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| Oct 01 • 06:30 | Feliciano López |  | - |  | Borna Ćorić | 2 | : | 1 |
| Oct 01 • 08:30 | Karen Khachanov |  | - |  | Sam Querrey | 2 | : | 0 |
| Oct 01 • 09:30 | Andreas Seppi |  | - |  | Márton Fucsovics | 0 | : | 2 |
| Oct 01 • 10:00 | Kyle Edmund |  | - |  | Peter Gojowczyk | 2 | : | 1 |
| Oct 01 • 11:00 | Vasek Pospisil |  | - |  | Dušan Lajović | 1 | : | 2 |
| Oct 01 • 13:30 | Yibing Wu |  | - |  | Malek Jaziri | 0 | : | 2 |
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| Oct 02 • 06:30 | Matteo Berrettini | | - |  | Leonardo Mayer | 2 | : | 0 |
| Oct 02 • 06:30 | Fernando Verdasco | | - |  | Gaël Monfils | 2 | : | 1 |
| Oct 02 • 08:00 | Mischa Zverev | | - | | Filip Krajinović | 0 | : | 2 |
| Oct 02 • 08:30 | Ryan Harrison | | - |  | Grigor Dimitrov | 0 | : | 0 |
| Oct 02 • 09:30 | Jack Sock | | - |  | Nikoloz Basilashvili | 1 | : | 2 |
| Oct 02 • 10:00 | Juan Martín del Potro | | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| Oct 02 • 11:00 | João Sousa |  | - | | Andrey Rublev | 0 | : | 2 |
| Oct 02 • 12:30 | Fabio Fognini | | - |  | Radu Albot | 2 | : | 1 |
| Oct 02 • 12:30 | Marcos Baghdatis |  | - | | Marco Cecchinato | 1 | : | 2 |
| Oct 02 • 15:00 | Roberto Bautista-Agut | | - | | Alexander Zverev | 0 | : | 2 |
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| Oct 03 • 06:30 | Dušan Lajović | | - | | Grigor Dimitrov | 2 | : | 1 |
| Oct 03 • 08:30 | Kyle Edmund | | - | | Matteo Berrettini | 2 | : | 1 |
| Oct 03 • 10:00 | Filip Krajinović | | - | | Feliciano López | 2 | : | 0 |
| Oct 03 • 13:30 | Juan Martín del Potro | | - | | Karen Khachanov | 2 | : | 0 |
| Oct 04 • 08:30 | Márton Fucsovics | | - | | Marco Cecchinato | 2 | : | 0 |
| Oct 04 • 10:30 | Fabio Fognini | | - | | Andrey Rublev | 2 | : | 0 |
| Oct 04 • 12:30 | Nikoloz Basilashvili | | - | | Fernando Verdasco | 2 | : | 0 |
| Oct 04 • 15:00 | Malek Jaziri | | - | | Alexander Zverev | 2 | : | 1 |
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| Oct 05 • 06:30 | Fabio Fognini | | - | | Márton Fucsovics | 2 | : | 0 |
| Oct 05 • 08:30 | Juan Martín del Potro | | - | | Filip Krajinović | 2 | : | 0 |
| Oct 05 • 10:30 | Kyle Edmund | | - | | Dušan Lajović | 2 | : | 0 |
| Oct 05 • 13:30 | Nikoloz Basilashvili | | - | | Malek Jaziri | 2 | : | 0 |
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| Oct 06 • 10:35 | Juan Martín del Potro | | - | | Fabio Fognini | 0 | : | 0 |
| Oct 06 • 15:00 | Kyle Edmund | | - | | Nikoloz Basilashvili | 0 | : | 2 |
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| Oct 07 • 13:30 | Juan Martín del Potro | | - | | Nikoloz Basilashvili | 0 | : | 2 |
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