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| May 26 • 11:00 | Blaž Kavčič |  | - |  | James Duckworth | 3 | : | 0 |
| May 26 • 11:00 | Milos Raonic |  | - |  | Xavier Malisse | 3 | : | 1 |
| May 26 • 11:00 | Illya Marchenko |  | - |  | Kevin Anderson | 0 | : | 3 |
| May 26 • 11:00 | João Sousa |  | - |  | Go Soeda | 3 | : | 0 |
| May 26 • 12:15 | Gilles Simon |  | - | | Lleyton Hewitt | 3 | : | 2 |
| May 26 • 12:25 | Roberto Bautista-Agut |  | - |  | Gilles Müller | 3 | : | 0 |
| May 26 • 13:40 | Andreas Seppi |  | - |  | Leonardo Mayer | 3 | : | 2 |
| May 26 • 14:30 | Lukáš Lacko |  | - |  | Sam Querrey | 0 | : | 3 |
| May 26 • 14:30 | Pablo Carreño Busta | | - |  | Roger Federer | 0 | : | 3 |
| May 26 • 14:40 | Jan Hájek |  | - | | Denis Kudla | 3 | : | 1 |
| May 26 • 14:40 | Somdev Devvarman |  | - | | Daniel Muñoz de la Nava | 3 | : | 0 |
| May 26 • 15:00 | Benjamin Becker |  | - | | Jérémy Chardy | 0 | : | 3 |
| May 26 • 15:55 | Marinko Matosevic | | - | | David Ferrer | 0 | : | 3 |
| May 26 • 16:10 | Steve Darcis | | - | | Michaël Llodra | 1 | : | 3 |
| May 26 • 18:30 | Marcel Granollers | | - | | Feliciano López | 2 | : | 3 |
| May 26 • 18:50 | Viktor Troicki |  | - | | James Blake | 3 | : | 0 |
| May 27 • 11:00 | Jesse Levine | | - | | Kei Nishikori | 0 | : | 3 |
| May 27 • 11:00 | Igor Sijsling |  | - |  | Jürgen Melzer | 3 | : | 0 |
| May 27 • 11:00 | Jurgen Zopp |  | - | | Tommy Robredo | 0 | : | 3 |
| May 27 • 11:00 | Martín Alund | | - | | Édouard Roger-Vasselin | 1 | : | 3 |
| May 27 • 11:00 | Jan-Lennard Struff | | - |  | Evgeny Donskoy | 1 | : | 3 |
| May 27 • 11:00 | Radek Štěpánek | | - | | Nick Kyrgios | 0 | : | 3 |
| May 27 • 11:00 | Adrian Mannarino | | - |  | Pablo Cuevas | 2 | : | 3 |
| May 27 • 11:00 | Tobias Kamke | | - | | Paolo Lorenzi | 3 | : | 2 |
| May 27 • 12:20 | Julien Benneteau | | - |  | Ričardas Berankis | 3 | : | 1 |
| May 27 • 12:25 | Jo-Wilfried Tsonga | | - | | Aljaž Bedene | 3 | : | 0 |
| May 27 • 12:30 | Grega Žemlja | | - |  | Santiago Giraldo | 3 | : | 0 |
| May 27 • 13:15 | Rafael Nadal | | - | | Daniel Brands | 3 | : | 1 |
| May 27 • 13:20 | Andreas Haider-Maurer | | - | | Nicolás Almagro | 1 | : | 3 |
| May 27 • 14:00 | Philipp Petzschner | | - |  | Marin Čilić | 0 | : | 3 |
| May 27 • 14:35 | Andrey Kuznetsov | | - | | Ryan Harrison | 0 | : | 3 |
| May 27 • 14:50 | Martin Kližan | | - | | Michael Russell | 2 | : | 1 |
| May 27 • 14:50 | Pere Riba | | - | | Lukáš Rosol | 0 | : | 3 |
| May 27 • 15:00 | Andreas Beck | | - | | Fabio Fognini | 0 | : | 3 |
| May 27 • 15:15 | Paul-Henri Mathieu | | - |  | Jarkko Nieminen | 2 | : | 3 |
| May 27 • 15:15 | Juan Mónaco | | - | | Daniel Gimeno-Traver | 2 | : | 3 |
| May 27 • 15:20 | Ernests Gulbis |  | - |  | Rogério Dutra da Silva | 3 | : | 0 |
| May 27 • 16:05 | Sergiy Stakhovsky | | - | | Richard Gasquet | 0 | : | 3 |
| May 27 • 16:10 | Kenny de Schepper | | - | | Robin Haase | 1 | : | 3 |
| May 27 • 16:30 | Tomáš Berdych | | - | | Gaël Monfils | 2 | : | 3 |
| May 27 • 17:05 | Carlos Berlocq | | - | | John Isner | 0 | : | 3 |
| May 27 • 17:40 | Michał Przysiężny |  | - | | Rhyne Williams | 3 | : | 1 |
| May 27 • 17:40 | Steve Johnson | | - | | Albert Montañés | 2 | : | 3 |
| May 27 • 18:20 | Albert Ramos-Viñolas | | - | | Jerzy Janowicz | 0 | : | 3 |
| May 28 • 11:00 | Alex Kuznetsov | | - | | Lucas Pouille | 0 | : | 3 |
| May 28 • 11:00 | Alejandro Falla | | - |  | Grigor Dimitrov | 0 | : | 1 |
| May 28 • 11:00 | Alexandr Dolgopolov | | - | | Dmitry Tursunov | 0 | : | 3 |
| May 28 • 11:00 | Bernard Tomic | | - |  | Victor Hănescu | 0 | : | 2 |
| May 28 • 11:00 | Tommy Haas | | - | | Guillaume Rufin | 3 | : | 0 |
| May 28 • 11:00 | Jack Sock | | - | | Guillermo García López | 3 | : | 0 |
| May 28 • 11:00 | Mikhail Youzhny | | - | | Pablo Andújar | 3 | : | 1 |
| May 28 • 11:00 | Federico Delbonis | | - | | Julian Reister | 3 | : | 1 |
| May 28 • 15:10 | Florent Serra | | - | | Nikolay Davydenko | 0 | : | 3 |
| May 28 • 15:55 | Stanislas Wawrinka | | - | | Thiemo de Bakker | 3 | : | 1 |
| May 28 • 16:00 | Novak Djokovic | | - | | David Goffin | 3 | : | 0 |
| May 28 • 16:00 | Ivan Dodig | | - | | Guido Pella | 2 | : | 3 |
| May 28 • 16:15 | Jiří Veselý | | - | | Philipp Kohlschreiber | 1 | : | 3 |
| May 28 • 16:15 | Florian Mayer | | - |  | Denis Istomin | 1 | : | 2 |
| May 28 • 16:30 | Simone Bolelli | | - |  | Lu Yen-Hsun | 0 | : | 2 |
| May 28 • 16:35 | Vasek Pospisil | | - | | Horacio Zeballos | 2 | : | 3 |
| May 28 • 17:00 | Fernando Verdasco | | - | | Marc Gicquel | 3 | : | 0 |
| May 28 • 17:20 | Nicolas Mahut | | - | | Janko Tipsarević | 0 | : | 3 |
| May 28 • 17:45 | Benoît Paire | | - |  | Marcos Baghdatis | 3 | : | 1 |
| May 28 • 17:50 | Łukasz Kubot | | - | | Maxime Teixeira | 3 | : | 1 |
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| May 29 • 11:00 | Feliciano López | | - | | João Sousa | 3 | : | 1 |
| May 29 • 11:00 | Albert Montañés | | - | | David Ferrer | 0 | : | 3 |
| May 29 • 11:00 | Daniel Gimeno-Traver | | - | | Viktor Troicki | 2 | : | 3 |
| May 29 • 11:00 | Nick Kyrgios | | - | | Marin Čilić | 0 | : | 3 |
| May 29 • 12:40 | Evgeny Donskoy | | - | | Kevin Anderson | 1 | : | 3 |
| May 29 • 12:40 | Jo-Wilfried Tsonga | | - | | Jarkko Nieminen | 3 | : | 0 |
| May 29 • 13:30 | Andreas Seppi | | - | | Blaž Kavčič | 3 | : | 2 |
| May 29 • 14:25 | Igor Sijsling | | - | | Tommy Robredo | 2 | : | 3 |
| May 29 • 14:30 | Milos Raonic | | - | | Michaël Llodra | 3 | : | 1 |
| May 29 • 14:30 | Gilles Simon | | - | | Pablo Cuevas | 3 | : | 1 |
| May 29 • 14:45 | Roberto Bautista-Agut | | - | | Jérémy Chardy | 0 | : | 3 |
| May 29 • 15:00 | Julien Benneteau | | - | | Tobias Kamke | 3 | : | 2 |
| May 29 • 15:10 | Gaël Monfils | | - | | Ernests Gulbis | 3 | : | 1 |
| May 29 • 15:15 | Édouard Roger-Vasselin | | - | | Nicolás Almagro | 0 | : | 3 |
| May 29 • 17:20 | Jan Hájek | | - | | Sam Querrey | 0 | : | 3 |
| May 29 • 17:30 | Somdev Devvarman | | - | | Roger Federer | 0 | : | 3 |
| May 30 • 11:00 | Grega Žemlja | | - | | Kei Nishikori | 1 | : | 3 |
| May 30 • 11:00 | Dmitry Tursunov | | - | | Victor Hănescu | 0 | : | 1 |
| May 30 • 11:00 | Lucas Pouille | | - | | Grigor Dimitrov | 0 | : | 3 |
| May 30 • 11:00 | Lu Yen-Hsun | | - | | Philipp Kohlschreiber | 0 | : | 0 |
| May 30 • 12:15 | Novak Djokovic | | - | | Guido Pella | 3 | : | 0 |
| May 30 • 12:30 | Lukáš Rosol | | - | | Fabio Fognini | 1 | : | 3 |
| May 30 • 12:30 | Stanislas Wawrinka | | - | | Horacio Zeballos | 3 | : | 0 |
| May 30 • 12:30 | Benoît Paire | | - | | Łukasz Kubot | 3 | : | 0 |
| May 30 • 14:00 | Mikhail Youzhny | | - | | Federico Delbonis | 3 | : | 1 |
| May 30 • 15:30 | Denis Istomin | | - | | Nikolay Davydenko | 1 | : | 3 |
| May 31 • 11:00 | Rafael Nadal | | - | | Martin Kližan | 3 | : | 1 |
| May 31 • 11:00 | Ryan Harrison | | - | | John Isner | 2 | : | 3 |
| May 31 • 11:00 | Michał Przysiężny | | - | | Richard Gasquet | 0 | : | 3 |
| May 31 • 11:00 | Robin Haase | | - | | Jerzy Janowicz | 1 | : | 3 |
| May 31 • 11:00 | Tommy Haas | | - | | Jack Sock | 3 | : | 0 |
| May 31 • 11:00 | Fernando Verdasco | | - | | Janko Tipsarević | 2 | : | 3 |
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| May 31 • 12:30 | Feliciano López | | - | | David Ferrer | 0 | : | 3 |
| May 31 • 13:00 | Julien Benneteau | | - | | Roger Federer | 0 | : | 3 |
| May 31 • 13:30 | Milos Raonic | | - | | Kevin Anderson | 0 | : | 3 |
| May 31 • 14:00 | Viktor Troicki | | - | | Marin Čilić | 3 | : | 0 |
| May 31 • 14:00 | Gilles Simon | | - | | Sam Querrey | 3 | : | 2 |
| May 31 • 14:00 | Gaël Monfils | | - | | Tommy Robredo | 2 | : | 3 |
| May 31 • 14:30 | Jo-Wilfried Tsonga | | - | | Jérémy Chardy | 3 | : | 0 |
| May 31 • 15:00 | Andreas Seppi | | - | | Nicolás Almagro | 0 | : | 3 |
| Jun 01 • 11:00 | Benoît Paire | | - | | Kei Nishikori | 1 | : | 3 |
| Jun 01 • 14:00 | Rafael Nadal | | - | | Fabio Fognini | 3 | : | 0 |
| Jun 01 • 14:00 | Tommy Haas | | - | | John Isner | 3 | : | 2 |
| Jun 01 • 14:00 | Mikhail Youzhny | | - | | Janko Tipsarević | 3 | : | 0 |
| Jun 01 • 14:00 | Nikolay Davydenko | | - | | Richard Gasquet | 0 | : | 3 |
| Jun 01 • 15:30 | Victor Hănescu | | - | | Philipp Kohlschreiber | 0 | : | 3 |
| Jun 01 • 15:30 | Stanislas Wawrinka | | - | | Jerzy Janowicz | 3 | : | 1 |
| Jun 01 • 16:00 | Novak Djokovic | | - | | Grigor Dimitrov | 3 | : | 0 |
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| Jun 02 • 11:00 | Kevin Anderson | | - | | David Ferrer | 0 | : | 3 |
| Jun 02 • 12:30 | Tommy Robredo | | - | | Nicolás Almagro | 3 | : | 2 |
| Jun 02 • 14:00 | Jo-Wilfried Tsonga | | - | | Viktor Troicki | 3 | : | 0 |
| Jun 02 • 15:30 | Gilles Simon | | - | | Roger Federer | 2 | : | 3 |
| Jun 03 • 11:00 | Tommy Haas | | - | | Mikhail Youzhny | 3 | : | 0 |
| Jun 03 • 12:30 | Novak Djokovic | | - | | Philipp Kohlschreiber | 3 | : | 1 |
| Jun 03 • 14:30 | Rafael Nadal | | - | | Kei Nishikori | 3 | : | 0 |
| Jun 03 • 14:30 | Stanislas Wawrinka | | - | | Richard Gasquet | 3 | : | 2 |
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| Jun 04 • 15:30 | David Ferrer | | - | | Tommy Robredo | 3 | : | 0 |
| Jun 04 • 15:30 | Jo-Wilfried Tsonga | | - | | Roger Federer | 3 | : | 0 |
| Jun 05 • 15:30 | Novak Djokovic | | - | | Tommy Haas | 3 | : | 0 |
| Jun 05 • 15:30 | Rafael Nadal | | - | | Stanislas Wawrinka | 3 | : | 0 |
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| Jun 07 • 13:00 | Novak Djokovic | | - | | Rafael Nadal | 2 | : | 3 |
| Jun 07 • 15:30 | David Ferrer | | - | | Jo-Wilfried Tsonga | 3 | : | 0 |
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| Jun 09 • 15:00 | Rafael Nadal | | - | | David Ferrer | 3 | : | 0 |
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