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| May 12 • 13:00 | Matteo Viola |  | - |  | Alexandr Dolgopolov | 0 | : | 2 |
| May 12 • 13:00 | Denis Istomin |  | - |  | John Isner | 2 | : | 1 |
| May 12 • 14:30 | Kevin Anderson |  | - |  | Jürgen Melzer | 2 | : | 0 |
| May 12 • 14:30 | Sam Querrey | | - |  | Richard Gasquet | 0 | : | 2 |
| May 12 • 16:00 | Marcel Granollers |  | - |  | Nikolay Davydenko | 2 | : | 0 |
| May 12 • 16:00 | Marcos Baghdatis |  | - |  | Grigor Dimitrov | 0 | : | 2 |
| May 13 • 11:00 | Albert Ramos-Viñolas | | - |  | Jan Hájek | 2 | : | 0 |
| May 13 • 11:00 | Juan Mónaco |  | - | | Benoît Paire | 1 | : | 2 |
| May 13 • 12:00 | Radek Štěpánek | | - | | Potito Starace | 1 | : | 2 |
| May 13 • 12:35 | Andrey Kuznetsov | | - |  | Xavier Malisse | 1 | : | 0 |
| May 13 • 13:30 | Marin Čilić |  | - |  | Andrey Golubev | 2 | : | 0 |
| May 13 • 14:20 | Jarkko Nieminen |  | - |  | Ernests Gulbis | 0 | : | 2 |
| May 13 • 16:15 | Santiago Giraldo |  | - |  | Jerzy Janowicz | 0 | : | 2 |
| May 13 • 16:25 | Albert Montañés | | - |  | Martin Kližan | 2 | : | 1 |
| May 13 • 16:30 | Fabio Fognini | | - | | Andreas Seppi | 2 | : | 0 |
| May 13 • 19:00 | Philipp Kohlschreiber |  | - |  | Milos Raonic | 2 | : | 0 |
| May 13 • 21:00 | Kei Nishikori |  | - | | Paolo Lorenzi | 2 | : | 0 |
| May 14 • 11:00 | Horacio Zeballos | | - | | Fernando Verdasco | 1 | : | 2 |
| May 14 • 11:00 | Jérémy Chardy | | - | | Feliciano López | 2 | : | 1 |
| May 14 • 11:00 | Tommy Haas | | - | | Mikhail Youzhny | 0 | : | 2 |
| May 14 • 12:30 | Lukáš Rosol | | - |  | Viktor Troicki | 1 | : | 2 |
| May 14 • 12:30 | Julien Benneteau | | - | | Nicolás Almagro | 2 | : | 0 |
| May 14 • 12:30 | Filippo Volandri | | - | | Gilles Simon | 1 | : | 2 |
| May 14 • 14:00 | Carlos Berlocq | | - |  | Stanislas Wawrinka | 1 | : | 2 |
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| May 14 • 13:30 | Grigor Dimitrov | | - | | Richard Gasquet | 0 | : | 2 |
| May 14 • 16:50 | Novak Djokovic | | - | | Albert Montañés | 2 | : | 0 |
| May 14 • 16:50 | Marin Čilić | | - | | Kevin Anderson | 0 | : | 2 |
| May 14 • 17:25 | Juan Martín del Potro | | - | | Alex Kuznetsov | 2 | : | 0 |
| May 14 • 19:10 | Tomáš Berdych | | - | | Denis Istomin | 2 | : | 0 |
| May 14 • 19:30 | Roger Federer | | - | | Potito Starace | 2 | : | 0 |
| May 15 • 12:00 | Jo-Wilfried Tsonga | | - | | Jerzy Janowicz | 0 | : | 2 |
| May 15 • 12:40 | Benoît Paire | | - | | Julien Benneteau | 2 | : | 1 |
| May 15 • 12:45 | Mikhail Youzhny | | - | | Gilles Simon | 0 | : | 2 |
| May 15 • 13:20 | Andy Murray |  | - | | Marcel Granollers | 1 | : | 1 |
| May 15 • 13:35 | Alexandr Dolgopolov | | - | | Stanislas Wawrinka | 0 | : | 0 |
| May 15 • 15:15 | Kei Nishikori | | - | | Jérémy Chardy | 0 | : | 2 |
| May 15 • 15:55 | Albert Ramos-Viñolas | | - | | Philipp Kohlschreiber | 0 | : | 2 |
| May 15 • 17:30 | David Ferrer | | - | | Fernando Verdasco | 2 | : | 1 |
| May 15 • 19:00 | Viktor Troicki | | - | | Ernests Gulbis | 0 | : | 2 |
| May 15 • 19:30 | Fabio Fognini | | - | | Rafael Nadal | 0 | : | 2 |
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| May 16 • 11:05 | Kevin Anderson | | - | | Tomáš Berdych | 0 | : | 2 |
| May 16 • 12:00 | Novak Djokovic | | - | | Alexandr Dolgopolov | 2 | : | 0 |
| May 16 • 14:35 | Juan Martín del Potro | | - | | Benoît Paire | 0 | : | 2 |
| May 16 • 15:15 | Ernests Gulbis | | - | | Rafael Nadal | 1 | : | 2 |
| May 16 • 16:40 | Jérémy Chardy | | - | | Marcel Granollers | 1 | : | 2 |
| May 16 • 17:40 | David Ferrer | | - | | Philipp Kohlschreiber | 0 | : | 0 |
| May 16 • 19:00 | Jerzy Janowicz | | - | | Richard Gasquet | 2 | : | 1 |
| May 16 • 21:10 | Gilles Simon | | - | | Roger Federer | 0 | : | 2 |
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| May 17 • 12:00 | Benoît Paire | | - | | Marcel Granollers | 2 | : | 0 |
| May 17 • 14:00 | Novak Djokovic | | - | | Tomáš Berdych | 1 | : | 2 |
| May 17 • 16:45 | David Ferrer | | - | | Rafael Nadal | 1 | : | 2 |
| May 17 • 21:00 | Jerzy Janowicz | | - | | Roger Federer | 0 | : | 2 |
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| May 18 • 16:00 | Tomáš Berdych | | - | | Rafael Nadal | 0 | : | 2 |
| May 18 • 20:00 | Benoît Paire | | - | | Roger Federer | 0 | : | 2 |
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| May 19 • 16:00 | Rafael Nadal | | - | | Roger Federer | 2 | : | 0 |
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