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| Oct 28 • 11:00 | Adrian Mannarino |  | - |  | Santiago Giraldo | 1 | : | 2 |
| Oct 28 • 11:00 | Lukáš Rosol |  | - | | Jérémy Chardy | 2 | : | 0 |
| Oct 28 • 12:30 | Feliciano López |  | - |  | Bernard Tomic | 2 | : | 1 |
| Oct 28 • 13:10 | Denis Istomin |  | - |  | Robin Haase | 0 | : | 2 |
| Oct 28 • 15:00 | Ernests Gulbis |  | - | | Fernando Verdasco | 0 | : | 2 |
| Oct 28 • 15:00 | Igor Sijsling | | - |  | Marin Čilić | 1 | : | 2 |
| Oct 28 • 15:30 | Andreas Seppi |  | - |  | Philipp Kohlschreiber | 1 | : | 2 |
| Oct 28 • 19:30 | Kei Nishikori |  | - | | Julien Benneteau | 2 | : | 0 |
| Oct 28 • 20:30 | Benoît Paire | | - | | Pierre-Hugues Herbert | 0 | : | 2 |
| Oct 29 • 11:00 | Michaël Llodra | | - |  | Grigor Dimitrov | 1 | : | 2 |
| Oct 29 • 11:00 | Michał Przysiężny |  | - |  | Jarkko Nieminen | 2 | : | 0 |
| Oct 29 • 12:30 | Gaël Monfils | | - |  | Vasek Pospisil | 0 | : | 0 |
| Oct 29 • 12:30 | Nicolas Mahut | | - |  | Alexandr Dolgopolov | 2 | : | 0 |
| Oct 29 • 14:00 | Édouard Roger-Vasselin | | - | | Ivan Dodig | 0 | : | 2 |
| Oct 29 • 16:15 | Dmitry Tursunov |  | - | | Marcel Granollers | 0 | : | 2 |
| Oct 29 • 17:30 | Kevin Anderson |  | - | | Mikhail Youzhny | 1 | : | 1 |
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| Oct 29 • 16:05 | Richard Gasquet | | - | | Fernando Verdasco | 2 | : | 1 |
| Oct 29 • 19:30 | Kei Nishikori | | - | | Jo-Wilfried Tsonga | 2 | : | 1 |
| Oct 29 • 19:45 | Santiago Giraldo | | - | | Jerzy Janowicz | 0 | : | 2 |
| Oct 29 • 21:50 | Pierre-Hugues Herbert | | - |  | Novak Djokovic | 0 | : | 2 |
| Oct 30 • 10:30 | David Ferrer | | - | | Lukáš Rosol | 2 | : | 1 |
| Oct 30 • 11:00 | John Isner |  | - | | Michał Przysiężny | 2 | : | 1 |
| Oct 30 • 12:30 | Nicolas Mahut | | - | | Gilles Simon | 1 | : | 2 |
| Oct 30 • 13:15 | Ivan Dodig | | - | | Nicolás Almagro | 0 | : | 2 |
| Oct 30 • 14:30 | Stanislas Wawrinka |  | - | | Feliciano López | 2 | : | 1 |
| Oct 30 • 14:50 | Marin Čilić | | - |  | Juan Martín del Potro | 0 | : | 2 |
| Oct 30 • 16:30 | Fabio Fognini | | - | | Grigor Dimitrov | 1 | : | 2 |
| Oct 30 • 17:10 | Rafael Nadal | | - | | Marcel Granollers | 2 | : | 0 |
| Oct 30 • 18:45 | Philipp Kohlschreiber | | - | | Tommy Haas | 2 | : | 0 |
| Oct 30 • 20:25 | Pablo Andújar | | - | | Tomáš Berdych | 0 | : | 2 |
| Oct 30 • 20:25 | Roger Federer | | - | | Kevin Anderson | 2 | : | 0 |
| Oct 30 • 22:00 | Milos Raonic | | - | | Robin Haase | 2 | : | 0 |
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| Oct 31 • 10:30 | Stanislas Wawrinka | | - | | Nicolás Almagro | 2 | : | 0 |
| Oct 31 • 12:00 | David Ferrer | | - | | Gilles Simon | 2 | : | 0 |
| Oct 31 • 14:00 | John Isner | | - | | Novak Djokovic | 1 | : | 2 |
| Oct 31 • 14:30 | Grigor Dimitrov | | - | | Juan Martín del Potro | 1 | : | 2 |
| Oct 31 • 15:30 | Roger Federer | | - | | Philipp Kohlschreiber | 2 | : | 0 |
| Oct 31 • 16:30 | Milos Raonic | | - | | Tomáš Berdych | 0 | : | 2 |
| Oct 31 • 19:30 | Richard Gasquet | | - | | Kei Nishikori | 2 | : | 0 |
| Oct 31 • 20:30 | Rafael Nadal | | - | | Jerzy Janowicz | 2 | : | 0 |
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| Nov 01 • 14:00 | Stanislas Wawrinka | | - | | Novak Djokovic | 0 | : | 2 |
| Nov 01 • 15:45 | Roger Federer | | - | | Juan Martín del Potro | 2 | : | 1 |
| Nov 01 • 19:30 | Rafael Nadal | | - | | Richard Gasquet | 2 | : | 0 |
| Nov 01 • 21:00 | David Ferrer | | - | | Tomáš Berdych | 2 | : | 1 |
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| Nov 02 • 14:30 | Roger Federer | | - | | Novak Djokovic | 1 | : | 2 |
| Nov 02 • 17:00 | Rafael Nadal | | - | | David Ferrer | 0 | : | 2 |
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| Nov 03 • 15:00 | David Ferrer | | - | | Novak Djokovic | 0 | : | 2 |
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