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| Oct 30 • 11:00 | Alejandro Davidovich Fokina |  | - |  | Ben Shelton | 2 | : | 1 |
| Oct 30 • 11:00 | Jiří Lehečka |  | - | | Roberto Bautista-Agut | 0 | : | 2 |
| Oct 30 • 11:00 | Nicolás Jarry |  | - |  | Alexei Popyrin | 2 | : | 0 |
| Oct 30 • 12:30 | Tallon Griekspoor |  | - | | Christopher Eubanks | 2 | : | 1 |
| Oct 30 • 13:00 | Frances Tiafoe | | - |  | Alexander Bublik | 0 | : | 2 |
| Oct 30 • 14:00 | Andy Murray |  | - | | Alex De Minaur | 1 | : | 2 |
| Oct 30 • 14:30 | Alexandre Muller |  | - |  | Roman Safiullin | 0 | : | 2 |
| Oct 30 • 14:45 | Karen Khachanov | | - | | Max Purcell | 2 | : | 0 |
| Oct 30 • 16:30 | Botic van de Zandschulp | | - | | Adrian Mannarino | 2 | : | 0 |
| Oct 30 • 16:30 | Laslo Djere |  | - | | Luca Van Assche | 2 | : | 1 |
| Oct 30 • 18:45 | Taylor Harry Fritz | | - |  | Sebastián Báez | 2 | : | 0 |
| Oct 30 • 19:30 | Jordan Thompson | | - |  | Yoshihito Nishioka | 1 | : | 2 |
| Oct 30 • 19:45 | Grigor Dimitrov |  | - |  | Lorenzo Musetti | 2 | : | 1 |
| Oct 30 • 21:00 | Tommy Paul | | - | | Richard Gasquet | 2 | : | 1 |
| Oct 30 • 22:45 | Stanislas Wawrinka |  | - |  | Dominic Thiem | 1 | : | 2 |
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| Oct 31 • 11:00 | Miomir Kecmanovic | | - | | Tomás Martín Etcheverry | 1 | : | 2 |
| Oct 31 • 11:00 | Dušan Lajović | | - | | Benjamin Bonzi | 2 | : | 0 |
| Oct 31 • 11:00 | Márton Fucsovics |  | - |  | Alexander Zverev | 1 | : | 2 |
| Oct 31 • 12:45 | Jeffrey John Wolf | | - | | Mackenzie McDonald | 1 | : | 2 |
| Oct 31 • 13:00 | Daniel Altmaier | | - | | Arthur Fils | 2 | : | 0 |
| Oct 31 • 13:00 | Sebastian Korda | | - |  | Hubert Hurkacz | 1 | : | 2 |
| Oct 31 • 14:45 | Felix Auger Aliassime |  | - | | Jan-Lennard Struff | 2 | : | 0 |
| Oct 31 • 15:45 | Ugo Humbert | | - | | Marcos Giron | 2 | : | 0 |
| Oct 31 • 17:00 | Gaël Monfils | | - | | Francisco Cerundolo | 1 | : | 2 |
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| Oct 31 • 16:00 | Tallon Griekspoor | | - | | Alejandro Davidovich Fokina | 2 | : | 0 |
| Oct 31 • 18:30 | Karen Khachanov | | - | | Laslo Djere | 2 | : | 0 |
| Oct 31 • 19:30 | Roman Safiullin | | - | | Carlos Alcaraz | 2 | : | 0 |
| Oct 31 • 20:00 | Alexander Bublik | | - | | Nicolás Jarry | 2 | : | 0 |
| Oct 31 • 21:45 | Yoshihito Nishioka | | - | | Andrey Rublev | 0 | : | 2 |
| Nov 01 • 11:00 | Taylor Harry Fritz | | - | | Daniel Altmaier | 0 | : | 0 |
| Nov 01 • 11:00 | Tommy Paul | | - | | Botic van de Zandschulp | 1 | : | 2 |
| Nov 01 • 11:00 | Grigor Dimitrov | | - | | Daniil Medvedev | 2 | : | 1 |
| Nov 01 • 13:55 | Roberto Bautista-Agut | | - | | Hubert Hurkacz | 0 | : | 2 |
| Nov 01 • 14:15 | Stefanos Tsitsipas |  | - | | Felix Auger Aliassime | 2 | : | 0 |
| Nov 01 • 15:10 | Dušan Lajović | | - | | Alex De Minaur | 1 | : | 2 |
| Nov 01 • 15:40 | Novak Djokovic | | - | | Tomás Martín Etcheverry | 2 | : | 0 |
| Nov 01 • 16:45 | Casper Ruud |  | - | | Francisco Cerundolo | 0 | : | 2 |
| Nov 01 • 17:45 | Ugo Humbert | | - | | Alexander Zverev | 1 | : | 2 |
| Nov 01 • 20:00 | Dominic Thiem | | - |  | Holger Rune | 0 | : | 2 |
| Nov 01 • 21:20 | Jannik Sinner | | - | | Mackenzie McDonald | 2 | : | 1 |
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| Nov 02 • 11:00 | Alexander Bublik | | - | | Grigor Dimitrov | 0 | : | 2 |
| Nov 02 • 12:30 | Botic van de Zandschulp | | - | | Andrey Rublev | 0 | : | 2 |
| Nov 02 • 12:30 | Karen Khachanov | | - | | Roman Safiullin | 2 | : | 1 |
| Nov 02 • 14:00 | Francisco Cerundolo | | - | | Hubert Hurkacz | 0 | : | 2 |
| Nov 02 • 14:00 | Stefanos Tsitsipas | | - | | Alexander Zverev | 2 | : | 0 |
| Nov 02 • 15:30 | Jannik Sinner | | - | | Alex De Minaur | 0 | : | 0 |
| Nov 02 • 19:30 | Novak Djokovic | | - | | Tallon Griekspoor | 2 | : | 1 |
| Nov 02 • 20:50 | Daniel Altmaier | | - | | Holger Rune | 0 | : | 2 |
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| Nov 03 • 14:00 | Hubert Hurkacz | | - | | Grigor Dimitrov | 1 | : | 2 |
| Nov 03 • 15:30 | Stefanos Tsitsipas | | - | | Karen Khachanov | 2 | : | 0 |
| Nov 03 • 19:30 | Novak Djokovic | | - | | Holger Rune | 2 | : | 1 |
| Nov 03 • 21:00 | Alex De Minaur | | - | | Andrey Rublev | 1 | : | 2 |
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| Nov 04 • 14:00 | Grigor Dimitrov | | - | | Stefanos Tsitsipas | 2 | : | 1 |
| Nov 04 • 17:00 | Novak Djokovic | | - | | Andrey Rublev | 2 | : | 1 |
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| Nov 05 • 15:00 | Novak Djokovic | | - | | Grigor Dimitrov | 2 | : | 0 |
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