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| May 08 • 11:00 | Jakub Mensik |  | - |  | Yannick Hanfmann | 0 | : | 2 |
| May 08 • 11:00 | Zhang Zhizhen |  | - |  | Daniel Elahi Galán | 2 | : | 0 |
| May 08 • 11:00 | Luciano Darderi |  | - |  | Denis Shapovalov | 2 | : | 1 |
| May 08 • 11:00 | Nuno Borges |  | - |  | Pedro Martínez | 2 | : | 1 |
| May 08 • 11:00 | Yoshihito Nishioka |  | - |  | Sebastian Ofner | 2 | : | 1 |
| May 08 • 12:30 | Alexander Shevchenko |  | - |  | Fábián Marozsán | 2 | : | 0 |
| May 08 • 12:30 | Pavel Kotov | | - |  | Alex Michelsen | 2 | : | 0 |
| May 08 • 12:30 | Maximilian Marterer | | - | | Flavio Cobolli | 0 | : | 2 |
| May 08 • 14:00 | Thiago Moura Monteiro |  | - |  | Gaël Monfils | 2 | : | 0 |
| May 08 • 15:55 | Arthur Rinderknech | | - | | Francesco Passaro | 1 | : | 2 |
| May 08 • 16:15 | Christopher Eubanks | | - | | Terence Atmane | 0 | : | 2 |
| May 08 • 16:20 | Diego Schwartzman |  | - |  | Aleksandar Vukic | 0 | : | 2 |
| May 09 • 11:00 | Rinky Hijikata | | - | | Jaume Munar | 0 | : | 2 |
| May 09 • 11:00 | Thiago Seyboth Wild | | - | | Gregoire Barrere | 2 | : | 0 |
| May 09 • 11:00 | Dominik Koepfer | | - | | Andrea Vavassori | 2 | : | 0 |
| May 09 • 11:00 | Alexei Popyrin | | - |  | Hamad Medjedovic | 0 | : | 2 |
| May 09 • 13:15 | Zizou Bergs |  | - | | Rafael Nadal | 1 | : | 2 |
| May 09 • 13:45 | Stefano Napolitano | | - | | Jeffrey John Wolf | 2 | : | 0 |
| May 09 • 14:00 | Matteo Gigante | | - | | Giulio Zeppieri | 2 | : | 0 |
| May 09 • 14:15 | Corentin Moutet | | - | | Roman Safiullin | 2 | : | 1 |
| May 09 • 15:15 | Miomir Kecmanovic | | - | | Brandon Nakashima | 2 | : | 0 |
| May 09 • 17:50 | Harold Mayot | | - | | Matteo Arnaldi | 1 | : | 2 |
| May 09 • 18:25 | Jack Draper |  | - |  | Borna Ćorić | 2 | : | 0 |
| May 09 • 19:00 | Roberto Carballés Baena | | - | | Christopher O'Connell | 0 | : | 0 |
| May 09 • 19:00 | Emil Ruusuvuori |  | - | | Marcos Giron | 1 | : | 2 |
| May 09 • 19:40 | Jan-Lennard Struff | | - | | Pedro Cachín | 2 | : | 0 |
| May 09 • 19:50 | Alexandre Muller | | - | | Márton Fucsovics | 2 | : | 1 |
| May 09 • 20:00 | Daniel Evans | | - | | Fabio Fognini | 1 | : | 2 |
| May 09 • 20:10 | Nicolas Moreno de Alboran | | - |  | Botic van de Zandschulp | 1 | : | 2 |
| May 09 • 21:15 | Mackenzie McDonald | | - | | Aslan Karatsev | 1 | : | 2 |
| May 09 • 21:55 | Daniel Altmaier | | - | | Luca Nardi | 0 | : | 2 |
| May 09 • 22:25 | Dušan Lajović | | - | | Lorenzo Sonego | 2 | : | 1 |
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| May 10 • 11:00 | Nuno Borges | | - |  | Alexander Bublik | 2 | : | 0 |
| May 10 • 11:00 | Lorenzo Musetti | | - | | Terence Atmane | 0 | : | 1 |
| May 10 • 12:30 | Ben Shelton | | - | | Pavel Kotov | 2 | : | 1 |
| May 10 • 12:30 | Zhang Zhizhen | | - | | Adrian Mannarino | 2 | : | 0 |
| May 10 • 12:30 | Luciano Darderi | | - | | Mariano Navone | 2 | : | 0 |
| May 10 • 12:30 | Yoshihito Nishioka | | - |  | Grigor Dimitrov | 0 | : | 2 |
| May 10 • 14:25 | Jordan Thompson | | - | | Thiago Moura Monteiro | 0 | : | 2 |
| May 10 • 14:45 | Flavio Cobolli | | - | | Sebastian Korda | 1 | : | 2 |
| May 10 • 15:00 | Alexander Zverev | | - | | Aleksandar Vukic | 2 | : | 0 |
| May 10 • 16:55 | Alexander Shevchenko | | - | | Karen Khachanov | 0 | : | 2 |
| May 10 • 17:25 | Tallon Griekspoor | | - | | Francesco Passaro | 1 | : | 2 |
| May 10 • 17:45 | Yannick Hanfmann | | - |  | Alejandro Tabilo | 0 | : | 2 |
| May 10 • 17:45 | Miomir Kecmanovic | | - |  | Casper Ruud | 2 | : | 1 |
| May 10 • 17:45 | Taylor Harry Fritz | | - | | Fabio Fognini | 2 | : | 0 |
| May 10 • 18:10 | Francisco Cerundolo | | - | | Matteo Gigante | 2 | : | 0 |
| May 10 • 19:00 | Novak Djokovic | | - | | Corentin Moutet | 2 | : | 0 |
| May 11 • 11:00 | Matteo Arnaldi | | - | | Nicolás Jarry | 0 | : | 2 |
| May 11 • 11:00 | Thiago Seyboth Wild | | - | | Tomás Martín Etcheverry | 0 | : | 2 |
| May 11 • 11:00 | Alejandro Davidovich Fokina | | - | | Hamad Medjedovic | 0 | : | 2 |
| May 11 • 13:00 | Hubert Hurkacz |  | - | | Rafael Nadal | 2 | : | 0 |
| May 11 • 13:30 | Tommy Paul | | - | | Aslan Karatsev | 2 | : | 0 |
| May 11 • 13:55 | Shang Juncheng | | - | | Stefano Napolitano | 1 | : | 2 |
| May 11 • 14:15 | Dominik Koepfer | | - | | Frances Tiafoe | 2 | : | 0 |
| May 11 • 14:45 | Roberto Carballés Baena | | - | | Alex De Minaur | 0 | : | 2 |
| May 11 • 14:45 | Jack Draper | | - | | Daniil Medvedev | 0 | : | 2 |
| May 11 • 15:30 | Arthur Fils | | - | | Alexandre Muller | 0 | : | 2 |
| May 11 • 15:55 | Sebastián Báez | | - | | Dušan Lajović | 2 | : | 0 |
| May 11 • 16:55 | Jaume Munar | | - | | Cameron Norrie | 1 | : | 2 |
| May 11 • 18:45 | Felix Auger Aliassime | | - | | Botic van de Zandschulp | 2 | : | 0 |
| May 11 • 18:55 | Stefanos Tsitsipas |  | - | | Jan-Lennard Struff | 2 | : | 1 |
| May 11 • 20:30 | Luca Nardi | | - |  | Holger Rune | 0 | : | 2 |
| May 11 • 21:10 | Marcos Giron | | - | | Andrey Rublev | 1 | : | 2 |
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| May 12 • 11:00 | Thiago Moura Monteiro | | - | | Miomir Kecmanovic | 2 | : | 1 |
| May 12 • 11:00 | Francesco Passaro | | - | | Nuno Borges | 1 | : | 2 |
| May 12 • 12:30 | Francisco Cerundolo | | - | | Karen Khachanov | 0 | : | 2 |
| May 12 • 12:30 | Terence Atmane | | - | | Grigor Dimitrov | 0 | : | 2 |
| May 12 • 14:00 | Novak Djokovic | | - | | Alejandro Tabilo | 0 | : | 2 |
| May 12 • 14:00 | Taylor Harry Fritz | | - | | Sebastian Korda | 2 | : | 0 |
| May 12 • 19:30 | Ben Shelton | | - | | Zhang Zhizhen | 0 | : | 2 |
| May 12 • 20:30 | Alexander Zverev | | - | | Luciano Darderi | 2 | : | 0 |
| May 13 • 11:00 | Felix Auger Aliassime | | - | | Alex De Minaur | 1 | : | 2 |
| May 13 • 12:30 | Stefanos Tsitsipas | | - | | Cameron Norrie | 2 | : | 0 |
| May 13 • 13:00 | Alexandre Muller | | - | | Andrey Rublev | 2 | : | 1 |
| May 13 • 14:30 | Stefano Napolitano | | - | | Nicolás Jarry | 1 | : | 2 |
| May 13 • 15:00 | Tommy Paul | | - | | Dominik Koepfer | 2 | : | 0 |
| May 13 • 16:45 | Hubert Hurkacz | | - | | Tomás Martín Etcheverry | 2 | : | 0 |
| May 13 • 18:30 | Sebastián Báez | | - | | Holger Rune | 2 | : | 1 |
| May 13 • 19:00 | Hamad Medjedovic | | - | | Daniil Medvedev | 1 | : | 2 |
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| May 14 • 11:00 | Alejandro Tabilo | | - | | Karen Khachanov | 2 | : | 0 |
| May 14 • 11:00 | Taylor Harry Fritz | | - | | Grigor Dimitrov | 2 | : | 1 |
| May 14 • 12:55 | Zhang Zhizhen | | - | | Thiago Moura Monteiro | 2 | : | 0 |
| May 14 • 15:40 | Alexander Zverev | | - | | Nuno Borges | 2 | : | 0 |
| May 14 • 16:00 | Hubert Hurkacz | | - | | Sebastián Báez | 2 | : | 1 |
| May 14 • 16:15 | Nicolás Jarry | | - | | Alexandre Muller | 2 | : | 0 |
| May 14 • 18:00 | Tommy Paul | | - | | Daniil Medvedev | 2 | : | 0 |
| May 14 • 19:00 | Stefanos Tsitsipas | | - | | Alex De Minaur | 2 | : | 0 |
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| May 15 • 15:00 | Alejandro Tabilo | | - | | Zhang Zhizhen | 2 | : | 0 |
| May 15 • 20:30 | Alexander Zverev | | - | | Taylor Harry Fritz | 2 | : | 0 |
| May 16 • 13:00 | Hubert Hurkacz | | - | | Tommy Paul | 1 | : | 2 |
| May 16 • 19:00 | Stefanos Tsitsipas | | - | | Nicolás Jarry | 1 | : | 2 |
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| May 17 • 15:30 | Alejandro Tabilo | | - | | Alexander Zverev | 1 | : | 2 |
| May 17 • 20:30 | Nicolás Jarry | | - | | Tommy Paul | 2 | : | 1 |
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| May 19 • 17:00 | Alexander Zverev | | - | | Nicolás Jarry | 2 | : | 0 |
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