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| May 22 • 11:00 | Aljaž Bedene |  | - |  | Christopher O'Connell | 3 | : | 1 |
| May 22 • 11:00 | Grigor Dimitrov |  | - |  | Marcos Giron | 3 | : | 0 |
| May 22 • 11:00 | Borna Ćorić |  | - |  | Carlos Taberner | 3 | : | 1 |
| May 22 • 11:00 | Daniel Altmaier |  | - | | Jaume Munar | 1 | : | 3 |
| May 22 • 11:00 | Hugo Dellien |  | - |  | Dominic Thiem | 3 | : | 0 |
| May 22 • 12:30 | Andrey Kuznetsov |  | - |  | Diego Schwartzman | 1 | : | 3 |
| May 22 • 12:30 | Felix Auger Aliassime |  | - |  | Juan Pablo Varillas | 3 | : | 2 |
| May 22 • 12:30 | Botic van de Zandschulp |  | - | | Pavel Kotov | 3 | : | 1 |
| May 22 • 12:30 | John Isner | | - |  | Quentin Halys | 3 | : | 1 |
| May 22 • 12:30 | Taro Daniel |  | - | | Gregoire Barrere | 2 | : | 3 |
| May 22 • 13:00 | Pablo Cuevas |  | - | | Jenson Brooksby | 3 | : | 0 |
| May 22 • 15:05 | Fabio Fognini |  | - | | Alexei Popyrin | 3 | : | 0 |
| May 22 • 15:10 | Tallon Griekspoor | | - | | Alejandro Davidovich Fokina | 3 | : | 1 |
| May 22 • 15:15 | Nuno Borges |  | - | | Karen Khachanov | 1 | : | 3 |
| May 22 • 16:30 | Camilo Ugo Carabelli | | - | | Aslan Karatsev | 3 | : | 2 |
| May 22 • 16:35 | Albert Ramos-Viñolas | | - | | Thanasi Kokkinakis | 3 | : | 1 |
| May 22 • 17:15 | Alexander Zverev | | - | | Sebastian Ofner | 3 | : | 0 |
| May 22 • 17:35 | Michael Mmoh | | - | | Bernabe Zapata Miralles | 0 | : | 3 |
| May 22 • 18:20 | Jason Kubler | | - | | Denis Kudla | 3 | : | 0 |
| May 22 • 18:30 | Juan Ignacio Londero | | - | | Carlos Alcaraz | 0 | : | 3 |
| May 23 • 11:00 | Alessandro Giannessi | | - | | Borna Gojo | 2 | : | 3 |
| May 23 • 11:00 | Filip Krajinović |  | - | | Reilly Opelka | 3 | : | 0 |
| May 23 • 11:00 | Santiago Rodriguez Taverna | | - | | Taylor Harry Fritz | 2 | : | 3 |
| May 23 • 12:40 | Dušan Lajović | | - | | Sebastián Báez | 1 | : | 3 |
| May 23 • 12:45 | Brandon Nakashima | | - |  | Kamil Majchrzak | 3 | : | 2 |
| May 23 • 12:50 | Daniel Evans |  | - | | Francisco Cerundolo | 3 | : | 0 |
| May 23 • 12:50 | Nikoloz Basilashvili |  | - | | Maxime Cressy | 3 | : | 2 |
| May 23 • 13:00 | Stanislas Wawrinka |  | - | | Corentin Moutet | 1 | : | 3 |
| May 23 • 13:00 | Cameron Norrie | | - | | Manuel Guinard | 3 | : | 0 |
| May 23 • 14:15 | Mikael Ymer |  | - | | James Duckworth | 3 | : | 0 |
| May 23 • 14:15 | Márton Fucsovics |  | - | | Geoffrey Blancaneaux | 3 | : | 0 |
| May 23 • 14:15 | Miomir Kecmanovic | | - | | Tomás Martín Etcheverry | 3 | : | 0 |
| May 23 • 14:20 | Mackenzie McDonald | | - | | Franco Agamenone | 3 | : | 1 |
| May 23 • 14:30 | Jordan Thompson | | - | | Rafael Nadal | 0 | : | 3 |
| May 23 • 14:30 | Attila Balazs | | - | | Marin Čilić | 0 | : | 3 |
| May 23 • 14:40 | Norbert Gombos |  | - | | Pedro Cachín | 1 | : | 3 |
| May 23 • 19:35 | Pedro Martínez | | - | | Henri Laaksonen | 1 | : | 3 |
| May 23 • 19:45 | Benoît Paire | | - |  | Ilya Ivashka | 1 | : | 3 |
| May 23 • 20:10 | Cristian Garín |  | - | | Tommy Paul | 3 | : | 1 |
| May 23 • 20:15 | Sebastian Korda | | - | | John Millman | 3 | : | 0 |
| May 23 • 20:15 | Lloyd Harris |  | - | | Richard Gasquet | 0 | : | 3 |
| May 23 • 20:45 | Novak Djokovic | | - | | Yoshihito Nishioka | 3 | : | 0 |
| May 23 • 20:50 | Arthur Rinderknech | | - |  | Alexander Bublik | 0 | : | 3 |
| May 24 • 11:00 | Emil Ruusuvuori |  | - | | Ugo Humbert | 3 | : | 2 |
| May 24 • 11:00 | João Sousa | | - |  | Tseng Chun-hsin | 3 | : | 2 |
| May 24 • 11:00 | Denis Shapovalov | | - |  | Holger Rune | 0 | : | 3 |
| May 24 • 11:00 | Ričardas Berankis |  | - | | Laslo Djere | 0 | : | 3 |
| May 24 • 11:00 | Facundo Bagnis | | - | | Daniil Medvedev | 0 | : | 3 |
| May 24 • 12:00 | Alex Molcan | | - | | Federico Coria | 3 | : | 1 |
| May 24 • 13:00 | Jiří Lehečka |  | - |  | David Goffin | 1 | : | 3 |
| May 24 • 13:30 | Casper Ruud |  | - | | Jo-Wilfried Tsonga | 3 | : | 1 |
| May 24 • 14:00 | Andrey Rublev | | - |  | Kwon Soon-woo | 3 | : | 1 |
| May 24 • 14:15 | Peter Gojowczyk | | - | | Lorenzo Sonego | 0 | : | 3 |
| May 24 • 14:40 | Frances Tiafoe | | - | | Benjamin Bonzi | 3 | : | 0 |
| May 24 • 14:45 | Adrian Mannarino | | - | | Federico Delbonis | 0 | : | 3 |
| May 24 • 16:15 | Hugo Gaston | | - | | Alex De Minaur | 3 | : | 2 |
| May 24 • 17:15 | Roberto Carballés Baena | | - | | Oscar Otte | 3 | : | 2 |
| May 24 • 17:25 | Giulio Zeppieri | | - | | Hubert Hurkacz | 0 | : | 3 |
| May 24 • 17:30 | Marco Cecchinato | | - | | Pablo Andújar | 3 | : | 2 |
| May 24 • 19:25 | Bjorn Fratangelo | | - | | Jannik Sinner | 0 | : | 3 |
| May 24 • 19:30 | Lucas Pouille | | - | | Zdeněk Kolář | 1 | : | 3 |
| May 24 • 19:45 | Jiří Veselý | | - | | Steve Johnson | 1 | : | 3 |
| May 24 • 20:45 | Lorenzo Musetti | | - |  | Stefanos Tsitsipas | 2 | : | 3 |
| May 24 • 21:00 | Pablo Carreño Busta | | - | | Gilles Simon | 2 | : | 3 |
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| May 25 • 11:00 | Felix Auger Aliassime | | - | | Camilo Ugo Carabelli | 3 | : | 0 |
| May 25 • 11:00 | John Isner | | - | | Gregoire Barrere | 3 | : | 1 |
| May 25 • 11:00 | Hugo Dellien | | - | | Karen Khachanov | 1 | : | 3 |
| May 25 • 12:30 | Aljaž Bedene | | - | | Pablo Cuevas | 3 | : | 1 |
| May 25 • 12:30 | Borna Gojo | | - | | Filip Krajinović | 1 | : | 3 |
| May 25 • 12:30 | Bernabe Zapata Miralles | | - | | Taylor Harry Fritz | 3 | : | 1 |
| May 25 • 12:30 | Cameron Norrie | | - | | Jason Kubler | 3 | : | 0 |
| May 25 • 13:45 | Alexander Zverev | | - | | Sebastián Báez | 3 | : | 2 |
| May 25 • 15:10 | Novak Djokovic | | - | | Alex Molcan | 3 | : | 0 |
| May 25 • 15:15 | Jaume Munar | | - | | Diego Schwartzman | 2 | : | 3 |
| May 25 • 15:25 | Albert Ramos-Viñolas | | - | | Carlos Alcaraz | 2 | : | 3 |
| May 25 • 16:10 | Brandon Nakashima | | - | | Tallon Griekspoor | 3 | : | 0 |
| May 25 • 16:30 | Botic van de Zandschulp | | - | | Fabio Fognini | 2 | : | 0 |
| May 25 • 16:45 | Grigor Dimitrov | | - | | Borna Ćorić | 3 | : | 0 |
| May 25 • 17:00 | Sebastian Korda | | - | | Richard Gasquet | 3 | : | 0 |
| May 25 • 20:45 | Corentin Moutet | | - | | Rafael Nadal | 0 | : | 3 |
| May 26 • 11:00 | Casper Ruud | | - | | Emil Ruusuvuori | 3 | : | 0 |
| May 26 • 11:00 | Holger Rune | | - | | Henri Laaksonen | 3 | : | 0 |
| May 26 • 12:00 | Laslo Djere | | - | | Daniil Medvedev | 0 | : | 3 |
| May 26 • 12:30 | João Sousa | | - | | Lorenzo Sonego | 0 | : | 3 |
| May 26 • 12:30 | Frances Tiafoe | | - | | David Goffin | 1 | : | 3 |
| May 26 • 12:30 | Pedro Cachín | | - | | Hugo Gaston | 0 | : | 3 |
| May 26 • 12:30 | Márton Fucsovics | | - | | Marin Čilić | 1 | : | 3 |
| May 26 • 12:30 | Miomir Kecmanovic | | - | | Alexander Bublik | 3 | : | 1 |
| May 26 • 13:30 | Marco Cecchinato | | - | | Hubert Hurkacz | 0 | : | 3 |
| May 26 • 14:00 | Ilya Ivashka | | - | | Cristian Garín | 1 | : | 3 |
| May 26 • 14:30 | Nikoloz Basilashvili | | - | | Mackenzie McDonald | 0 | : | 3 |
| May 26 • 15:30 | Gilles Simon | | - | | Steve Johnson | 3 | : | 0 |
| May 26 • 16:00 | Daniel Evans | | - | | Mikael Ymer | 1 | : | 3 |
| May 26 • 16:00 | Zdeněk Kolář | | - | | Stefanos Tsitsipas | 1 | : | 3 |
| May 26 • 16:00 | Andrey Rublev | | - | | Federico Delbonis | 3 | : | 1 |
| May 26 • 16:00 | Roberto Carballés Baena | | - | | Jannik Sinner | 1 | : | 3 |
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| May 27 • 11:00 | Grigor Dimitrov | | - | | Diego Schwartzman | 0 | : | 3 |
| May 27 • 14:25 | Novak Djokovic | | - | | Aljaž Bedene | 3 | : | 0 |
| May 27 • 14:25 | Felix Auger Aliassime | | - | | Filip Krajinović | 3 | : | 0 |
| May 27 • 15:40 | Botic van de Zandschulp | | - | | Rafael Nadal | 0 | : | 3 |
| May 27 • 15:50 | John Isner | | - | | Bernabe Zapata Miralles | 2 | : | 3 |
| May 27 • 17:25 | Cameron Norrie | | - | | Karen Khachanov | 1 | : | 3 |
| May 27 • 17:40 | Alexander Zverev | | - | | Brandon Nakashima | 3 | : | 0 |
| May 27 • 20:45 | Sebastian Korda | | - | | Carlos Alcaraz | 0 | : | 3 |
| May 28 • 11:00 | Andrey Rublev | | - | | Cristian Garín | 3 | : | 1 |
| May 28 • 11:00 | Mackenzie McDonald | | - | | Jannik Sinner | 0 | : | 3 |
| May 28 • 12:30 | Miomir Kecmanovic | | - | | Daniil Medvedev | 0 | : | 3 |
| May 28 • 14:30 | David Goffin | | - | | Hubert Hurkacz | 0 | : | 3 |
| May 28 • 15:00 | Gilles Simon | | - | | Marin Čilić | 0 | : | 3 |
| May 28 • 16:35 | Mikael Ymer | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| May 28 • 17:50 | Casper Ruud | | - | | Lorenzo Sonego | 3 | : | 2 |
| May 28 • 20:45 | Holger Rune | | - | | Hugo Gaston | 3 | : | 0 |
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| May 29 • 12:30 | Novak Djokovic | | - | | Diego Schwartzman | 3 | : | 0 |
| May 29 • 14:30 | Alexander Zverev | | - | | Bernabe Zapata Miralles | 3 | : | 0 |
| May 29 • 15:00 | Felix Auger Aliassime | | - | | Rafael Nadal | 2 | : | 3 |
| May 29 • 20:55 | Karen Khachanov | | - | | Carlos Alcaraz | 0 | : | 3 |
| May 30 • 12:30 | Casper Ruud | | - | | Hubert Hurkacz | 3 | : | 1 |
| May 30 • 13:30 | Holger Rune | | - | | Stefanos Tsitsipas | 3 | : | 1 |
| May 30 • 17:15 | Andrey Rublev | | - | | Jannik Sinner | 1 | : | 1 |
| May 30 • 20:45 | Marin Čilić | | - | | Daniil Medvedev | 3 | : | 0 |
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| May 31 • 15:00 | Alexander Zverev | | - | | Carlos Alcaraz | 3 | : | 1 |
| May 31 • 20:45 | Novak Djokovic | | - | | Rafael Nadal | 1 | : | 3 |
| Jun 01 • 15:00 | Andrey Rublev | | - | | Marin Čilić | 2 | : | 3 |
| Jun 01 • 20:45 | Casper Ruud | | - | | Holger Rune | 3 | : | 1 |
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| Jun 03 • 14:45 | Rafael Nadal | | - | | Alexander Zverev | 1 | : | 0 |
| Jun 03 • 17:30 | Casper Ruud | | - | | Marin Čilić | 3 | : | 1 |
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| Jun 05 • 15:10 | Rafael Nadal | | - | | Casper Ruud | 3 | : | 0 |
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