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| May 25 • 11:00 | Mikhail Youzhny |  | - |  | Pablo Carreño Busta | 3 | : | 2 |
| May 25 • 11:00 | Milos Raonic |  | - |  | Nick Kyrgios | 3 | : | 0 |
| May 25 • 11:15 | Somdev Devvarman |  | - |  | Aleksandr Nedovyesov | 1 | : | 3 |
| May 25 • 11:15 | Radek Štěpánek |  | - |  | Facundo Argüello | 3 | : | 2 |
| May 25 • 11:15 | Jarkko Nieminen |  | - |  | Michał Przysiężny | 3 | : | 2 |
| May 25 • 12:30 | Lukáš Lacko |  | - |  | Roger Federer | 0 | : | 3 |
| May 25 • 13:45 | Tomáš Berdych | | - | | Peter Polansky | 3 | : | 0 |
| May 25 • 14:40 | Gastão Elias |  | - | | Diego Schwartzman | 0 | : | 3 |
| May 25 • 15:00 | Víctor Estrella Burgos |  | - | | Jerzy Janowicz | 1 | : | 3 |
| May 25 • 15:15 | Pierre-Hugues Herbert |  | - |  | John Isner | 0 | : | 3 |
| May 25 • 16:00 | Jo-Wilfried Tsonga | | - | | Édouard Roger-Vasselin | 3 | : | 0 |
| May 25 • 16:15 | Dmitry Tursunov | | - |  | Potito Starace | 3 | : | 0 |
| May 25 • 16:25 | Filippo Volandri | | - | | Sam Querrey | 0 | : | 3 |
| May 25 • 18:00 | Alexandr Dolgopolov |  | - | | Albert Ramos-Viñolas | 3 | : | 0 |
| May 25 • 18:40 | Jérémy Chardy | | - | | Daniel Gimeno-Traver | 3 | : | 0 |
| May 25 • 19:10 | David Goffin |  | - |  | Jürgen Melzer | 1 | : | 3 |
| May 26 • 11:00 | Alejandro Falla |  | - | | Benoît Paire | 0 | : | 3 |
| May 26 • 11:00 | Albert Montañés | | - | | Kenny de Schepper | 0 | : | 0 |
| May 26 • 11:00 | Nicolas Mahut | | - | | Mikhail Kukushkin | 1 | : | 3 |
| May 26 • 11:00 | Lukáš Rosol | | - | | Jiří Veselý | 0 | : | 3 |
| May 26 • 11:00 | Robin Haase |  | - | | Nikolay Davydenko | 3 | : | 0 |
| May 26 • 11:00 | Martin Kližan | | - |  | Kei Nishikori | 3 | : | 0 |
| May 26 • 11:00 | Marin Čilić |  | - | | Pablo Andújar | 3 | : | 0 |
| May 26 • 11:00 | Miloslav Mečíř, Jr. | | - |  | Tobias Kamke | 0 | : | 3 |
| May 26 • 13:30 | Tommy Robredo | | - |  | James Ward | 3 | : | 1 |
| May 26 • 13:30 | Michael Russell | | - | | Alejandro González | 1 | : | 3 |
| May 26 • 13:30 | Ante Pavić | | - | | Gilles Simon | 0 | : | 3 |
| May 26 • 13:30 | Ivan Dodig | | - | | Marcel Granollers | 0 | : | 0 |
| May 26 • 13:30 | João Sousa | | - |  | Novak Djokovic | 0 | : | 3 |
| May 26 • 15:50 | Teymuraz Gabashvili | | - | | Vasek Pospisil | 3 | : | 0 |
| May 26 • 15:50 | Damir Džumhur |  | - | | Feliciano López | 0 | : | 3 |
| May 26 • 15:50 | Paolo Lorenzi | | - | | Roberto Bautista-Agut | 0 | : | 3 |
| May 26 • 15:50 | Facundo Bagnis | | - | | Julien Benneteau | 3 | : | 2 |
| May 26 • 16:15 | Benjamin Becker | | - |  | Thomaz Bellucci | 2 | : | 3 |
| May 26 • 17:10 | Łukasz Kubot | | - |  | Ernests Gulbis | 1 | : | 3 |
| May 26 • 17:15 | Rafael Nadal | | - | | Robby Ginepri | 3 | : | 0 |
| May 26 • 17:15 | Andreas Beck | | - | | Fabio Fognini | 0 | : | 3 |
| May 26 • 17:30 | Adrian Mannarino | | - |  | Lu Yen-Hsun | 3 | : | 0 |
| May 26 • 17:30 | Donald Young | | - |  | Dudi Sela | 3 | : | 1 |
| May 26 • 18:00 | James Duckworth | | - | | Leonardo Mayer | 1 | : | 3 |
| May 26 • 18:30 | Paul-Henri Mathieu | | - | | Dominic Thiem | 0 | : | 3 |
| May 26 • 18:45 | Stanislas Wawrinka | | - | | Guillermo García López | 1 | : | 3 |
| May 27 • 11:00 | Grigor Dimitrov |  | - | | Ivo Karlović | 0 | : | 3 |
| May 27 • 11:00 | Axel Michon | | - | | Bradley Klahn | 3 | : | 2 |
| May 27 • 11:00 | Andreas Seppi | | - | | Santiago Giraldo | 3 | : | 0 |
| May 27 • 11:00 | Lleyton Hewitt | | - | | Carlos Berlocq | 1 | : | 3 |
| May 27 • 12:30 | Igor Sijsling | | - | | David Ferrer | 0 | : | 3 |
| May 27 • 12:30 | Philipp Kohlschreiber | | - | | Pere Riba | 3 | : | 0 |
| May 27 • 12:30 | Sergiy Stakhovsky | | - |  | Denis Istomin | 1 | : | 3 |
| May 27 • 13:00 | Juan Mónaco | | - | | Lucas Pouille | 3 | : | 0 |
| May 27 • 13:05 | Stéphane Robert | | - |  | Kevin Anderson | 0 | : | 3 |
| May 27 • 13:10 | Andreas Haider-Maurer | | - | | Daniel Brands | 3 | : | 2 |
| May 27 • 13:30 | Simone Bolelli | | - | | Andrea Arnaboldi | 3 | : | 0 |
| May 27 • 13:30 | Richard Gasquet | | - | | Bernard Tomic | 3 | : | 0 |
| May 27 • 14:00 | Dušan Lajović | | - | | Federico Delbonis | 3 | : | 0 |
| May 27 • 14:00 | Matthew Ebden | | - |  | Pablo Cuevas | 0 | : | 3 |
| May 27 • 14:30 | Jurgen Zopp |  | - | | Tommy Haas | 0 | : | 0 |
| May 27 • 15:15 | Nicolás Almagro | | - | | Jack Sock | 0 | : | 0 |
| May 27 • 15:15 | Michaël Llodra | | - | | Fernando Verdasco | 0 | : | 3 |
| May 27 • 15:30 | Marinko Matosevic | | - | | Dustin Brown | 3 | : | 1 |
| May 27 • 15:30 | Andrey Golubev | | - | | Andy Murray | 1 | : | 3 |
| May 27 • 16:00 | Gaël Monfils | | - |  | Victor Hănescu | 3 | : | 1 |
| May 27 • 16:00 | Albano Olivetti | | - | | Jan-Lennard Struff | 0 | : | 3 |
| May 27 • 17:40 | Steve Johnson | | - | | Laurent Lokoli | 3 | : | 2 |
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| May 28 • 11:00 | Benoît Paire | | - | | Roberto Bautista-Agut | 0 | : | 3 |
| May 28 • 11:00 | Mikhail Youzhny | | - | | Radek Štěpánek | 1 | : | 3 |
| May 28 • 11:00 | Facundo Bagnis | | - | | Ernests Gulbis | 0 | : | 3 |
| May 28 • 11:00 | Alejandro González | | - | | Gilles Simon | 0 | : | 3 |
| May 28 • 11:00 | Alexandr Dolgopolov | | - | | Marcel Granollers | 2 | : | 3 |
| May 28 • 13:00 | Dmitry Tursunov | | - | | Sam Querrey | 3 | : | 0 |
| May 28 • 13:25 | Jérémy Chardy | | - | | Novak Djokovic | 0 | : | 3 |
| May 28 • 13:30 | Robin Haase | | - | | Martin Kližan | 2 | : | 3 |
| May 28 • 13:30 | Marin Čilić | | - | | Tobias Kamke | 3 | : | 1 |
| May 28 • 13:45 | Milos Raonic | | - | | Jiří Veselý | 3 | : | 0 |
| May 28 • 14:00 | Tomáš Berdych | | - | | Aleksandr Nedovyesov | 3 | : | 1 |
| May 28 • 14:45 | Diego Schwartzman | | - | | Roger Federer | 0 | : | 3 |
| May 28 • 15:30 | Tommy Robredo | | - | | Kenny de Schepper | 3 | : | 0 |
| May 28 • 15:30 | Jo-Wilfried Tsonga | | - | | Jürgen Melzer | 3 | : | 0 |
| May 28 • 16:00 | Jarkko Nieminen | | - | | Jerzy Janowicz | 0 | : | 3 |
| May 28 • 17:00 | Mikhail Kukushkin | | - | | John Isner | 1 | : | 3 |
| May 29 • 11:00 | Ivo Karlović | | - | | Andreas Haider-Maurer | 3 | : | 0 |
| May 29 • 11:00 | Axel Michon | | - | | Kevin Anderson | 0 | : | 3 |
| May 29 • 11:00 | Simone Bolelli | | - | | David Ferrer | 0 | : | 3 |
| May 29 • 11:00 | Donald Young | | - | | Feliciano López | 3 | : | 0 |
| May 29 • 12:30 | Rafael Nadal | | - | | Dominic Thiem | 3 | : | 0 |
| May 29 • 12:30 | Leonardo Mayer | | - | | Teymuraz Gabashvili | 3 | : | 1 |
| May 29 • 12:30 | Guillermo García López | | - | | Adrian Mannarino | 3 | : | 1 |
| May 29 • 13:00 | Andreas Seppi | | - | | Juan Mónaco | 3 | : | 0 |
| May 29 • 13:30 | Dušan Lajović | | - | | Jurgen Zopp | 3 | : | 0 |
| May 29 • 14:00 | Pablo Cuevas | | - | | Fernando Verdasco | 2 | : | 3 |
| May 29 • 14:00 | Philipp Kohlschreiber | | - | | Denis Istomin | 3 | : | 0 |
| May 29 • 14:30 | Jack Sock | | - | | Steve Johnson | 3 | : | 0 |
| May 29 • 14:30 | Richard Gasquet | | - | | Carlos Berlocq | 3 | : | 0 |
| May 29 • 14:30 | Marinko Matosevic | | - | | Andy Murray | 0 | : | 3 |
| May 29 • 16:00 | Gaël Monfils | | - | | Jan-Lennard Struff | 3 | : | 0 |
| May 29 • 16:00 | Thomaz Bellucci | | - | | Fabio Fognini | 0 | : | 3 |
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| May 30 • 11:00 | Radek Štěpánek | | - | | Ernests Gulbis | 0 | : | 3 |
| May 30 • 12:30 | Dmitry Tursunov | | - | | Roger Federer | 1 | : | 3 |
| May 30 • 12:30 | Marin Čilić | | - | | Novak Djokovic | 1 | : | 3 |
| May 30 • 14:30 | Tommy Robredo | | - | | John Isner | 1 | : | 3 |
| May 30 • 14:30 | Jo-Wilfried Tsonga | | - | | Jerzy Janowicz | 3 | : | 0 |
| May 30 • 15:30 | Tomáš Berdych | | - | | Roberto Bautista-Agut | 3 | : | 1 |
| May 30 • 15:30 | Marcel Granollers | | - | | Martin Kližan | 3 | : | 1 |
| May 30 • 17:30 | Milos Raonic | | - | | Gilles Simon | 3 | : | 2 |
| May 31 • 11:00 | Jack Sock | | - | | Dušan Lajović | 0 | : | 3 |
| May 31 • 11:00 | Andreas Seppi | | - | | David Ferrer | 0 | : | 3 |
| May 31 • 12:30 | Rafael Nadal | | - | | Leonardo Mayer | 3 | : | 0 |
| May 31 • 12:30 | Ivo Karlović | | - | | Kevin Anderson | 0 | : | 1 |
| May 31 • 14:00 | Gaël Monfils | | - | | Fabio Fognini | 3 | : | 2 |
| May 31 • 14:30 | Guillermo García López | | - | | Donald Young | 3 | : | 2 |
| May 31 • 16:00 | Richard Gasquet | | - | | Fernando Verdasco | 0 | : | 3 |
| May 31 • 16:00 | Philipp Kohlschreiber | | - | | Andy Murray | 2 | : | 3 |
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| Jun 01 • 11:00 | Tomáš Berdych | | - | | John Isner | 3 | : | 0 |
| Jun 01 • 12:30 | Ernests Gulbis | | - | | Roger Federer | 3 | : | 2 |
| Jun 01 • 14:30 | Milos Raonic | | - | | Marcel Granollers | 3 | : | 0 |
| Jun 01 • 14:30 | Jo-Wilfried Tsonga | | - | | Novak Djokovic | 0 | : | 3 |
| Jun 02 • 11:00 | Kevin Anderson | | - | | David Ferrer | 1 | : | 3 |
| Jun 02 • 12:30 | Rafael Nadal | | - | | Dušan Lajović | 3 | : | 0 |
| Jun 02 • 14:30 | Fernando Verdasco | | - | | Andy Murray | 0 | : | 3 |
| Jun 02 • 15:30 | Guillermo García López | | - | | Gaël Monfils | 0 | : | 3 |
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| Jun 03 • 15:30 | Tomáš Berdych | | - | | Ernests Gulbis | 0 | : | 3 |
| Jun 03 • 15:30 | Milos Raonic | | - | | Novak Djokovic | 0 | : | 3 |
| Jun 04 • 15:30 | Rafael Nadal | | - | | David Ferrer | 3 | : | 1 |
| Jun 04 • 15:30 | Gaël Monfils | | - | | Andy Murray | 2 | : | 3 |
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| Jun 06 • 13:00 | Ernests Gulbis | | - | | Novak Djokovic | 1 | : | 3 |
| Jun 06 • 15:00 | Rafael Nadal | | - | | Andy Murray | 3 | : | 0 |
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| Jun 08 • 15:00 | Rafael Nadal | | - | | Novak Djokovic | 3 | : | 1 |
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