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| Oct 28 • 11:00 | Luciano Darderi |  | - |  | Tallon Griekspoor | 0 | : | 2 |
| Oct 28 • 11:00 | Tomáš Macháč |  | - |  | Arthur Rinderknech | 0 | : | 0 |
| Oct 28 • 11:00 | Jordan Thompson |  | - |  | Pedro Martínez | 2 | : | 0 |
| Oct 28 • 12:20 | Quentin Halys | | - |  | Francisco Cerundolo | 0 | : | 2 |
| Oct 28 • 12:20 | Tomás Martín Etcheverry | | - |  | Zhang Zhizhen | 2 | : | 0 |
| Oct 28 • 13:40 | Sebastián Báez | | - |  | Miomir Kecmanovic | 1 | : | 2 |
| Oct 28 • 13:40 | Ugo Humbert | | - |  | Brandon Nakashima | 2 | : | 1 |
| Oct 28 • 13:40 | Shang Juncheng | | - | | Marcos Giron | 0 | : | 2 |
| Oct 28 • 15:30 | Fabio Fognini | | - |  | Alexander Bublik | 0 | : | 2 |
| Oct 28 • 16:50 | Nicolás Jarry |  | - | | Lorenzo Sonego | 2 | : | 0 |
| Oct 28 • 19:00 | Stefanos Tsitsipas |  | - | | Roberto Carballés Baena | 2 | : | 1 |
| Oct 28 • 19:00 | Nuno Borges |  | - | | Alejandro Tabilo | 1 | : | 2 |
| Oct 28 • 20:30 | Adrian Mannarino | | - | | Tommy Paul | 2 | : | 0 |
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| Oct 29 • 11:00 | Arthur Fils | | - |  | Marin Čilić | 2 | : | 0 |
| Oct 29 • 11:00 | Jan-Lennard Struff |  | - | | Lorenzo Musetti | 2 | : | 0 |
| Oct 29 • 11:00 | Alex Michelsen | | - |  | Hubert Hurkacz | 2 | : | 0 |
| Oct 29 • 12:30 | Frances Tiafoe | | - | | Giovanni Mpetshi Perricard | 1 | : | 2 |
| Oct 29 • 12:30 | Alexei Popyrin | | - | | Matteo Berrettini | 2 | : | 0 |
| Oct 29 • 14:00 | Matteo Arnaldi | | - |  | Holger Rune | 0 | : | 2 |
| Oct 29 • 14:00 | Karen Khachanov |  | - | | Christopher O'Connell | 2 | : | 1 |
| Oct 29 • 14:00 | Zizou Bergs |  | - | | Richard Gasquet | 2 | : | 0 |
| Oct 29 • 16:00 | Alex De Minaur | | - | | Mariano Navone | 2 | : | 0 |
| Oct 29 • 16:30 | Ben Shelton | | - | | Corentin Moutet | 2 | : | 1 |
| Oct 29 • 17:00 | Jack Draper |  | - | | Jiří Lehečka | 2 | : | 0 |
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| Oct 29 • 12:30 | Francisco Cerundolo | | - | | Andrey Rublev | 2 | : | 0 |
| Oct 29 • 18:00 | Stefanos Tsitsipas | | - | | Alejandro Tabilo | 2 | : | 0 |
| Oct 29 • 20:00 | Nicolás Jarry | | - | | Carlos Alcaraz | 0 | : | 2 |
| Oct 29 • 20:55 | Casper Ruud |  | - | | Jordan Thompson | 1 | : | 2 |
| Oct 30 • 11:00 | Grigor Dimitrov |  | - | | Tomás Martín Etcheverry | 2 | : | 1 |
| Oct 30 • 11:00 | Arthur Rinderknech | | - | | Alex Michelsen | 2 | : | 0 |
| Oct 30 • 11:00 | Alexei Popyrin | | - | | Daniil Medvedev | 2 | : | 1 |
| Oct 30 • 12:30 | Arthur Fils | | - | | Jan-Lennard Struff | 2 | : | 0 |
| Oct 30 • 12:30 | Zizou Bergs | | - | | Adrian Mannarino | 1 | : | 2 |
| Oct 30 • 12:30 | Ugo Humbert | | - | | Marcos Giron | 2 | : | 0 |
| Oct 30 • 14:00 | Alexander Bublik | | - | | Holger Rune | 0 | : | 2 |
| Oct 30 • 14:00 | Giovanni Mpetshi Perricard | | - | | Karen Khachanov | 1 | : | 2 |
| Oct 30 • 17:10 | Alex De Minaur | | - | | Miomir Kecmanovic | 2 | : | 0 |
| Oct 30 • 18:30 | Jack Draper | | - | | Taylor Harry Fritz | 2 | : | 1 |
| Oct 30 • 19:00 | Alexander Zverev | | - | | Tallon Griekspoor | 2 | : | 0 |
| Oct 30 • 20:30 | Arthur Cazaux | | - | | Ben Shelton | 2 | : | 0 |
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| Oct 31 • 11:00 | Jordan Thompson | | - | | Adrian Mannarino | 2 | : | 0 |
| Oct 31 • 12:20 | Stefanos Tsitsipas | | - | | Francisco Cerundolo | 2 | : | 1 |
| Oct 31 • 13:40 | Karen Khachanov | | - | | Alexei Popyrin | 2 | : | 0 |
| Oct 31 • 16:00 | Alex De Minaur | | - | | Jack Draper | 2 | : | 1 |
| Oct 31 • 16:00 | Alexander Zverev | | - | | Arthur Fils | 2 | : | 1 |
| Oct 31 • 17:20 | Arthur Cazaux | | - | | Holger Rune | 1 | : | 2 |
| Oct 31 • 19:00 | Ugo Humbert | | - | | Carlos Alcaraz | 2 | : | 1 |
| Oct 31 • 20:30 | Grigor Dimitrov | | - | | Arthur Rinderknech | 2 | : | 1 |
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| Nov 01 • 14:00 | Alexander Zverev | | - | | Stefanos Tsitsipas | 2 | : | 0 |
| Nov 01 • 15:30 | Holger Rune | | - | | Alex De Minaur | 2 | : | 1 |
| Nov 01 • 19:00 | Jordan Thompson | | - | | Ugo Humbert | 0 | : | 2 |
| Nov 01 • 20:30 | Grigor Dimitrov | | - | | Karen Khachanov | 0 | : | 2 |
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| Nov 02 • 14:00 | Holger Rune | | - | | Alexander Zverev | 0 | : | 2 |
| Nov 02 • 16:00 | Karen Khachanov | | - | | Ugo Humbert | 1 | : | 2 |
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| Nov 03 • 15:00 | Alexander Zverev | | - | | Ugo Humbert | 2 | : | 0 |
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