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| Sep 03 • 18:00 | UD Somozas | | - | | CD Varea | 3 | : | 0 |
| Sep 03 • 19:30 | SD Leioa | | - | | Sestao River Club | 1 | : | 0 |
| Sep 03 • 20:00 | CD Izarra | | - | | Atlético Granadilla | 1 | : | 0 |
| Sep 03 • 20:00 | CD Puertollano | | - | | CD Teruel | 0 | : | 3 |
| Sep 03 • 20:15 | Barakaldo CF | | - | | Trival Valderas | 3 | : | 0 |
| Sep 03 • 20:30 | Racing de Ferrol | | - | | Atlético Astorga | 5 | : | 1 |
| Sep 03 • 20:30 | Gimnástica de Torrelavega | | - | | CD Lealtad | 1 | : | 2 |
| Sep 03 • 20:30 | Real Avilés | | - | | Marino de Luanco | 0 | : | 0 |
| Sep 03 • 20:30 | SD Huesca | | - | | CD Toledo | 2 | : | 1 |
| Sep 03 • 20:30 | Gimnàstic de Tarragona | | - | | Atlético Baleares | 0 | : | 0 |
| Sep 03 • 20:30 | CD Alcoyano | | - | | SCR Peña Deportiva | 1 | : | 1 |
| Sep 03 • 20:30 | Real Oviedo | | - | | SD Amorebieta | 4 | : | 0 |
| Sep 03 • 20:30 | UE Cornellà | | - | | Real Jaén | 0 | : | 0 |
| Sep 03 • 21:00 | Hércules CF | | - | | CD Eldense | 2 | : | 2 |
| Sep 03 • 21:00 | CD San Roque de Lepe | | - | | Cádiz CF | 0 | : | 3 |
| Sep 03 • 21:00 | Marbella FC | | - | | Real Balompédica Linense | 0 | : | 1 |
| Sep 03 • 21:00 | FC Cartagena | | - | | UCAM Murcia | 0 | : | 1 |
| Sep 03 • 21:00 | La Hoya Lorca CF | | - | | CF Villanovense | 2 | : | 2 |
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| Sep 09 • 20:00 | Girona FC | | - | | CD Tenerife | 0 | : | 0 |
| Sep 09 • 22:00 | Deportivo Alavés | | - | | CA Osasuna | 2 | : | 0 |
| Sep 10 • 19:30 | SD Leioa | | - | | CD Teruel | 2 | : | 0 |
| Sep 10 • 20:00 | CD Izarra | | - | | UD Somozas | 3 | : | 1 |
| Sep 10 • 20:00 | Sporting de Gijon | | - | | Real Valladolid | 1 | : | 3 |
| Sep 10 • 20:00 | Real Betis | | - | | UE Llagostera | 2 | : | 0 |
| Sep 10 • 20:00 | Albacete Balompié | | - | | Real Zaragoza | 1 | : | 0 |
| Sep 10 • 20:30 | CD Alcoyano | | - | | Gimnàstic de Tarragona | 1 | : | 0 |
| Sep 10 • 20:30 | Real Avilés | | - | | Barakaldo CF | 0 | : | 1 |
| Sep 10 • 20:30 | UCAM Murcia | | - | | CD Eldense | 1 | : | 1 |
| Sep 10 • 20:45 | CD Mirandés | | - | | Racing de Ferrol | 4 | : | 1 |
| Sep 10 • 21:00 | CD Guijuelo | | - | | CE L'Hospitalet | 0 | : | 1 |
| Sep 10 • 21:00 | Lleida CF | | - | | CD Guadalajara | 3 | : | 0 |
| Sep 10 • 21:00 | CF Villanovense | | - | | SD Huesca | 2 | : | 2 |
| Sep 10 • 21:00 | Cádiz CF | | - | | CD Lealtad | 2 | : | 1 |
| Sep 10 • 21:00 | Real Balompédica Linense | | - | | CF Fuenlabrada | 4 | : | 1 |
| Sep 10 • 21:00 | UE Cornellà | | - | | Zamora CF | 3 | : | 2 |
| Sep 10 • 21:00 | Recreativo Huelva | | - | | SD Ponferradina | 2 | : | 1 |
| Sep 10 • 21:00 | Real Murcia | | - | | CE Sabadell | 1 | : | 2 |
| Sep 10 • 21:00 | CD Leganés | | - | | CD Numancia | 1 | : | 1 |
| Sep 10 • 22:00 | RCD Mallorca | | - | | UD Las Palmas | 0 | : | 2 |
| Sep 11 • 21:00 | CD Lugo | | - | | AD Alcorcón | 1 | : | 0 |
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| Oct 14 • 20:00 | CD Mirandés | | - | | Deportivo Alavés | 0 | : | 1 |
| Oct 14 • 22:00 | Albacete Balompié | | - | | Recreativo Huelva | 2 | : | 1 |
| Oct 15 • 20:00 | CE L'Hospitalet | | - | | CD Izarra | 3 | : | 2 |
| Oct 15 • 20:00 | Real Valladolid | | - | | Girona FC | 2 | : | 0 |
| Oct 15 • 20:30 | CD Alcoyano | | - | | Lleida CF | 1 | : | 0 |
| Oct 15 • 20:30 | Real Oviedo | | - | | UCAM Murcia | 1 | : | 0 |
| Oct 15 • 20:30 | SD Huesca | | - | | Barakaldo CF | 2 | : | 1 |
| Oct 15 • 21:00 | UE Cornellà | | - | | SD Leioa | 2 | : | 1 |
| Oct 15 • 21:00 | Real Balompédica Linense | | - | | Cádiz CF | 1 | : | 2 |
| Oct 15 • 22:00 | Real Betis | | - | | CD Lugo | 0 | : | 0 |
| Oct 16 • 21:00 | UD Las Palmas | | - | | CD Numancia | 2 | : | 0 |
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| Oct 29 • 20:00 | UE Cornellà | | - | | Real Madrid | 1 | : | 4 |
| Oct 29 • 22:00 | CE Sabadell | | - | | Sevilla FC | 1 | : | 6 |
| Dec 02 • 20:00 | CD Alcoyano | | - | | Athletic Bilbao | 1 | : | 1 |
| Dec 02 • 20:00 | Deportivo Alavés | | - | | RCD Espanyol | 0 | : | 2 |
| Dec 02 • 22:00 | UD Las Palmas | | - | | Celta de Vigo | 2 | : | 1 |
| Dec 02 • 22:00 | Real Valladolid | | - | | Elche CF | 0 | : | 0 |
| Dec 03 • 20:00 | CE L'Hospitalet | | - | | Atlético Madrid | 0 | : | 3 |
| Dec 03 • 20:00 | Deportivo La Coruña | | - | | Málaga CF | 1 | : | 1 |
| Dec 03 • 22:00 | Granada CF | | - | | Córdoba CF | 1 | : | 0 |
| Dec 03 • 22:00 | SD Huesca | | - | | FC Barcelona | 0 | : | 4 |
| Dec 04 • 20:00 | Cádiz CF | | - | | Villarreal CF | 1 | : | 2 |
| Dec 04 • 20:00 | Real Oviedo | | - | | Real Sociedad | 0 | : | 0 |
| Dec 04 • 22:00 | Rayo Vallecano | | - | | Valencia CF | 1 | : | 2 |
| Dec 05 • 20:00 | Albacete Balompié | | - | | Levante UD | 1 | : | 1 |
| Dec 05 • 20:00 | Getafe CF | | - | | SD Eibar | 3 | : | 0 |
| Dec 05 • 22:00 | Real Betis | | - | | UD Almeria | 3 | : | 4 |
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| Dec 02 • 20:00 | Real Madrid | | - | | UE Cornellà | 5 | : | 0 |
| Dec 03 • 20:00 | Sevilla FC | | - | | CE Sabadell | 5 | : | 1 |
| Dec 16 • 20:00 | Celta de Vigo | | - | | UD Las Palmas | 3 | : | 1 |
| Dec 16 • 20:00 | Valencia CF | | - | | Rayo Vallecano | 4 | : | 4 |
| Dec 16 • 22:00 | FC Barcelona | | - | | SD Huesca | 8 | : | 1 |
| Dec 16 • 22:00 | UD Almeria | | - | | Real Betis | 2 | : | 1 |
| Dec 17 • 20:00 | RCD Espanyol | | - | | Deportivo Alavés | 1 | : | 0 |
| Dec 17 • 20:00 | Levante UD | | - | | Albacete Balompié | 0 | : | 0 |
| Dec 17 • 20:00 | SD Eibar | | - | | Getafe CF | 1 | : | 2 |
| Dec 17 • 22:00 | Córdoba CF | | - | | Granada CF | 1 | : | 1 |
| Dec 17 • 22:00 | Villarreal CF | | - | | Cádiz CF | 3 | : | 0 |
| Dec 17 • 22:00 | Real Sociedad | | - | | Real Oviedo | 2 | : | 0 |
| Dec 18 • 20:00 | Elche CF | | - | | Real Valladolid | 1 | : | 0 |
| Dec 18 • 20:00 | Atlético Madrid | | - | | CE L'Hospitalet | 2 | : | 2 |
| Dec 18 • 22:00 | Athletic Bilbao | | - | | CD Alcoyano | 1 | : | 0 |
| Dec 18 • 22:00 | Málaga CF | | - | | Deportivo La Coruña | 4 | : | 1 |
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| Jan 06 • 17:00 | Celta de Vigo | | - | | Athletic Bilbao | 2 | : | 4 |
| Jan 06 • 19:00 | Málaga CF | | - | | Levante UD | 2 | : | 0 |
| Jan 07 • 20:00 | Villarreal CF | | - | | Real Sociedad | 1 | : | 0 |
| Jan 07 • 21:00 | Atlético Madrid | | - | | Real Madrid | 2 | : | 0 |
| Jan 07 • 22:00 | Valencia CF | | - | | RCD Espanyol | 2 | : | 1 |
| Jan 07 • 22:00 | UD Almeria | | - | | Getafe CF | 1 | : | 1 |
| Jan 08 • 20:00 | Granada CF | | - | | Sevilla FC | 1 | : | 2 |
| Jan 08 • 22:00 | FC Barcelona | | - | | Elche CF | 5 | : | 0 |
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| Jan 13 • 20:00 | RCD Espanyol | | - | | Valencia CF | 2 | : | 0 |
| Jan 13 • 22:00 | Levante UD | | - | | Málaga CF | 3 | : | 2 |
| Jan 14 • 20:00 | Real Sociedad | | - | | Villarreal CF | 2 | : | 2 |
| Jan 14 • 20:00 | Getafe CF | | - | | UD Almeria | 1 | : | 0 |
| Jan 14 • 20:00 | Athletic Bilbao | | - | | Celta de Vigo | 0 | : | 2 |
| Jan 14 • 22:00 | Sevilla FC | | - | | Granada CF | 4 | : | 0 |
| Jan 15 • 20:00 | Real Madrid | | - | | Atlético Madrid | 2 | : | 2 |
| Jan 15 • 22:00 | Elche CF | | - | | FC Barcelona | 0 | : | 4 |
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| Jan 21 • 20:00 | Villarreal CF | | - | | Getafe CF | 1 | : | 0 |
| Jan 21 • 22:00 | FC Barcelona | | - | | Atlético Madrid | 1 | : | 0 |
| Jan 21 • 22:00 | Málaga CF | | - | | Athletic Bilbao | 0 | : | 0 |
| Jan 22 • 22:00 | RCD Espanyol | | - | | Sevilla FC | 3 | : | 1 |
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| Jan 28 • 21:00 | Atlético Madrid | | - | | FC Barcelona | 2 | : | 3 |
| Jan 29 • 20:00 | Getafe CF | | - | | Villarreal CF | 0 | : | 1 |
| Jan 29 • 22:00 | Athletic Bilbao | | - | | Málaga CF | 1 | : | 0 |
| Jan 29 • 22:00 | Sevilla FC | | - | | RCD Espanyol | 1 | : | 0 |
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| Feb 11 • 20:00 | FC Barcelona | | - | | Villarreal CF | 3 | : | 1 |
| Feb 11 • 22:00 | Athletic Bilbao | | - | | RCD Espanyol | 1 | : | 1 |
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| Mar 04 • 20:00 | Villarreal CF | | - | | FC Barcelona | 1 | : | 3 |
| Mar 04 • 22:00 | RCD Espanyol | | - | | Athletic Bilbao | 0 | : | 2 |
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| May 30 • 21:30 | Athletic Bilbao | | - | | FC Barcelona | 1 | : | 3 |
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