3 |
| May 30 • 14:30 | Alexander Zverev | | - | | David Goffin | 3 | : | 0 |
| May 30 • 14:30 | Alex De Minaur | | - | | Jaume Munar | 3 | : | 0 |
| May 30 • 14:30 | Jan-Lennard Struff | | - | | Alexander Bublik | 3 | : | 0 |
| May 30 • 16:20 | Novak Djokovic | | - | | Roberto Carballés Baena | 3 | : | 0 |
| May 30 • 19:00 | Karen Khachanov | | - | | Jozef Kovalík | 2 | : | 3 |
| May 30 • 19:10 | Alejandro Davidovich Fokina | | - | | Casper Ruud | 2 | : | 3 |
| May 30 • 19:30 | Taylor Harry Fritz | | - | | Dušan Lajović | 3 | : | 1 |
| May 30 • 20:00 | Tomás Martín Etcheverry | | - | | Arthur Rinderknech | 0 | : | 0 |
| May 30 • 20:15 | Gaël Monfils | | - | | Lorenzo Musetti | 0 | : | 3 |
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| May 31 • 12:15 | Andrey Rublev | | - | | Matteo Arnaldi | 0 | : | 3 |
| May 31 • 13:45 | Pavel Kotov | | - | | Jannik Sinner | 0 | : | 3 |
| May 31 • 17:50 | Hubert Hurkacz | | - | | Denis Shapovalov | 3 | : | 1 |
| May 31 • 18:00 | Zhang Zhizhen | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| May 31 • 18:40 | Zizou Bergs | | - | | Grigor Dimitrov | 1 | : | 3 |
| May 31 • 19:45 | Corentin Moutet | | - | | Sebastian Ofner | 3 | : | 1 |
| May 31 • 20:10 | Ben Shelton | | - | | Felix Auger Aliassime | 0 | : | 3 |
| May 31 • 20:15 | Sebastian Korda | | - | | Carlos Alcaraz Garfia | 0 | : | 3 |
| Jun 01 • 11:00 | Alex De Minaur | | - | | Jan-Lennard Struff | 3 | : | 1 |
| Jun 01 • 14:15 | Tomáš Macháč | | - | | Daniil Medvedev | 1 | : | 3 |
| Jun 01 • 15:00 | Alexander Zverev | | - | | Tallon Griekspoor | 3 | : | 2 |
| Jun 01 • 16:10 | Francisco Cerundolo | | - | | Tommy Paul | 3 | : | 1 |
| Jun 01 • 16:25 | Jozef Kovalík | | - | | Holger Rune | 0 | : | 3 |
| Jun 01 • 17:30 | Tomás Martín Etcheverry | | - | | Casper Ruud | 1 | : | 3 |
| Jun 01 • 18:00 | Taylor Harry Fritz | | - | | Thanasi Kokkinakis | 3 | : | 2 |
| Jun 01 • 20:15 | Novak Djokovic | | - | | Lorenzo Musetti | 3 | : | 2 |
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| Jun 02 • 12:30 | Matteo Arnaldi | | - | | Stefanos Tsitsipas | 1 | : | 3 |
| Jun 02 • 14:00 | Felix Auger Aliassime | | - | | Carlos Alcaraz Garfia | 0 | : | 3 |
| Jun 02 • 18:00 | Hubert Hurkacz | | - | | Grigor Dimitrov | 0 | : | 3 |
| Jun 02 • 20:15 | Corentin Moutet | | - | | Jannik Sinner | 1 | : | 3 |
| Jun 03 • 12:30 | Alex De Minaur | | - | | Daniil Medvedev | 3 | : | 1 |
| Jun 03 • 16:00 | Novak Djokovic | | - | | Francisco Cerundolo | 3 | : | 2 |
| Jun 03 • 16:00 | Taylor Harry Fritz | | - | | Casper Ruud | 1 | : | 3 |
| Jun 03 • 20:15 | Alexander Zverev | | - | | Holger Rune | 3 | : | 2 |
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| Jun 04 • 13:45 | Grigor Dimitrov | | - | | Jannik Sinner | 0 | : | 3 |
| Jun 04 • 20:15 | Stefanos Tsitsipas | | - | | Carlos Alcaraz Garfia | 0 | : | 3 |
| Jun 05 • 10:00 | Novak Djokovic | | - | | Casper Ruud | 0 | : | 0 |
| Jun 05 • 20:15 | Alexander Zverev | | - | | Alex De Minaur | 3 | : | 0 |
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| Jun 07 • 14:30 | Carlos Alcaraz Garfia | | - | | Jannik Sinner | 3 | : | 2 |
| Jun 07 • 17:30 | Casper Ruud | | - | | Alexander Zverev | 1 | : | 3 |
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| Jun 09 • 14:30 | Alexander Zverev | | - | | Carlos Alcaraz Garfia | 2 | : | 3 |
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