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| Jun 24 • 12:35 | Stéphane Robert |  | - |  | Alejandro Falla | 3 | : | 0 |
| Jun 24 • 12:35 | Adrian Ungur |  | - | | Benoît Paire | 1 | : | 3 |
| Jun 24 • 12:35 | Fabio Fognini |  | - |  | Jürgen Melzer | 1 | : | 3 |
| Jun 24 • 12:35 | Julian Reister |  | - |  | Lukáš Rosol | 3 | : | 2 |
| Jun 24 • 12:35 | Rogério Dutra da Silva |  | - |  | Sergiy Stakhovsky | 0 | : | 3 |
| Jun 24 • 13:45 | Łukasz Kubot |  | - |  | Igor Andreev | 3 | : | 0 |
| Jun 24 • 13:45 | Marinko Matosevic |  | - | | Guillaume Rufin | 1 | : | 3 |
| Jun 24 • 14:05 | Victor Hănescu | | - |  | Roger Federer | 0 | : | 3 |
| Jun 24 • 14:10 | Marcos Baghdatis |  | - |  | Marin Čilić | 0 | : | 3 |
| Jun 24 • 14:15 | Robin Haase |  | - | | Mikhail Youzhny | 0 | : | 3 |
| Jun 24 • 14:20 | Kyle Edmund |  | - | | Jerzy Janowicz | 0 | : | 3 |
| Jun 24 • 15:15 | John Isner |  | - | | Evgeny Donskoy | 3 | : | 0 |
| Jun 24 • 15:25 | Marc Gicquel | | - |  | Vasek Pospisil | 0 | : | 3 |
| Jun 24 • 15:30 | Andrey Kuznetsov | | - |  | Albert Montañés | 3 | : | 1 |
| Jun 24 • 15:50 | Janko Tipsarević |  | - | | Viktor Troicki | 0 | : | 3 |
| Jun 24 • 15:55 | Ernests Gulbis |  | - | | Édouard Roger-Vasselin | 3 | : | 0 |
| Jun 24 • 16:00 | Jo-Wilfried Tsonga | | - |  | David Goffin | 3 | : | 0 |
| Jun 24 • 16:05 | Rafael Nadal | | - | | Steve Darcis | 0 | : | 3 |
| Jun 24 • 16:10 | Pablo Andújar | | - | | Adrian Mannarino | 0 | : | 3 |
| Jun 24 • 16:10 | Juan Mónaco |  | - | | Bastian Knittel | 3 | : | 0 |
| Jun 24 • 16:20 | Lukáš Lacko |  | - | | Rajeev Ram | 1 | : | 3 |
| Jun 24 • 16:20 | Kenny de Schepper | | - | | Paolo Lorenzi | 3 | : | 0 |
| Jun 24 • 16:30 | Fernando Verdasco | | - | | Xavier Malisse | 3 | : | 1 |
| Jun 24 • 16:50 | Nicolás Almagro | | - |  | Jurgen Zopp | 3 | : | 0 |
| Jun 24 • 16:55 | Radek Štěpánek | | - | | Matt Reid | 3 | : | 0 |
| Jun 24 • 17:10 | James Ward | | - |  | Lu Yen-Hsun | 1 | : | 3 |
| Jun 24 • 17:20 | Tobias Kamke | | - | | Julien Benneteau | 1 | : | 3 |
| Jun 24 • 17:30 | Dustin Brown | | - | | Guillermo García López | 3 | : | 0 |
| Jun 24 • 17:40 | Benjamin Becker | | - | | Andy Murray | 0 | : | 3 |
| Jun 24 • 18:00 | Nicolas Mahut | | - | | Jan Hájek | 3 | : | 0 |
| Jun 24 • 18:45 | Tommy Robredo | | - | | Alex Bogomolov Jr | 3 | : | 0 |
| Jun 24 • 19:20 | Lleyton Hewitt | | - | | Stanislas Wawrinka | 3 | : | 0 |
| Jun 25 • 12:30 | Blaž Kavčič |  | - | | Jan-Lennard Struff | 0 | : | 3 |
| Jun 25 • 12:30 | Thiemo de Bakker | | - | | James Blake | 0 | : | 3 |
| Jun 25 • 12:30 | Kevin Anderson |  | - | | Olivier Rochus | 3 | : | 0 |
| Jun 25 • 12:30 | Philipp Petzschner | | - | | Michał Przysiężny | 0 | : | 3 |
| Jun 25 • 12:30 | James Duckworth | | - | | Denis Kudla | 2 | : | 3 |
| Jun 25 • 12:30 | Ivan Dodig | | - | | Philipp Kohlschreiber | 2 | : | 2 |
| Jun 25 • 12:30 | Leonardo Mayer | | - | | Aljaž Bedene | 3 | : | 0 |
| Jun 25 • 12:30 | Guido Pella | | - | | Jesse Levine | 2 | : | 2 |
| Jun 25 • 13:40 | Kei Nishikori |  | - | | Matthew Ebden | 3 | : | 0 |
| Jun 25 • 13:45 | Dmitry Tursunov | | - | | Tommy Haas | 0 | : | 3 |
| Jun 25 • 13:55 | Ryan Harrison | | - | | Jérémy Chardy | 1 | : | 3 |
| Jun 25 • 13:55 | Bernard Tomic | | - | | Sam Querrey | 3 | : | 2 |
| Jun 25 • 14:00 | Michaël Llodra | | - |  | Jarkko Nieminen | 3 | : | 0 |
| Jun 25 • 14:00 | Albert Ramos-Viñolas | | - | | Juan Martín del Potro | 0 | : | 3 |
| Jun 25 • 14:25 | Wayne Odesnik | | - | | Jimmy Wang | 2 | : | 3 |
| Jun 25 • 15:05 | Denis Istomin |  | - | | Andreas Seppi | 2 | : | 3 |
| Jun 25 • 15:25 | Novak Djokovic | | - | | Florian Mayer | 3 | : | 0 |
| Jun 25 • 16:10 | Andreas Haider-Maurer | | - | | Go Soeda | 0 | : | 3 |
| Jun 25 • 16:10 | Gastão Elias |  | - | | Alexandr Dolgopolov | 0 | : | 3 |
| Jun 25 • 16:25 | Horacio Zeballos | | - | | Santiago Giraldo | 2 | : | 3 |
| Jun 25 • 16:35 | Roberto Bautista-Agut | | - | | Teymuraz Gabashvili | 3 | : | 0 |
| Jun 25 • 16:40 | Richard Gasquet | | - | | Marcel Granollers | 3 | : | 1 |
| Jun 25 • 17:00 | Alex Kuznetsov | | - | | Igor Sijsling | 0 | : | 3 |
| Jun 25 • 17:10 | Milos Raonic | | - | | Carlos Berlocq | 3 | : | 0 |
| Jun 25 • 17:25 | Grigor Dimitrov |  | - | | Simone Bolelli | 3 | : | 0 |
| Jun 25 • 17:40 | David Ferrer | | - | | Martín Alund | 3 | : | 1 |
| Jun 25 • 17:55 | Martin Kližan | | - | | Tomáš Berdych | 0 | : | 3 |
| Jun 25 • 18:20 | Daniel Brands | | - | | Daniel Gimeno-Traver | 3 | : | 2 |
| Jun 25 • 18:30 | Ričardas Berankis |  | - | | Paul-Henri Mathieu | 1 | : | 3 |
| Jun 25 • 18:40 | Bobby Reynolds | | - | | Steve Johnson | 3 | : | 2 |
| Jun 25 • 18:40 | Gilles Simon | | - | | Feliciano López | 0 | : | 3 |
| Jun 25 • 18:40 | Grega Žemlja | | - | | Michael Russell | 3 | : | 1 |
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| Jun 26 • 12:30 | John Isner | | - | | Adrian Mannarino | 0 | : | 0 |
| Jun 26 • 12:30 | Radek Štěpánek | | - | | Jerzy Janowicz | 0 | : | 1 |
| Jun 26 • 12:30 | Viktor Troicki | | - | | Andrey Kuznetsov | 3 | : | 0 |
| Jun 26 • 12:30 | Dustin Brown | | - | | Lleyton Hewitt | 3 | : | 1 |
| Jun 26 • 13:30 | Nicolás Almagro | | - | | Guillaume Rufin | 3 | : | 1 |
| Jun 26 • 14:05 | Vasek Pospisil | | - | | Mikhail Youzhny | 2 | : | 3 |
| Jun 26 • 14:10 | Fernando Verdasco | | - | | Julien Benneteau | 3 | : | 0 |
| Jun 26 • 14:20 | Stéphane Robert | | - | | Benoît Paire | 0 | : | 3 |
| Jun 26 • 14:20 | Steve Darcis | | - | | Łukasz Kubot | 0 | : | 0 |
| Jun 26 • 15:40 | Jo-Wilfried Tsonga | | - | | Ernests Gulbis | 1 | : | 2 |
| Jun 26 • 16:50 | Jürgen Melzer | | - | | Julian Reister | 3 | : | 1 |
| Jun 26 • 16:55 | Tommy Robredo | | - | | Nicolas Mahut | 3 | : | 0 |
| Jun 26 • 16:55 | Lu Yen-Hsun | | - | | Andy Murray | 0 | : | 3 |
| Jun 26 • 17:20 | Kenny de Schepper | | - | | Marin Čilić | 0 | : | 0 |
| Jun 26 • 18:00 | Sergiy Stakhovsky | | - | | Roger Federer | 3 | : | 1 |
| Jun 26 • 18:00 | Juan Mónaco | | - | | Rajeev Ram | 3 | : | 1 |
| Jun 27 • 12:30 | Michaël Llodra | | - | | Andreas Seppi | 0 | : | 1 |
| Jun 27 • 14:00 | James Blake | | - | | Bernard Tomic | 0 | : | 3 |
| Jun 27 • 14:00 | Kevin Anderson | | - | | Michał Przysiężny | 3 | : | 0 |
| Jun 27 • 14:00 | Kei Nishikori | | - | | Leonardo Mayer | 3 | : | 0 |
| Jun 27 • 14:00 | Jesse Levine | | - | | Juan Martín del Potro | 0 | : | 3 |
| Jun 27 • 14:00 | Daniel Brands | | - | | Tomáš Berdych | 0 | : | 3 |
| Jun 27 • 14:00 | Grigor Dimitrov | | - | | Grega Žemlja | 2 | : | 3 |
| Jun 27 • 15:40 | Richard Gasquet | | - | | Go Soeda | 3 | : | 1 |
| Jun 27 • 15:45 | Milos Raonic | | - | | Igor Sijsling | 0 | : | 3 |
| Jun 27 • 16:00 | Denis Kudla | | - | | Ivan Dodig | 0 | : | 3 |
| Jun 27 • 16:25 | Feliciano López | | - | | Paul-Henri Mathieu | 1 | : | 0 |
| Jun 27 • 16:50 | Jan-Lennard Struff | | - | | Jérémy Chardy | 1 | : | 3 |
| Jun 27 • 17:00 | Santiago Giraldo | | - | | Alexandr Dolgopolov | 0 | : | 3 |
| Jun 27 • 18:00 | Novak Djokovic | | - | | Bobby Reynolds | 3 | : | 0 |
| Jun 28 • 12:30 | Jimmy Wang | | - | | Tommy Haas | 0 | : | 3 |
| Jun 28 • 12:30 | David Ferrer | | - | | Roberto Bautista-Agut | 3 | : | 1 |
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| Jun 28 • 15:25 | Jürgen Melzer | | - | | Sergiy Stakhovsky | 3 | : | 1 |
| Jun 28 • 16:00 | Nicolás Almagro | | - | | Jerzy Janowicz | 0 | : | 3 |
| Jun 28 • 18:00 | Adrian Mannarino | | - | | Dustin Brown | 3 | : | 0 |
| Jun 28 • 18:30 | Tommy Robredo | | - | | Andy Murray | 0 | : | 3 |
| Jun 29 • 12:30 | Viktor Troicki | | - | | Mikhail Youzhny | 0 | : | 3 |
| Jun 29 • 12:30 | Łukasz Kubot | | - | | Benoît Paire | 3 | : | 0 |
| Jun 29 • 12:30 | Ernests Gulbis | | - | | Fernando Verdasco | 0 | : | 3 |
| Jun 29 • 12:30 | Juan Mónaco | | - | | Kenny de Schepper | 0 | : | 3 |
| Jun 29 • 12:30 | Kei Nishikori | | - | | Andreas Seppi | 2 | : | 3 |
| Jun 29 • 14:00 | Richard Gasquet | | - | | Bernard Tomic | 1 | : | 3 |
| Jun 29 • 14:45 | Kevin Anderson | | - | | Tomáš Berdych | 1 | : | 3 |
| Jun 29 • 16:20 | Igor Sijsling | | - | | Ivan Dodig | 0 | : | 2 |
| Jun 29 • 16:35 | Grega Žemlja | | - | | Juan Martín del Potro | 0 | : | 3 |
| Jun 29 • 17:20 | Feliciano López | | - | | Tommy Haas | 1 | : | 3 |
| Jun 29 • 18:00 | David Ferrer | | - | | Alexandr Dolgopolov | 3 | : | 2 |
| Jun 29 • 19:25 | Novak Djokovic | | - | | Jérémy Chardy | 3 | : | 0 |
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| Jul 01 • 12:30 | Jerzy Janowicz | | - | | Jürgen Melzer | 3 | : | 2 |
| Jul 01 • 12:30 | Łukasz Kubot | | - | | Adrian Mannarino | 3 | : | 2 |
| Jul 01 • 12:30 | David Ferrer | | - | | Ivan Dodig | 3 | : | 1 |
| Jul 01 • 15:30 | Fernando Verdasco | | - | | Kenny de Schepper | 3 | : | 0 |
| Jul 01 • 16:05 | Andreas Seppi | | - | | Juan Martín del Potro | 0 | : | 3 |
| Jul 01 • 16:35 | Mikhail Youzhny | | - | | Andy Murray | 0 | : | 3 |
| Jul 01 • 18:50 | Bernard Tomic | | - | | Tomáš Berdych | 1 | : | 3 |
| Jul 01 • 19:00 | Novak Djokovic | | - | | Tommy Haas | 3 | : | 0 |
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| Jul 03 • 14:00 | David Ferrer | | - | | Juan Martín del Potro | 0 | : | 3 |
| Jul 03 • 14:00 | Novak Djokovic | | - | | Tomáš Berdych | 3 | : | 0 |
| Jul 03 • 16:00 | Łukasz Kubot | | - | | Jerzy Janowicz | 0 | : | 3 |
| Jul 03 • 16:00 | Fernando Verdasco | | - | | Andy Murray | 2 | : | 3 |
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| Jul 05 • 14:00 | Novak Djokovic | | - | | Juan Martín del Potro | 3 | : | 2 |
| Jul 05 • 17:30 | Jerzy Janowicz | | - | | Andy Murray | 1 | : | 3 |
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| Jul 07 • 15:00 | Novak Djokovic | | - | | Andy Murray | 0 | : | 3 |
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