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| Aug 27 • 17:00 | Samantha Stosur |  | - |  | Petra Martic | 2 | : | 0 |
| Aug 27 • 17:00 | Li Na |  | - |  | Heather Watson | 2 | : | 0 |
| Aug 27 • 17:00 | Marion Bartoli |  | - |  | Jamie Hampton | 2 | : | 0 |
| Aug 27 • 17:00 | Sabine Lisicki |  | - |  | Sorana Cirstea | 1 | : | 2 |
| Aug 27 • 17:00 | Julia Görges | | - |  | Kristyna Pliskova | 0 | : | 2 |
| Aug 27 • 17:00 | Nadia Petrova |  | - | | Jarmila Gajdosova | 2 | : | 0 |
| Aug 27 • 17:00 | A Medina Garrigues |  | - | | Lucie Hradecka | 0 | : | 2 |
| Aug 27 • 17:00 | Mandy Minella |  | - | | Olivia Rogowska | 2 | : | 1 |
| Aug 27 • 17:00 | Stéphanie Foretz | | - | | Anna Tatishvili | 0 | : | 2 |
| Aug 27 • 17:00 | Lesia Tsurenko |  | - | | Casey Dellacqua | 0 | : | 2 |
| Aug 27 • 19:00 | Simona Halep | | - | | Iveta Benesova | 2 | : | 0 |
| Aug 27 • 21:25 | Varvara Lepchenko | | - | | Mathilde Johansson | 2 | : | 1 |
| Aug 27 • 21:50 | Alexandra Cadanțu-Ignatik | | - |  | Aleksandra Wozniak | 0 | : | 2 |
| Aug 27 • 22:10 | Romina Oprandi |  | - | | Andrea Petkovic | 2 | : | 0 |
| Aug 27 • 22:25 | Lucie Šafářová | | - | | Melanie Oudin | 2 | : | 0 |
| Aug 27 • 23:00 | Lourdes Dominguez Lino | | - |  | Sesil Karatantcheva | 2 | : | 0 |
| Aug 27 • 23:30 | Maria Sharapova | | - |  | Melinda Czink | 2 | : | 0 |
| Aug 27 • 23:30 | Petra Kvitova | | - |  | Polona Hercog | 2 | : | 0 |
| Aug 27 • 23:45 | Edina Gallovits-Hall | | - | | Stefanie Vögele | 2 | : | 0 |
| Aug 27 • 23:55 | Timea Bacsinszky | | - | | Mallory Burdette | 0 | : | 2 |
| Aug 28 • 00:15 | Samantha Crawford | | - | | Laura Robson | 0 | : | 2 |
| Aug 28 • 00:30 | Anastasia Pavlyuchenkova | | - |  | Daniela Hantuchova | 2 | : | 0 |
| Aug 28 • 00:30 | Nicole Gibbs | | - | | Alize Cornet | 0 | : | 2 |
| Aug 28 • 00:35 | Kristina Mladenovic | | - |  | Marina Erakovic | 2 | : | 0 |
| Aug 28 • 01:00 | Kim Clijsters |  | - | | Victoria Duval | 2 | : | 0 |
| Aug 28 • 01:00 | Yanina Wickmayer | | - |  | Julia Glushko | 2 | : | 0 |
| Aug 28 • 01:00 | Anastasia Rodionova | | - | | Julia Cohen | 2 | : | 0 |
| Aug 28 • 01:30 | Victoria Azarenka |  | - | | Alexandra Panova | 2 | : | 0 |
| Aug 28 • 01:30 | Su-Wei Hsieh |  | - | | Magdaléna Rybáriková | 1 | : | 2 |
| Aug 28 • 02:00 | Jie Zheng | | - | | Virginie Razzano | 1 | : | 1 |
| Aug 28 • 02:00 | Barbora Strýcová | | - | | Kirsten Flipkens | 1 | : | 2 |
| Aug 28 • 02:00 | Pauline Parmentier | | - |  | Michaella Krajicek | 2 | : | 0 |
| Aug 28 • 17:10 | Ana Ivanovic |  | - | | Elina Svitolina | 2 | : | 0 |
| Aug 28 • 17:10 | Klara Koukalová | | - | | Andrea Hlavackova | 0 | : | 2 |
| Aug 28 • 17:10 | Ksenia Pervak | | - | | Carla Suarez Navarro | 0 | : | 1 |
| Aug 28 • 17:10 | Kimiko Date-Krumm |  | - |  | Sofia Arvidsson | 0 | : | 2 |
| Aug 28 • 17:10 | Shuai Peng | | - | | Elena Vesnina | 0 | : | 2 |
| Aug 28 • 17:10 | Ekaterina Makarova | | - |  | Eleni Daniilidou | 2 | : | 0 |
| Aug 28 • 17:20 | Agnieszka Radwanska |  | - | | Nina Bratchikova | 2 | : | 0 |
| Aug 28 • 17:20 | Galina Voskoboeva |  | - | | Arantxa Rus | 2 | : | 0 |
| Aug 28 • 18:50 | Bojana Jovanovski | | - | | Mona Barthel | 2 | : | 1 |
| Aug 28 • 19:00 | Lara Arruabarrena-Vecino | | - | | Shahar Pe'er | 2 | : | 0 |
| Aug 28 • 19:20 | Monica Niculescu | | - | | Ayumi Morita | 0 | : | 2 |
| Aug 28 • 19:25 | Roberta Vinci |  | - | | Urszula Radwanska | 2 | : | 0 |
| Aug 28 • 20:30 | Dominika Cibulkova | | - | | Johanna Larsson | 2 | : | 1 |
| Aug 28 • 20:45 | Angelique Kerber | | - | | Anne Keothavong | 2 | : | 0 |
| Aug 28 • 20:50 | Vera Dushevina | | - | | Natassia Burnett | 2 | : | 0 |
| Aug 28 • 21:00 | Vania King | | - | | Yaroslava Shvedova | 0 | : | 2 |
| Aug 28 • 21:15 | Johanna Konta | | - | | Tímea Babos | 2 | : | 0 |
| Aug 28 • 21:30 | Jelena Jankovic | | - | | Kateryna Bondarenko | 2 | : | 0 |
| Aug 28 • 21:30 | Tsvetana Pironkova | | - | | Camila Giorgi | 2 | : | 0 |
| Aug 28 • 21:30 | Bethanie Mattek-Sands | | - | | Venus Williams | 0 | : | 2 |
| Aug 28 • 22:05 | Olga Puchkova | | - | | Irina Falconi | 2 | : | 1 |
| Aug 28 • 22:10 | Silvia Soler-Espinosa | | - | | Alla Kudryavtseva | 2 | : | 0 |
| Aug 28 • 22:25 | Sara Errani | | - | | Garbine Muguruza | 2 | : | 1 |
| Aug 28 • 23:00 | Tamira Paszek |  | - | | Olga Govortsova | 0 | : | 2 |
| Aug 28 • 23:40 | Francesca Schiavone | | - | | Sloane Stephens | 0 | : | 2 |
| Aug 29 • 00:25 | Agnes Szavay | | - | | Greta Arn | 0 | : | 1 |
| Aug 29 • 00:30 | Caroline Wozniacki |  | - | | Irina-Camelia Begu | 0 | : | 2 |
| Aug 29 • 00:30 | Maria Kirilenko | | - |  | Chanelle Scheepers | 2 | : | 0 |
| Aug 29 • 00:30 | Christina McHale | | - | | Kiki Bertens | 1 | : | 2 |
| Aug 29 • 00:30 | Akgul Amanmuradova |  | - | | Tatjana Maria | 1 | : | 2 |
| Aug 29 • 00:30 | Mirjana Lučić-Baroni | | - | | María José Martínez Sánchez | 0 | : | 2 |
| Aug 29 • 02:00 | Serena Williams | | - | | Coco Vandeweghe | 2 | : | 0 |
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| Aug 29 • 17:10 | Mallory Burdette | | - | | Lucie Hradecka | 2 | : | 0 |
| Aug 29 • 17:10 | Nadia Petrova | | - | | Simona Halep | 2 | : | 0 |
| Aug 29 • 17:10 | Aleksandra Wozniak | | - | | Lucie Šafářová | 1 | : | 2 |
| Aug 29 • 17:10 | Magdaléna Rybáriková | | - | | Jie Zheng | 0 | : | 2 |
| Aug 29 • 17:20 | Victoria Azarenka | | - | | Kirsten Flipkens | 2 | : | 0 |
| Aug 29 • 18:35 | Varvara Lepchenko | | - | | Anastasia Rodionova | 2 | : | 0 |
| Aug 29 • 19:05 | Kristyna Pliskova | | - | | Mandy Minella | 0 | : | 2 |
| Aug 29 • 19:35 | Yanina Wickmayer | | - | | Pauline Parmentier | 0 | : | 2 |
| Aug 29 • 19:50 | Alize Cornet | | - | | Petra Kvitova | 0 | : | 2 |
| Aug 29 • 21:10 | Li Na | | - | | Casey Dellacqua | 2 | : | 0 |
| Aug 29 • 21:50 | Anna Tatishvili | | - | | Sorana Cirstea | 2 | : | 1 |
| Aug 29 • 21:55 | Kristina Mladenovic | | - | | Anastasia Pavlyuchenkova | 2 | : | 0 |
| Aug 29 • 22:30 | Laura Robson | | - | | Kim Clijsters | 2 | : | 0 |
| Aug 29 • 23:55 | Marion Bartoli | | - | | Romina Oprandi | 2 | : | 1 |
| Aug 30 • 00:20 | Edina Gallovits-Hall | | - | | Samantha Stosur | 0 | : | 2 |
| Aug 30 • 01:00 | Maria Sharapova | | - | | Lourdes Dominguez Lino | 2 | : | 0 |
| Aug 30 • 17:05 | Sofia Arvidsson | | - | | Ana Ivanovic | 0 | : | 2 |
| Aug 30 • 17:05 | Galina Voskoboeva | | - | | Andrea Hlavackova | 1 | : | 2 |
| Aug 30 • 17:05 | Maria Kirilenko | | - | | Greta Arn | 2 | : | 0 |
| Aug 30 • 17:05 | Dominika Cibulkova | | - | | Bojana Jovanovski | 2 | : | 0 |
| Aug 30 • 17:05 | Jelena Jankovic | | - | | Lara Arruabarrena-Vecino | 2 | : | 0 |
| Aug 30 • 19:20 | Tsvetana Pironkova | | - | | Ayumi Morita | 2 | : | 0 |
| Aug 30 • 19:50 | Elena Vesnina | | - | | Ekaterina Makarova | 0 | : | 2 |
| Aug 30 • 20:20 | Irina-Camelia Begu | | - | | Silvia Soler-Espinosa | 0 | : | 2 |
| Aug 30 • 20:20 | Carla Suarez Navarro | | - | | Agnieszka Radwanska | 1 | : | 2 |
| Aug 30 • 20:55 | Yaroslava Shvedova | | - | | Roberta Vinci | 1 | : | 2 |
| Aug 30 • 21:30 | Sloane Stephens | | - | | Tatjana Maria | 2 | : | 1 |
| Aug 30 • 22:55 | María José Martínez Sánchez | | - | | Serena Williams | 0 | : | 2 |
| Aug 31 • 00:00 | Kiki Bertens | | - | | Olga Puchkova | 1 | : | 2 |
| Aug 31 • 00:05 | Johanna Konta | | - | | Olga Govortsova | 1 | : | 2 |
| Aug 31 • 01:00 | Vera Dushevina | | - | | Sara Errani | 0 | : | 2 |
| Aug 31 • 03:00 | Angelique Kerber | | - | | Venus Williams | 2 | : | 1 |
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| Aug 31 • 17:10 | Li Na | | - | | Laura Robson | 1 | : | 2 |
| Aug 31 • 17:15 | Marion Bartoli | | - | | Kristina Mladenovic | 2 | : | 0 |
| Aug 31 • 17:20 | Varvara Lepchenko | | - | | Samantha Stosur | 0 | : | 2 |
| Aug 31 • 19:35 | Pauline Parmentier | | - | | Petra Kvitova | 0 | : | 2 |
| Aug 31 • 21:05 | Nadia Petrova | | - | | Lucie Šafářová | 2 | : | 0 |
| Aug 31 • 21:15 | Maria Sharapova | | - | | Mallory Burdette | 2 | : | 0 |
| Sep 01 • 01:10 | Mandy Minella | | - | | Anna Tatishvili | 0 | : | 2 |
| Sep 01 • 02:00 | Victoria Azarenka | | - | | Jie Zheng | 2 | : | 0 |
| Sep 01 • 17:10 | Jelena Jankovic | | - | | Agnieszka Radwanska | 0 | : | 2 |
| Sep 01 • 17:15 | Dominika Cibulkova | | - | | Roberta Vinci | 0 | : | 2 |
| Sep 01 • 19:15 | Ekaterina Makarova | | - | | Serena Williams | 0 | : | 2 |
| Sep 01 • 20:40 | Maria Kirilenko | | - | | Andrea Hlavackova | 1 | : | 2 |
| Sep 01 • 21:00 | Silvia Soler-Espinosa | | - | | Tsvetana Pironkova | 1 | : | 2 |
| Sep 01 • 23:45 | Angelique Kerber | | - | | Olga Govortsova | 2 | : | 0 |
| Sep 01 • 23:45 | Olga Puchkova | | - | | Sara Errani | 0 | : | 2 |
| Sep 02 • 01:15 | Sloane Stephens | | - | | Ana Ivanovic | 1 | : | 2 |
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| Sep 02 • 23:00 | Laura Robson | | - | | Samantha Stosur | 0 | : | 2 |
| Sep 03 • 00:25 | Victoria Azarenka | | - | | Anna Tatishvili | 2 | : | 0 |
| Sep 03 • 00:30 | Marion Bartoli | | - | | Petra Kvitova | 2 | : | 1 |
| Sep 03 • 01:00 | Maria Sharapova | | - | | Nadia Petrova | 2 | : | 1 |
| Sep 03 • 17:10 | Tsvetana Pironkova | | - | | Ana Ivanovic | 0 | : | 2 |
| Sep 03 • 19:20 | Andrea Hlavackova | | - | | Serena Williams | 0 | : | 2 |
| Sep 03 • 19:30 | Angelique Kerber | | - | | Sara Errani | 0 | : | 2 |
| Sep 03 • 21:50 | Roberta Vinci | | - | | Agnieszka Radwanska | 2 | : | 0 |
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| Sep 04 • 17:00 | Victoria Azarenka | | - | | Samantha Stosur | 2 | : | 1 |
| Sep 04 • 22:30 | Maria Sharapova | | - | | Marion Bartoli | 2 | : | 1 |
| Sep 05 • 19:00 | Sara Errani | | - | | Roberta Vinci | 2 | : | 0 |
| Sep 06 • 01:00 | Ana Ivanovic | | - | | Serena Williams | 0 | : | 2 |
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| Sep 07 • 20:40 | Victoria Azarenka | | - | | Maria Sharapova | 2 | : | 1 |
| Sep 07 • 23:30 | Serena Williams | | - | | Sara Errani | 2 | : | 0 |
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| Sep 09 • 22:30 | Victoria Azarenka | | - | | Serena Williams | 1 | : | 2 |
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